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Geofluids
Volume 2017, Article ID 5783137, 14 pages
https://doi.org/10.1155/2017/5783137
Research Article

Biomarkers and C and S Isotopes of the Permian to Triassic Solid Bitumen and Its Potential Source Rocks in NE Sichuan Basin

1Key Laboratory of Exploration Technologies for Oil and Gas Resources of Ministry of Education, Yangtze University, Wuhan, Hubei 430100, China
2Key Laboratory of Petroleum Resources Research, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China
3College of Earth Sciences, University of Chinese Academy of Sciences, Beijing 100049, China

Correspondence should be addressed to Chunfang Cai; nc.ca.sacggi.liam@fc_iac

Received 16 February 2017; Revised 22 April 2017; Accepted 11 June 2017; Published 13 August 2017

Academic Editor: Timothy S. Collett

Copyright © 2017 Chunfang Cai et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. J. Li, Z. Xie, J. Dai, S. Zhang, G. Zhu, and Z. Liu, “Geochemistry and origin of sour gas accumulations in the northeastern Sichuan Basin, SW China,” Organic Geochemistry, vol. 36, no. 12, pp. 1703–1716, 2005. View at Publisher · View at Google Scholar · View at Scopus
  2. Y. Zhu, J. Wang, F. Hao, H. Zou, and X. Cai, “Geochemical characteristics and origin of natural gases from Xuanhan area, eastern Sichuan,” Scientia Geologica Sinica, vol. 43, no. 3, pp. 518–532, 2008 (Chinese). View at Google Scholar · View at Scopus
  3. X. Jin, C. Pan, S. Yu et al., “Organic geochemistry of marine source rocks and pyrobitumen-containing reservoir rocks of the Sichuan Basin and neighbouring areas, SW China,” Marine and Petroleum Geology, vol. 56, pp. 147–165, 2014. View at Publisher · View at Google Scholar · View at Scopus
  4. T. Borjigen, J. Qin, X. Fu, Y. Yang, and L. Lu, “Marine hydrocarbon source rocks of the Upper Permian Longtan Formation and their contribution to gas accumulation in the northeastern Sichuan Basin, southwest China,” Marine and Petroleum Geology, vol. 57, pp. 160–172, 2014. View at Publisher · View at Google Scholar · View at Scopus
  5. C. Cai, R. H. Worden, S. H. Bottrell, L. Wang, and C. Yang, “Thermochemical sulphate reduction and the generation of hydrogen sulphide and thiols (mercaptans) in Triassic carbonate reservoirs from the Sichuan Basin, China,” Chemical Geology, vol. 202, no. 1-2, pp. 39–57, 2003. View at Publisher · View at Google Scholar · View at Scopus
  6. C. Cai, Z. Xie, R. H. Worden, G. Hu, L. Wang, and H. He, “Methane-dominated thermochemical sulphate reduction in the Triassic Feixianguan Formation East Sichuan Basin, China: Towards prediction of fatal H2S concentrations,” Marine and Petroleum Geology, vol. 21, no. 10, pp. 1265–1279, 2004. View at Publisher · View at Google Scholar · View at Scopus
  7. G. Zhu, S. Zhang, Y. Liang, J. Dai, and J. Li, “Isotopic evidence of TSR origin for natural gas bearing high H2S contents within the Feixianguan Formation of the northeastern Sichuan Basin, southwestern China,” Science in China, Series D: Earth Sciences, vol. 48, no. 11, pp. 1960–1971, 2005. View at Publisher · View at Google Scholar · View at Scopus
  8. C. Cai, K. Li, Y. Zhu et al., “TSR origin of sulfur in Permian and Triassic reservoir bitumen, East Sichuan Basin, China,” Organic Geochemistry, vol. 41, no. 9, pp. 871–878, 2010. View at Publisher · View at Google Scholar · View at Scopus
  9. R. Sassen, “Geochemical and carbon isotopic studies of crude oil destruction, bitumen precipitation, and sulfate reduction in the deep Smackover Formation,” Organic Geochemistry, vol. 12, no. 4, pp. 351–361, 1988. View at Publisher · View at Google Scholar · View at Scopus
  10. T. G. Powell and R. W. Macqueen, “Precipitation of sulfide ores and organic matter: Sulfate reactions at Pine Point, Canada,” Science, vol. 224, no. 4644, pp. 63–66, 1984. View at Publisher · View at Google Scholar · View at Scopus
  11. C. Cai, A. Amrani, R. H. Worden et al., “Sulfur isotopic compositions of individual organosulfur compounds and their genetic links in the Lower Paleozoic petroleum pools of the Tarim Basin, NW China,” Geochimica et Cosmochimica Acta, vol. 182, pp. 88–108, 2016. View at Publisher · View at Google Scholar · View at Scopus
  12. C. Cai, L. Xiang, Y. Yuan et al., “Sulfur and carbon isotopic compositions of the Permian to Triassic TSR and non-TSR altered solid bitumen and its parent source rock in NE Sichuan Basin,” Organic Geochemistry, vol. 105, pp. 1–12, 2017. View at Publisher · View at Google Scholar
  13. C. Cai, C. Zhang, R. H. Worden et al., “Application of sulfur and carbon isotopes to oil-source rock correlation: A case study from the Tazhong area, Tarim Basin, China,” Organic Geochemistry, vol. 83-84, pp. 140–152, 2015. View at Publisher · View at Google Scholar · View at Scopus
  14. C. Cai, L. Xiang, Y. Yuan et al., “Marine C, S and N biogeochemical processes in the redox-stratified early Cambrian Yangtze ocean,” Journal of the Geological Society, vol. 172, pp. 390–406, 2015. View at Publisher · View at Google Scholar · View at Scopus
  15. C. Cai, K. Li, M. Anlai et al., “Distinguishing Cambrian from Upper Ordovician source rocks: Evidence from sulfur isotopes and biomarkers in the Tarim Basin,” Organic Geochemistry, vol. 40, no. 7, pp. 755–768, 2009. View at Publisher · View at Google Scholar · View at Scopus
  16. C. Cai, C. Zhang, L. Cai et al., “Origins of Palaeozoic oils in the Tarim Basin: Evidence from sulfur isotopes and biomarkers,” Chemical Geology, vol. 268, no. 3-4, pp. 197–210, 2009. View at Publisher · View at Google Scholar · View at Scopus
  17. X. D. Fu, J. Z. Qin, Borjigen, and F. X. Wang, “Evaluation on Dalong Formation source rock in the North Sichuan Basin,” Petroleum Geology & Experiment, vol. 32, pp. 566–577, 2010. View at Google Scholar
  18. C. Cai, C. Zhang, H. He, and Y. Tang, “Carbon isotope fractionation during methane-dominated TSR in East Sichuan Basin gasfields, China: A review,” Marine and Petroleum Geology, vol. 48, pp. 100–110, 2013. View at Publisher · View at Google Scholar · View at Scopus
  19. G. Y. Hu, C. Yu, D. Y. Gong, X. W. Tian, and W. Wu, “The origin of natural gas and influence on hydrogen isotope of methane by TSR in the Upper Permian Changxing and the Lower Triassic Feixianguan Formations in northern Sichuan Basin, SW China,” Energy Exploration and Exploitation, vol. 32, no. 1, pp. 139–158, 2014. View at Publisher · View at Google Scholar · View at Scopus
  20. J. X. Dai, Coal-Generating Giant Gasfields and Their Source Rocks in China, Science Publishing House, 2014 (Chinese).
  21. M. Schoell, “Genetic characterization of natural gases,” American Association of Petroleum Geologists Bulletin, vol. 67, no. 12, pp. 2225–2238, 1983. View at Google Scholar · View at Scopus
  22. F. Lorant, A. Prinzhofer, F. Behar, and A.-Y. Huc, “Carbon isotopic and molecular constraints on the formation and the expulsion of thermogenic hydrocarbon gases,” Chemical Geology, vol. 147, no. 3-4, pp. 249–264, 1998. View at Publisher · View at Google Scholar · View at Scopus
  23. Y. Ma, X. Guo, T. Guo, R. Huang, X. Cai, and G. Li, “The Puguang gas field: new giant discovery in the mature Sichuan Basin, southwest China,” American Association of Petroleum Geologists Bulletin, vol. 91, no. 5, pp. 627–643, 2007. View at Publisher · View at Google Scholar · View at Scopus
  24. D. G. Liang, T. Guo, J. Chen, L. Bian, and Z. Zhao, “Some progresses on studies of hydrocarbon generation and accumulation in marine sedimentary regions, southern China (part 1): distribution of four suites of regional marine source rocks,” Marine Origin Petroleum Geology, vol. 13, pp. 1–16, 2008 (Chinese). View at Google Scholar
  25. D. G. Liang, T. Guo, J. Chen, L. Bian, and Z. Zhao, “Some progresses on studies of hydrocarbon generation and accumulation in marine sedimentary regions, southern China (Part 2): geochemical characteristics of four suites of regional marine source rocks, South China,” Marine Origin Petroleum Geology, vol. 14, pp. 1–15, 2009 (Chinese). View at Google Scholar
  26. D. G. Liang, T. L. Guo, L. Z. Bian, J. P. Chen, and Z. Zhao, “Some progresses on studies of hydrocarbon generation and accumulation in marine sedimentary regions, southern China (part 3): controlling factors on the sedimentary facies and development of palaeozoic marine source rocks,” Marine Origin Petroleum Geology, vol. 14, pp. 1–19, 2009. View at Google Scholar
  27. J. Z. Qin, X. D. Fu, and B. Borjigen, “Evaluation of the excellent Triassic to Silurian marine hydrocarbon source rocks in Xuanhan-Daxian area of northeast Sichuan basin,” Petroleum Geology & Experiment, vol. 30, pp. 367–381, 2008 (Chinese). View at Google Scholar
  28. Y. Ma, S. Zhang, T. Guo, G. Zhu, X. Cai, and M. Li, “Petroleum geology of the Puguang sour gas field in the Sichuan Basin, SW China,” Marine and Petroleum Geology, vol. 25, no. 4-5, pp. 357–370, 2008. View at Publisher · View at Google Scholar · View at Scopus
  29. Y. M. Zhu, S. X. Gu, Y. Li, F. Hao, H. Y. Zou, and T. L. Guo, “Biological organic source and depositional environment of over-mature source rocks of Longtan Formation in the Sichuan Basin,” Geochimica, vol. 41, pp. 35–44, 2012 (Chinese). View at Google Scholar
  30. B. Chen and D. C. Pi, “Silurian Longmaxi shale gas potential analysis in middle & upper Yangtze region,” China Petroleum Exploration, vol. 5, pp. 15–19, 2009 (Chinese). View at Google Scholar
  31. C. Zhang, Z. X. M, Y. H. Guo, and W. S. Zhang, “Geochemical characteristics and paleoenvironment reconstruction of the Longmaxi Formation in Southeast Sichuan and Northern Guizhou,” Geological Science and Technology Information, vol. 32, pp. 124–130, 2013. View at Google Scholar
  32. B. Chen and Z. K. Lan, “Lower Cambrian shale gas resource potential in Upper Yangtze region,” China Petroleum Exploration, vol. 5, pp. 10–14, 2009 (Chinese). View at Google Scholar
  33. R. E. Summons and T. G. Powell, “Identification of aryl isoprenoids in source rocks and crude oils: Biological markers for the green sulphur bacteria,” Geochimica et Cosmochimica Acta, vol. 51, no. 3, pp. 557–566, 1987. View at Publisher · View at Google Scholar · View at Scopus
  34. T. C. Brown and F. Kenig, “Water column structure during deposition of Middle Devonian-Lower Mississippian black and green/gray shales of the Illinois and Michigan Basins: A biomarker approach,” Palaeogeography, Palaeoclimatology, Palaeoecology, vol. 215, no. 1-2, pp. 59–85, 2004. View at Publisher · View at Google Scholar · View at Scopus
  35. J. J. Brocks, G. D. Love, R. E. Summons, A. H. Knoll, G. A. Logan, and S. A. Bowden, “Biomarker evidence for green and purple sulphur bacteria in a stratified Palaeoproterozoic sea,” Nature, vol. 437, no. 7060, pp. 866–870, 2005. View at Publisher · View at Google Scholar · View at Scopus
  36. G. R. Sousa Júnior, A. L. S. Santos, S. G. De Lima et al., “Evidence for euphotic zone anoxia during the deposition of Aptian source rocks based on aryl isoprenoids in petroleum, Sergipe-Alagoas Basin, northeastern Brazil,” Organic Geochemistry, vol. 63, pp. 94–104, 2013. View at Publisher · View at Google Scholar · View at Scopus
  37. S. A. Bailey and J. W. Smith, “Improved method for the preparation of sulfur dioxide from barium sulfate for isotope ratio studies,” Analytical Chemistry, vol. 44, no. 8, pp. 1542-1543, 1972. View at Publisher · View at Google Scholar · View at Scopus
  38. J. Espitalié, G. Deroo, and F. Marquis, “Rock-Eval pyrolysis and its application 2,” Revue de l'Institut Francais du Petrole, vol. 40, pp. 563–579, 1985. View at Google Scholar · View at Scopus
  39. S. C. Zhang, A. D. Hanson, J. M. Moldowan et al., “Paleozoic oil-source rock correlations in the Tarim basin, NW China,” Organic Geochemistry, vol. 31, no. 4, pp. 273–286, 2000. View at Publisher · View at Google Scholar · View at Scopus
  40. J. M. Moldowan, K. E. Peters, R. M. K. Carlson, M. Schoell, and M. A. Abu-Ali, “Diverse applications of petroleum biomarker maturity parameters,” Arabian Journal for Science and Engineering, vol. 19, pp. 273–298, 1994. View at Google Scholar
  41. K. E. Peters, C. C. Walters, and J. M. Moldowan, The Biomarker Guide: 2. Biomarkers and Isotopes in Petroleum Exploration and Earth History, Cambridge University Press, Cambridge, UK, 2005.
  42. Y. Sun, S. Xu, H. Lu, and P. Cuai, “Source facies of the Paleozoic petroleum systems in the Tabei uplift, Tarim Basin, NW China: Implications from aryl isoprenoids in crude oils,” Organic Geochemistry, vol. 34, no. 4, pp. 629–634, 2003. View at Publisher · View at Google Scholar · View at Scopus
  43. C. Zhang, Y. Zhang, and C. Cai, “Aromatic isoprenoids from the 25–65 Ma saline lacustrine formations in the western Qaidam Basin, NW China,” Organic Geochemistry, vol. 42, no. 7, pp. 851–855, 2011. View at Publisher · View at Google Scholar · View at Scopus
  44. M. P. Koopmans, S. Schouten, M. E. L. Kohnen, and J. S. Sinninghe Damsté, “Restricted utility of aryl isoprenoids as indicators for photic zone anoxia,” Geochimica et Cosmochimica Acta, vol. 60, no. 23, pp. 4873–4876, 1996. View at Publisher · View at Google Scholar · View at Scopus
  45. S. Zhang, H. Huang, J. Su, M. Liu, and H. Zhang, “Geochemistry of alkylbenzenes in the Paleozoic oils from the Tarim Basin, NW China,” Organic Geochemistry, vol. 77, pp. 126–139, 2014. View at Publisher · View at Google Scholar · View at Scopus
  46. J. S. Sinninghe Damsté, F. Kenig, M. P. Koopmans et al., “Evidence for gammacerane as an indicator of water column stratification,” Geochimica et Cosmochimica Acta, vol. 59, no. 9, pp. 1895–1900, 1995. View at Publisher · View at Google Scholar · View at Scopus
  47. D. E. Canfield, R. Raiswell, J. T. Westrich, C. M. Reaves, and R. A. Berner, “The use of chromium reduction in the analysis of reduced inorganic sulfur in sediments and shales,” Chemical Geology, vol. 54, no. 1-2, pp. 149–155, 1986. View at Publisher · View at Google Scholar · View at Scopus
  48. G. E. Claypool, W. T. Holser, I. R. Kaplan, H. Sakai, and I. Zak, “The age curves of sulfur and oxygen isotopes in marine sulfate and their mutual interpretation,” Chemical Geology, vol. 28, pp. 199–260, 1980. View at Publisher · View at Google Scholar · View at Scopus
  49. S. H. Bottrell, R. J. G. Mortimer, I. M. Davies, S. Martyn Harvey, and M. D. Krom, “Sulphur cycling in organic-rich marine sediments from a Scottish fjord,” Sedimentology, vol. 56, no. 4, pp. 1159–1173, 2009. View at Publisher · View at Google Scholar · View at Scopus
  50. A. Amrani and Z. Aizenshtat, “Mechanisms of sulfur introduction chemically controlled: δ34S imprint,” Organic Geochemistry, vol. 35, no. 11-12, pp. 1319–1336, 2004. View at Publisher · View at Google Scholar · View at Scopus
  51. A. Amrani, W. Said-Ahamed, M. D. Lewan, and Z. Aizenshtat, “Experiments on δ34S mixing between organic and inorganic sulfur species during thermal maturation,” Geochimica et Cosmochimica Acta, vol. 70, no. 20, pp. 5146–5161, 2006. View at Publisher · View at Google Scholar · View at Scopus
  52. M. M. Joachimski, C. Ostertag-Henning, R. D. Pancost et al., “Water column anoxia, enhanced productivity and concomitant changes in δ13C and δ34S across the Frasnian-Famennian boundary (Kowala - Holy Cross Mountains/Poland),” Chemical Geology, vol. 175, no. 1-2, pp. 109–131, 2001. View at Publisher · View at Google Scholar · View at Scopus
  53. R. D. Pancost, K. H. Freeman, A. D. Herrmann, M. E. Patzkowsky, L. Ainsaar, and T. Martma, “Reconstructing Late Ordovician carbon cycle variations,” Geochimica et Cosmochimica Acta, vol. 105, pp. 433–454, 2013. View at Publisher · View at Google Scholar · View at Scopus