Research Article

Demonstration of Redox Potential of Metschnikowia koreensis for Stereoinversion of Secondary Alcohols/1,2-Diols

Table 2

Biocatalytic deracemization of 3-aryloxy-1,2-propanediol by stereoselective oxidation reduction using whole cells of M. .

EntrySubstrate
410530.tab.002
Yield (%)bee (%)bConfiguration

1R = H98>99S
2R = Me97>98S

Reactions were carried out with two substrates (5 mM, each) using the resting cells (250 mg/mL). bYield and ee were determined by chiral HPLC with Phenomenex Lux cellulose-1 (250 × 4.6 mm) column.