Novel Gallium(III), Germanium(IV), and Hafnium(IV) Folate Complexes and Their Spectroscopic, Thermal Decomposition, Morphological, and Biological Characteristics

Table 5

Kinetic thermodynamic parameters of the FAH₂ and synthesized complexes.

Compound	Steps	Coats–Redfern equation
		r	E (kJ mol^−1)	∆S (Jk^−1mol^−1)	∆H (kJ mol^−1)	∆G (kJ mol^−1)
Ga(III) complex	1^st	0.9976	4.9510^4	−1.6810^2	4.6310^4	1.1210^5
	2^nd	0.9429	2.8210^4	−1.3810^2	2.3410^4	1.0410^5
	3^rd	0.9872	1.1010^5	−1.7910^2	1.0210^5	2.6210^5
Ge(IV) complex	1^st	0.9896	2.9110^4	−1.7110^2	2.6110^4	8.8010^4
	2^nd	0.9808	5.0210^4	−1.7510^2	4.6010^4	1.3410^5
	3^rd	0.9477	5.2110^4	−1.4310^2	4.5210^4	1.6410^5
Hf(IV) complex	1^st	0.9987	3.1810^4	−1.6510^2	2.8710^4	8.9410^4
	2^nd	0.9892	4.3010^4	−1.6210^2	3.8510^4	1.2610^5
	3^rd	0.9970	4.9010^4	−1.6010^2	4.4510^4	1.3210^5
Compound	Steps	Horowitz and Metzger equation
		r	E (kJ mol^−1)	∆S (Jk^−1mol^−1)	∆H (kJ mol^−1)	∆G (kJ mol^−1)
Ga(III) complex	1^st	0.9895	5.6010^4	−1.4210^2	5.2710^4	1.0810^5
	2^nd	0.9372	3.6210^4	−2.3710^2	3.1310^4	1.7010^5
	3^rd	0.9858	1.2710^5	−1.5610^2	1.2010^5	2.6010^5
Ge(IV) complex	1^st	0.9846	3.5010^4	−1.9010^2	3.2010^4	1.0110^5
	2^nd	0.9969	5.9410^4	−1.7310^2	5.5110^4	1.4310^5
	3^rd	0.9706	6.7810^4	−2.2110^2	6.0910^4	2.4510^5
Hf(IV) complex	1^st	0.9778	3.9510^4	−1.7810^2	3.6410^4	1.0210^5
	2^nd	0.9827	5.2010^4	−1.9710^2	4.7510^4	1.5410^5
	3^rd	0.9822	6.8010^4	−1.9210^2	5.8010^4	2.3410^5