Adulteration and Contamination of Commercial Sap of Hymenaea Species

Table 2

The major compounds present in the sap of Hymenaea stigonocarpa (Hs-1) and stem bark (Hs-sb1).

Peak	Time (min)	Compound name	M/S (m/z)	Molecular formula	Error (ppm)	Sap/stem bark
1	3.1	Unknown	297.0611	C13H12O8	1	Sap
2	5.2	Unknown	269.0021	—		Stem bark
3	11.0	Unknown	329.0872	C14H16O9	1	Sap
4	19.4	Procyanidin II Derivative	579.1475; 579.1491	C30H26O12	5; 2	Sap; Stem bark
5	21.5	Procyanidin II Derivative glycosyl	725.2069	C36H36O16	3	Stem bark
6	21.1	Flavan-3-ol derivative	275.0910	C15H14O5	4	Sap
7	22.5	Catechin	291.0863; 291.0864	C15H14O6	2; 2	Sap; Stem bark
8	22.9	Procyanidin III Derivative	867.2103	C45H38O18	4	Stem bark
9	24.9	Procyanidin II Derivative	725.2074	C36H36O16	2	Stem bark
10	26.2	Unknown	453.2501	C24H36O8	3	Sap
11	26.2	Unknown	209.1152	—		Sap
12	27.1	Flavonoid Derivative	285.0749	C16H12O5	5	Sap
13	27.2	Unknown	453.2487	C24H36O8	1	Sap
14	27.2	Unknown	209.1152	—		Sap
15	28.5	Unknown	209.0878	—		Sap
16	28.5	Procyanidin II Derivative	563.1534	C30H26O11	2	Sap
17	28.8	Procyanidin II Derivative	579.1496	C30H26O12	2	Stem bark
18	30.0	Flavonol Glycosyl	479.1188	C22H22O12	1	Sap
19	30.4	Unknown	739.1850	C43H30O12	5	Stem bark
20	30.9	Procyanidin II Derivative	563.1553	C30H26O11	1	Sap
21	31.1	Epicatechin	291.0858; 291.0857	C15H14O6	4; 4	Sap; Stem bark
22	32.1	Flavonoid Derivative	289.0698	C15H12O6	5	Sap
23	32.1	Unknown	271.0599	C15H10O5	3	Sap
24	32.3	Procyanidin II Derivative	723.1900	C36H34O16	4	Stem bark
25	32.9	Unknown	739.1832	C43H30O12	3	Stem bark
26	32.9	Flavanonol Derivative	319.0801	C16H14O7	5	Sap
27	35.3	Procyanidin II Derivative	563.1541	C30H26O11	2	Sap
28	35.5	Procyanidin II Derivative	723.1904	C36H34O16	3	Stem bark
29	36.4	Unknown	739.1847	C43H30O12	4	Stem bark
30	36.7	Procyanidin III Derivative	867.2092	C45H38O18	5	Stem bark
31	37.9	Procyanidin II Derivative	563.1541	C30H26O11	3	Sap
32	38.9	Procyanidin II Derivative	723.1901	C36H34O16	4	Stem bark
33	40.2	Flavanonol Derivative	319.0802	C16H14O7	5	Sap
34	40.5	Unknown	277.1060	C15H16O5	6	Sap
35	40.9	Flavone Derivative	285.0753	C16H12O5	5	Sap
36	41.2	Flavan-3-ol Derivative	305.1019	C16H16O6	2	Sap
37	41.2	Unknown	153.0534	—		Sap
38	41.7	Procyanidin II Derivative	563.1542	C30H26O11	3	Sap
39	41.9	Procyanidin II Derivative	723.1911	C36H34O16	2	Stem bark
40	42.4	Procyanidin II Derivative	563.1553	C30H26O11	1	Sap
41	42.9	Unknown	739.1844	C43H30O12	4	Stem bark
42	43.6	Unknown	739.1851	C43H30O12	5	Stem bark
43	44.8	Procyanidin II Derivative	563.1533	C30H26O11	4	Sap
44	47.3	Unknown	249.1167; 249.1149	—	—	Sap; Stem bark
45	47.4	Procyanidin II Derivative	563.1545	C30H26O11	2	Sap
46	47.7	Flavanonol Derivative	305.0647	C15H12O7	5	Sap
47	48.3	Procyanidin II Derivative	563.1567	C30H26O11	3	Sap
48	50.0	Procyanidin II Derivative	563.1561	C30H26O11	2	Sap
49	50.6	Unknown	153.0538	—		Sap
50	51.1	Flavanonol Derivative	333.0974	C17H16O7	1	Sap
51	51.3	Flavanonol Derivative	305.0666; 305.0667	C15H12O7	2; 2	Sap; Stem bark
52	51.6	Flavonoid Derivative	287.0551; 287.0550	C15H10O6	2; 2	Sap; Stem bark
53	51.7	Procyanidin II Derivative	563.1555	C30H26O11	1	Sap
54	51.7	Flavonoid Derivative	331.0823	C17H14O7	2	Sap
55	51.8	Flavan-3-ol Derivative	305.1011	C16H16O6	5	Sap
56	52.0	Flavonoid Derivative	301.0709	C16H12O6	2	Sap
57	52.1	Flavanonol Derivative	319.0818	C16H14O7	1	Sap
58	52.2	Flavone Derivative	345.0979	C18H16O7	2	Sap
59	52.4	Quercetin	303.0513	C15H10O7	3	Sap
60	52.4	Flavone Derivative	373.1287; 373.1289	C20H20O7	1; 1	Sap; Stem bark
61	52.8	Unknown	305.2480	C20H32O2	1	Sap
63	53.8	Unknown	192.1406	—		Stem bark