Research Article

Predicting Accumulation of Intermediate Compounds in Nitrification and Autotrophic Denitrification Processes: A Chemical Approach

Table 4

calculation of the redox half-reactions involved during ammonia oxidation and autotrophic denitrification processes under the operating conditions of each studied stage.

NitrificationN2O reduction to O2 reduction to H2O reduction to
(V)(V)(V)

Stage 11.490.790.30
Stage 21.490.790.30
Stage 31.490.790.30
Stage 41.490.790.30
Stage 51.490.790.30
Stage 61.490.790.30
Stage 71.490.790.30
Stage 81.490.790.30
Stage 91.490.790.30
Stage 101.490.790.30
Stage 111.490.790.30
Stage 121.490.790.30

Autotrophic denitrification reduction to N2 reduction to N2 reduction to HS-S reduction to HS-
(V)(V)(V)(V)

Stage 10.70-0.19-0.27-0.34
Stage 20.68-0.21-0.28-0.35
Stage 30.64-0.26-0.32-0.36
Stage 40.59-0.31-0.37-0.38
Stage 50.72-0.17-0.25-0.33
Stage 60.67-0.23-0.29-0.35
Stage 70.66-0.24-0.31-0.36
Stage 80.70-0.19-0.26-0.34
Stage 90.70-0.19-0.26-0.34