Research Article
Heavy Metal Adsorption onto Kappaphycus sp. from Aqueous Solutions: The Use of Error Functions for Validation of Isotherm and Kinetics Models
Table 8
Error function data of the kinetic models.
| Metal ion | Kinetic model | Error function | SSE | ARE | HYBRID | EABS | MPSD | | | (%) | RMSE |
| Pb2+ | Pseudo-first-order | 25.7891 | 92.8427 | 129.9800 | 13.4342 | 157.948 | 0.49997 | 178.767 | 100.288 | 2.27108 | Pseudo-second-order | 0.003366 | 0.56776 | 0.79486 | 0.08086 | 1.82415 | 0.80927 | 0.00171 | 1.17070 | 0.02595 | Elovich | 9.30E − 05 | 0.16020 | 0.22428 | 0.02312 | 0.30064 | 0.98456 | 4.52E − 05 | 0.19128 | 0.00431 | Intraparticle diffusion | 2.39E − 06 | 0.03899 | 0.11698 | 0.00245 | 0.10672 | 0.98437 | 1.14E − 06 | 0.05210 | 0.00155 |
| Cu2+ | Pseudo-first-order | 25.3581 | 94.2342 | 131.928 | 13.3208 | 158.455 | 0.49992 | 220.398 | 101.787 | 2.25202 | Pseudo-second-order | 0.00015 | 0.16029 | 0.22440 | 0.02232 | 0.38712 | 0.97869 | 7.51E − 05 | 0.25151 | 0.00544 | Elovich | 0.00040 | 0.33223 | 0.46512 | 0.04693 | 0.62860 | 0.93190 | 0.00020 | 0.40416 | 0.00893 | Intraparticle diffusion | 3.29E − 06 | 0.05087 | 0.15262 | 0.00310 | 0.12720 | 0.98718 | 1.62E − 06 | 0.06311 | 0.00181 |
| Fe2+ | Pseudo-first-order | 3.49809 | 56.1628 | 78.6279 | 4.90190 | 74.5604 | 0.49752 | 6.56855 | 60.8816 | 0.83643 | Pseudo-second-order | 0.00400 | 1.35554 | 1.89776 | 0.10685 | 2.72686 | 0.95949 | 0.00390 | 2.40267 | 0.02828 | Elovich | 0.00181 | 1.13760 | 1.59264 | 0.09939 | 1.68403 | 0.97531 | 0.00141 | 1.36581 | 0.01902 | Intraparticle diffusion | 0.00031 | 0.66725 | 1.33449 | 0.03436 | 1.08937 | 0.96472 | 0.00024 | 0.78427 | 0.01236 |
| Zn2+ | Pseudo-first-order | 0.92442 | 73.8117 | 103.336 | 2.53393 | 61.3141 | 0.49932 | 7.65727 | 79.9178 | 0.42998 | Pseudo-second-order | 0.00279 | 2.59220 | 3.62908 | 0.08525 | 3.48380 | 0.77805 | 0.00673 | 4.68899 | 0.02363 | Elovich | 0.00064 | 1.63635 | 2.29089 | 0.05555 | 1.62276 | 0.88172 | 0.00133 | 2.12691 | 0.01133 | Intraparticle diffusion | 3.87E − 06 | 0.18119 | 0.36239 | 0.00362 | 0.19597 | 0.99645 | 7.68E − 06 | 0.22567 | 0.00139 |
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