Material Exchange and Migration between Pore Fluids and Sandstones during Diagenetic Processes in Rift Basins: A Case Study Based on Analysis of Diagenetic Products in Dongying Sag, Bohai Bay Basin, East China

Meng, W.; Zeng, J. H.; Cao, Z.; Song, G. Q.; Wang, Y. S.; Teng, J. L.; Guo, Z.

doi:https://doi.org/10.1155/2018/1653632

Geofluids

On this page

Abstract Introduction Methods Results Discussion Conclusions Conflicts of Interest Acknowledgments References Copyright Related Articles

Special Issue

Innovative Research for Geofluid Flow and Solute Transport in Subsurface from Pore to Terrestrial Scales

View this Special Issue

Research Article | Open Access

Volume 2018 | Article ID 1653632 | https://doi.org/10.1155/2018/1653632

Material Exchange and Migration between Pore Fluids and Sandstones during Diagenetic Processes in Rift Basins: A Case Study Based on Analysis of Diagenetic Products in Dongying Sag, Bohai Bay Basin, East China

W. Meng,^1,2J. H. Zeng ,^1,2Z. Cao,^1,2G. Q. Song,³Y. S. Wang,³J. L. Teng,^1,2and Z. Guo^1,2

Academic Editor: Jet-Chau Wen

Received30 Jun 2017

Revised15 Dec 2017

Accepted28 Dec 2017

Published15 Feb 2018

Abstract

The exchange and migration of basin materials that are carried by pore fluids are the essence of diagenesis, which can alter physical properties of clastic rocks as well as control formation and distribution of favorable reservoirs of petroliferous basins. Diagenetic products and pore fluids, resulting from migration and exchange of basin materials, can be used to deduce those processes. In this study, 300 core samples from 46 wells were collected for preparation of casting thin sections, SEM, BSE, EDS, inclusion analysis, and isotope analysis in Dongying Sag, Bohai Bay Basin, East China. Combined with geochemical characteristics of pore fluids and geological background of the study area, the source and exchange mechanisms of materials in the pore fluids of rift basins were discussed. It was revealed that the material exchange of pore fluids could be divided into five stages. The first stage was the evaporation concentration stage during which mainly , , and precipitated as high-Mg calcites. Then came the shale compaction stage, when mainly and from shale compaction water precipitated as calcites. The third stage was the carboxylic acid dissolution stage featured by predominant dissolution of plagioclases, during which and entered pore fluids, and Si and Al also entered pore fluids and then migrated as clathrates, ultimately precipitating as kaolinites. The fourth stage was the organic stage, mainly characterized by the kaolinization of K-feldspar as well as dissolution of metamorphic lithic fragments and carbon cements. During this stage, , , , , , and entered pore fluids. The fifth stage was the alkaline fluid stage, during which the cementation of ferro-carbonates and ankerites as well as illitization or chloritization of kaolinites prevailed, leading to the precipitation of , , , , and from pore fluids.

1. Introduction

Pore fluids mainly refer to all fluids that occupy and pass through the pore space of sedimentary basins [1, 2]. During the burial process, basin materials could be loaded and redistributed by pore fluids. Those processes could lead to regularly distributed diagenetic products in basins [3]. Formation and evolution of diagenetic products could result in preservation or destruction of primary pores as well as formation and transformation of secondary pores, which could significantly influence the formation and occurrence of effective reservoirs in the deep part of petroliferous basins [4–16]. Previous studies mainly highlighted evolution of physical properties of clastic rocks and primarily investigated diagenetic facies and sequences based on sedimentological and petrological analyses [11, 17–26]. However, insufficient attention was paid to the nature of diagenesis, namely, the exchange and migration of basin materials loaded by pore fluids. Meanwhile, many controversies arose concerning the formation mechanism of secondary pores, which further obscured prediction of distribution of secondary pores and effective reservoirs [5, 14, 23, 27–34]. Therefore, it should be critical to figure out the mechanism of basin material exchange and migration during the diagenetic process so as to analyze the formation and distribution of diagenetic products and favorable sandstone reservoirs.

During diagenetic process, matrix of clastic rocks could be transformed or dissolved, and materials might partly or totally enter into pore fluids as ions or complexes. Solutes (ions or complexes) carried by pore fluids could be deposited as cements under appropriate geological conditions. In these processes, compositions of clastic rocks and chemical properties of pore fluids could be changed. These changes could be used to infer material exchange and migration mechanisms during diagenesis.

2. Geological Setting

Dongying Sag is a subtectonic unit in the southeastern of Jiyang Depression, Bohai Bay Basin (Figure 1) [35]. It can be further subdivided into six secondary tectonic zones, known as Northern Steep Slope Zone, Lijin Subsag, Minfeng Subsag, Central Anticline Zone, Niuzhuang Subsag, and Southern Gentle Slope Zone (Figure 1) [35].

There are mainly three sets of successions in the Dongying Sag, namely, Paleogene, Neogene, and Quaternary. The Paleogene mainly comprises Kongdian (Ek), Shahejie (Es), and Dongying (Ed) Formations; the Neogene Guantao (Ng) and Minghuazhen (Nm) Formations; and the Quaternary Pingyuan (Qp) Formation (Zhai and He 1993) [36]. There is a main regional unconformity serving as the boundary between Ed and Ng Formations (Figure 2) (Zhai and He 1993) [35, 36]. Shahejie Formation can be subdivided into four members, namely, Es4, Es3, Es2, and Es1, from base to top [36]. This study focused on the Es4 and Es3 members.

Es4 consists of gray and dark-gray mudstones, gypsum and halite, interbedded nearshore subaqueous fan sandstones, and sublacustrine fan sandstones deposited in semideep and deep lacustrine environments, which are mainly located in the Northern Steep Slope Zone. The lower submember of Es3 (Es3³) was deposited in semideep and deep lacustrine environments, dominated by lacustrine oil shales, dark-gray mudstones, calcareous mudstones, and subaqueous (sublacustrine) fan sandstones in terms of lithology. The middle submember of Es3 (Es3²) consists of gray to dark-gray mudstones, calcareous mudstones, subaqueous (sublacustrine) fan sandstones, and delta sandstones deposited in semideep and deep lacustrine environments. The upper submember of Es3 (Es3¹) is dominated by deltaic sandstones.

3. Samples and Methods

A total of 1472 thin sections were collected, which were prepared from the Es core samples in the Dongying Sag by Geological Scientific Research Institute of China Sinopec Shengli Oilfield Company, where 1423 data about Es formation water chemical composition were also collected.

A total of 300 blue epoxy resin-impregnated thin sections were prepared for diagenesis analysis using the Es drill cores of 46 wells in Dongying Sag. This study focused on the type, occurrence, content, and contact metasomatic relationship of diagenetic products. With at least 300 points, estimations of component contents by point accounting can be more reliable with a standard deviation less than 5.5%. 40 out of 300 samples were implemented with EBSD, SEM, and EDX analysis in order to investigate chemical characteristics of authigenic kaolinites and carbon cements. 34 out of 300 samples showed only one type of carbon cements, and they were selected for analysis of δ¹³/ and δ¹⁸/. The collection of carbon cements from these samples was taken at the Institute of Mineral Resources and Regional Geology of Hebei Province, while the measurement of δ¹³/ and δ¹⁸/ was completed using Gas Isotope Ratio Mass Spectrometry (MAT 253) at Chinese Academy of Geological Sciences. Fluid inclusion analysis was carried out on 14 samples, which were prepared as doubly polished sections with approximate thicknesses of 100 mm for fluid inclusion petrographic analysis and thermometric measurement. Microthermometry of aqueous inclusions was conducted using calibrated Linkam-350, during which the homogenization temperature (Th) was obtained by cycling and Th measurements were completed with a heating rate of 10°C/min when the temperature was lower than 70°C, and 5°C/min when the temperature exceeded 70°C. The precision of measured Th was within °C. A total of 592 data concerning bulk rock and clay mineral analyses were collected from Geological Scientific Research Institute of China Sinopec Shengli Oilfield Company, which were mainly to identify the distribution of contents of different clay minerals.

4. Results

4.1. Detrital Composition of Es Sandstones

Es sandstones in Dongying Sag are medium to fine grained arkoses and lithic arkoses (av. Q_47.4F_33.8L_18.7; Figure 3). They are poorly to moderately sorted and subangular, with the matrix content of 1.7–13.6%. It was revealed by thin section observation that the quartz grains in those sandstones (av. 39.8%) were mainly monocrystalline quartz (av. 39.0%) and, less commonly, polycrystalline quartz (av. 0.8%). Es3 sandstones had the highest content of quartz grains (av. 43.2%), while Es1 sandstones had the lowest (av. 39.5%). The feldspar particles in those sandstones (av. 15.1%) were mainly K-feldspar (av. 9.0%) and, less commonly, plagioclase (av. 6.1%). Es1 sandstones had the highest content of feldspar particles (av. 20.2%), while Es3 sandstones had the lowest (av. 12.2%). The content range of lithic fragments in those sandstones was relatively large, 1.7–53.2%. Lithic fragments in Es sandstones were all dominated by metamorphic lithic fragments. The difference is that the amount of igneous and sedimentary lithic fragments was relatively higher in the Es1 and Es2 sandstones, but relatively lower in Es3 and Es4 sandstones (Table 1).

During the burial process, the interaction between pore fluids and grains in sandstones could result in the changes of type and content of clastic particles. In the sandstones with depth less than 3200 m, the content of quartz particles increased significantly, and the content of feldspar grains decreased dramatically, with the increase of depth. However, such trend was opposite in sandstones with depth more than 3200 m. Moreover, it was found that the content of lithic fragments kept relatively unchanged until the depth reached 2800 m, after which it sharply decreased with depth (Figure 4). In addition, in the depth less than 2800 m, the proportion of different lithic fragments in total lithic fragments was relatively constant, which, however, changed when the depth reached 2800 m. To be specific, the proportion of igneous lithic fragments increased with depth, while that of metamorphic lithic fragments decreased (Figure 4). Similarly, the proportion of anorthose grains in total feldspar grains declined with depth, while that of K-feldspar grains increased, when the depth was less than 2800 m (Figure 4). However, in sandstones with depth from 2800 m to 3200 m, the trend was opposite, which meant increasing anorthose grains and decreasing K-feldspar grains with depth. As for the sandstones buried deeper than 3200 m, contents of anorthose and K-feldspar rarely changed (Figure 4).

4.2. Chemical Characteristics of Formation Water in Dongying Sag

The major elements of formation water were found to change regularly with depth in Dongying Sag. The contents of Na⁺ and K⁺ increased in the depth ranges of 2200 m–2500 m and 2800 m–3400 m, respectively, reaching the maximum at the depth of 3400 m and then slightly declining. The content of increased with depth from 2200 m, achieving the maximum and remaining stable after the depth exceeded 2500 m. The content of greatly increased with depth in the range of 2200 m–3200 m, reaching the maximum at 3200 m and then dropping greatly with depth. The content of increased in the range of 2500 m–3000 m, achieving the maximum at 3000 m and then decreasing greatly with depth. The content of increased with depth after the depth exceeded 2800 m (Figure 5).

4.3. Morphological, Geochemical, and Distribution Features of Diagenetic Products in Es Sandstones

Pore fluids in Es sandstones experienced multiphase material exchange and migration, leading to the formation and evolution of diagenetic products. These diagenetic products mainly included carbonate cements; quartz cements; aluminosilicate minerals such as kaolinite, illite, and chlorite; opaque minerals such as pyrite; dissolution pores of unstable particles (feldspar and lithic fragments) and carbonate cements. The contents of different diagenetic products varied greatly in the sandstones of different members of Es. The contents of carbonate cements were relatively higher in Es3 and Es4 sandstones (av. 13.5% and av. 13.4%, resp.), while that in Es1 sandstones was relatively lower (av. 8.1%). The carbonate cements in Es1 sandstones were mainly calcite; those in Es2 sandstones calcite, dolomite, ferrocalcite, and ankerite; those in Es3 sandstones mainly ferrocalcite and ankerite; and those in Es4 sandstones mainly dolomite and ankerite. Quartz cements were mainly observed in sandstones of Es2, Es3, and Es4, with rare observations of them in Es1 sandstones. Authigenic kaolinites were mainly found in Es2 and Es3 sandstones, while few of them were observed in sandstones of Es1 and Es4. Feldspar dissolution pores were predominantly in sandstones of Es2, Es3, and Es4, and they were most developed in Es3 sandstones. Es3 and Es4 sandstones were main hosts to carbonate cement dissolution pores, and Es4 sandstones had the largest amount of carbonate cement dissolution pores (Table 1).

4.3.1. Distribution and Geochemical Features of Carbonate Cements with Different Morphologies

There were mainly four stages of carbonate cements with different morphologies in the study area. Carbonate cements of the first stage (Cc1) were generally isopachous on the surface of particles (Figures 6(a) and 6(b)), occurring in sandstones with depth ranging from 1700 m to 3600 m (Figure 7). They were only observed in a few sandstone samples. Carbonate cements of the second stage (Cc2) were mainly medium-coarse crystalline calcite, filling the primary pores which were not obviously affected by compaction. This type of carbonate cements was generally on the outer side of Cc1 (Figures 6(a), 6(b), and 6(c)), and they usually occurred in sandstones with depth ranging from 1700 m to 3600 m, concentrated in the depth range of 1700–2800 m. From 2800 m to 3600 m, Cc2 was obviously dissolved (Figure 7). Carbonate cements of the third stage (Cc3) filled in residual primary pores after compaction as well as feldspar dissolution pores (Figures 6(e) and 6(f)). They generally occurred in the sandstones with depth ranging from 2000 m to 3600 m, concentrated in the range of 2100 m to 2700 m. The content of Cc3 decreased greatly with depth once the depth reached 2700 m (Figure 7). Carbonate cements of the fourth stage (Cc4) were euhedral fine crystalline ferrocalcites and ankerites, lying on the outer part of kaolinization feldspar or secondary pores dissolved by Cc3 (Figures 6(g) and 6(h)). They were mainly found in the sandstones with the depth over 3100 m, and their content increased greatly with depth (Figure 7).

(a)

(b)

(c)

(d)

(e)

(f)

(g)

(h)

Figure 6

Morphological features of diagenetic products in Es of Dongying Sag. ((a) Well Shi127 2180.8 m, micritic high-Mg calcite (Cc1) and medium-coarse calcites (Cc2); (b) Well Shi127 2180.8 m, local amplification of (a), Cc1, Cc2, and Py1; (c) Well Xin 154 2960.50 m, Cc2 partly filled in primary pores and the outer part was filled by K1; (d) Well Xin 154, 2960.50 m, local amplification of (c); (e) Well Niu110, 3004.80, dissolution of Cc3 and fillings in the outer of Q1; (g) Well FS1, 4322.40 m, Cc4 occurred in the outer of kaolinization feldspar (K2); (h) Well FS1, 4322.40 m, local amplification of (g)).

Cc1 was mainly micritic high-Mg calcite (CaCO₃ 71–79%; MgCO₃ 15–23%; FeCO₃ 2–5%; MnCO₃ 0–2%) (Figure 8). It was difficult to obtain isotope data from Cc1, due to its low content. Cc2 was mainly calcite (CaCO₃ 91–100%; MgCO₃ 0–5%; FeCO₃ 0–5%; MnCO₃ 0–2%) (Figure 8), with δ¹³/ values from +1.60 to +3.50 (av. 2.76) and δ¹⁸/ values from −12.40 to −9.10 (av. −10.33) (Figure 9). The chemical composition of Cc3 was complicated (CaCO₃ 43–97%; MgCO₃ 0–54%; FeCO₃ 1–11%; MnCO₃ 0–4%) (Figure 8), and it had a relatively wide range of δ¹³/ values from −6.60 to +4.30 (av. 1.03) and δ¹⁸/ values from −13.90 to −5.10 (av. −11.00) (Figure 9). Cc4 had higher contents of Fe and Mn (CaCO₃ 38–83%; MgCO₃ 3–53%; FeCO₃ 6–14%; MnCO₃ 0–7%) (Figure 8), with the δ¹³/ values from −6.40 to −3.30 (av. −4.85), and δ¹⁸/ values from −15.90 to −13.50 (av. −14.70) (Figure 9).

4.3.2. Distribution of Quartz Cementation with Different Morphologies and Fluid Inclusions

Three types of quartz cementation could be identified according to the morphology, respectively, in forms of quartz overgrowth, micro- to mega- crystalline pore-filling quartz cements, and fracture-filling quartz cements (Figure 10). The first stage of quartz cements (Q1) was mainly in forms of quartz overgrowth, and the outer part was filled by Cc3 (Figures 6(e), and 6(f), 13(a), 13(b), and 13(c)). Q1 had a depth ranging from 2000 m to 3600 m, mainly concentrated in 2500–3600 m (Figure 11). The second stage of authigenic quartz (Q2) was mainly euhedral quartz and fracture-filling quartz, filled in the outer part or cutting Q1 (Figures 10(a) and 10(b)). Q2 was in a depth ranging from 2500 m to 3600 m and was mainly concentrated in 2900 m–3600 m (Figure 11).

(a)

(b)

The homogenization temperature of inclusions in Q1 ranged from 70°C to 115°C and that in Q2 from 110°C to 130°C (Figures 10(a), 10(b), and 12).

(a)

(b)

(c)

(d)

(e)

(f)

(g)

(h)

Figure 13

Morphological features of diagenetic products in Es of Dongying Sag. ((a) Well He 142, 3064.83 m, wormlike authigenic kaolinites (K1) intergrew with quartz overgrowths; (b) Well He 142, 3064.83 m, local amplification of (a), K1 intergrew with quartz overgrowths; (c) Well Xin 154, 2938.56 m, K1 filled in secondary pores; (d) Well Xin 154, 2938.56 m, local amplification of (c), wormlike authigenic kaolinite (K1); (e) Well N105, 3096.2 m, disordered authigenic kaolinite distributed on the surface of K-feldspars (K2); (f) Well N105, 3096.2 m, local amplification of (e); (g) Well XX161, 3272.5 m, illitization of K1 and K2; (h) Well S106, 3398.70 m, Cc4 and Py2).

4.3.3. Distribution and Geochemical Features of Authigenic Kaolinites with Different Morphologies

The morphological features of authigenic kaolinites were comprehensively studied by thin section observation and SEM analysis. The authigenic kaolinites in the study area could be classified into two categories based on their morphologies. The first kind of authigenic kaolinite (K1) was featured by predominant scaly-vermiform shape under the microscope (Figures 6(c), 13(a), and 13(c)) as well as single crystals characterized by closely packed, thin complete pseudohexagonal flakes under SEM. The wormlike or book-like aggregation of K1 (Figures 6(d), 13(b), and 13(d)) was mainly in feldspar dissolution pores and residual primary pores which had been partially filled by Cc2 (Figure 6(c)). K1 intergrew with quartz overgrowth (Q1) (Figure 13(b)), and it could be replaced by illites (Figure 13(g)). K1 had a wide range of distribution from 1700 m to 3600 m and was mainly concentrated in the range of 2600 m to 3200 m (Figure 14). Under microscopes, the second kind of authigenic kaolinite (K2) was mainly distributed on the surface of feldspar particles, showing disordered scales, and the aggregate of K2 presented in the shape of feldspar particles (Figures 6(g) and 13(e)). Under SEM, single crystals of K2 were flake-shaped, thin, and loosely arranged. These crystals had curved edges and imperfect forms (Figure 13(f)). K2 was mainly in dissolution pores within Cc3, with the outer side filled by Cc4 (Figures 6(g) and 6(h)). Part of K2 intergrew with authigenic quartz (Q2). K2 was mainly in the range of 2600 m to 3600 m and was mainly concentrated in the range of 2900–3200 m (Figure 14).

K1 mainly contained three elements, namely, Al, Si, and O, while K2 had additional trace elements such as K (av. 1.01%) and Fe (av. 1.89%) (Table 2).

4.3.4. Morphological and Distribution Characteristics of Other Water-Rock Reaction Products

In the sandstones with depth less than 3200 m, contents of illite (less than 5%) and chlorite (less than 2%) were relatively low and stable, while that of kaolinite increased significantly with depth (Figure 15). However, when the burial depth reached 3200 m, the contents of illite and chlorite began to increase with depth, while that of kaolinites dropped (Figure 15), which was attributed to the transformation of kaolinites into illite and chlorite as observed under SEM (Figures 6(h), 13(g)).

There were mainly two kinds of authigenic pyrites in Es sandstones, Dongying Sag. The first kind of pyrites (Py1) occurred as single particles in the inner side of Cc1 (Figure 6(b)), while the other kind (Py2) occurred as framboids around Cc4 (Figure 13(h)).

5. Discussion

5.1. Formation Timing and Diagenetic Sequence of Major Diagenetic Products

The δ¹⁸/ value of carbonate cements was controlled by formation temperatures and δ¹⁸/ values of pore fluids. It was necessary to firstly determine δ¹⁸/ values of pore when using δ¹⁸/ value of carbonate cements to calculate the formation temperature [37, 48]. During diagenetic process, material exchanges between particles and pore fluids (mainly feldspar dissolution) led the δ¹⁸/ value of pore fluids to be heavier [35, 39, 43]. The δ¹⁸/ value of pore water at eodiagenetic stage was about −4.8, which became heavier, reaching about −3 due to significant feldspar dissolution [35, 49]. In other words, Cc1 and Cc2, which were clearly anterior to feldspar dissolution, precipitated from pore fluids with δ¹⁸/ value of −4.8 (Figures 6(a), 6(b), and 6(c)), while Cc3 and Cc4, which were clearly posterior to feldspar dissolution, precipitated from pore fluids with δ¹/ value of −3 (Figures 6(e), 6(f), 6(g), and 6(h)). The chemical composition of Cc1 was similar to micritic high-Mg calcite formed during syndiagenetic stage in shales (Figure 8). Thus, it could be deduced that Cc1 should be formed during syndiagenetic stage as well. The δ¹⁸/ values of Cc2 ranged from −12.40 to −8.20, indicating the formation temperature range of Cc2 to be 33.2–58.1°C. The δ¹⁸/ value of Cc3 ranged from −13.90 to −5.10, suggesting the formation temperature range of Cc3 to be 50.0–115.2°C. Similarly, the δ¹⁸/ of Cc4 ranged from −15.90 to −13.50, implying the formation temperature range of Cc3 to be 130–170°C [37, 48].

The homogenization temperatures of brine inclusions in Q1 and Q2, respectively, ranged from 70°C to 115°C and from 110°C to 130°C (Figures 10(a), 10(b), and 12).

K1, which was posterior to cementation of Cc1 and Cc2 and prior to Cc3, generally presented as intergrowth of Q1 (Figures 6(c), 6(h), and 13(b)), indicating the formation temperature range of K1 to be 70–115°C. K2, which was posterior to cementation of Cc3 and anterior to Cc4, generally occurred as intergrowth of K2, implying the formation temperature of K1 to range from 115°C to 130°C.

Chlorite and illite were synchronous with or posterior to Cc4 and were concentrated in depth more than 3200 m (>140°C), suggesting that they were the latest diagenetic products (Figure 6(h), and 15).

Py1 was generally associated with Cc1 (Figure 6(b)) and Py2 with Cc4 (Figure 13(h)).

Finally, the diagenetic sequence of sandstones in Es, Dongying Sag, was concluded as shown in Figure 16.

5.2. Material Sources of Main Diagenetic Products

5.2.1. Material Sources of Carbonate Cements

Cc1 could be directly precipitated out from sedimentary waters during syndiagenetic stage [51]. The δ¹³/ and δ¹⁸/ values of Cc2 in sandstones ranged from 1.60 to 3.50 and from −12.4 to −8.2, respectively, indicating Cc2 to be typical lacustrine carbonate cements (Figure 9). Cc2 mainly occurred in sandstones which were proximal to sand-shale interfaces [52–55]. Formation temperatures of Cc2 were within the range of 33.2–58.1°C, which corresponded to the depth range of 500–1000 m [50]. In this depth range, the porosity of mudstones declined from 60% to 10–20% because of compaction, leading to discharge of a large amount of sedimentary water into sandstones [13, 53, 55–58]. Ca²⁺ and were rich in those fluids, and they were main material sources for Cc2.

The δ¹³/ and δ¹⁸/ values of Cc3 in sandstones mainly ranged from −6.6 to 4.3 and from −13.9 to −5.1, respectively, which indicated the influence of organic carbon on part of Cc3 (Figure 9). The chemical composition of Cc3 was complex (Figure 8). Vertically, Cc3 was mainly concentrated in transitional areas of normal-pressure and overpressure zones (Figure 7; [59]). Laterally, distribution of Cc3 was controlled by main faults [59]. All of these proved that hydrothermal fluids that flowed through the faults provided part of the material sources for Cc3. Formation temperatures of Cc3 ranged from 50.0°C to 115.2°C, in the range of which carboxylic acids were formed and expelled from organic matters into mudstones [13, 60]. The presence of carboxylic acids led to dissolution of plagioclases (mainly Ca-feldspars and Na-feldspars) and also caused the entrance of Ca²⁺ and Na⁺ into pore fluids (Figures 4, 6(f), and 5). During this time, no obvious dissolution of Cc1 and Cc2 occurred (Figure 6(c), Figure 7; [61]). The Ca²⁺, Mg²⁺, and (partly influenced by organic carbon) in hydrothermal fluids and Ca²⁺ (dissolved by Ca-feldspar) and (sedimentary carbon) in formation water were material sources for Cc3 [59, 62, 63].

The δ¹³/ and δ¹⁸/ values of Cc4 in sandstones ranged from −6.4 to −3.3 and from −15.9 to −13.5, respectively, indicating the significant influence of organic carbon on Cc4 (Figure 9). Cc4 was mainly concentrated in sandstones with depth over 3200 m (Figure 7). At this depth (corresponding temperature > 120°C), cracking of carboxylic acids and organic matters resulted in a large amount of CO₂, which was transformed to in the following diagenetic processes [13, 27, 35, 50, 54, 60]. Carbonate cements (mainly Cc2 and Cc3) were dissolved obviously, leading to the entrance of Ca²⁺ and into pore fluids (Figures 6(e), and 7; [64]). The dissolution of metamorphic lithic fragments promoted the entrance of Fe²⁺ and Mg²⁺ into pore fluids (Figure 4). All of these materials were the sources for precipitation of Cc4.

5.2.2. Material Sources of Authigenic Quartz

Precipitation of authigenic quartz occurred in the diagenesis process (Figure 16) as the concentration of SiO₂ (aq) (<100 ppm) in lake waters was too low for authigenic quartz [11]. There were no external sources of free SiO₂ for sandstones of Es in Dongying Sag [35]. However, quartz dissolution at grain contacts and dissolution or transformation of feldspars in sandstones could be possible internal source for authigenic quartz. Contact relationships of Es sandstones were mainly point contact, with a small proportion of line contact (Figures 6(a), 6(c), 13(a), and 13(c)). No much free SiO₂ (aq) was released during this process. Therefore, the depth distribution range of authigenic quartz was identical to that of feldspar (Figures 4 and 11). In the thin sections and SEM, dissolution and transformation of feldspars associated with authigenic quartz could be identified (Figure 13(b)). Therefore, the most likely source of authigenic quartz might be the internal dissolution and transformation of feldspars.

5.2.3. Material Sources of Authigenic Kaolinites

The concentrations of SiO₂ (aq) (<100 ppm) and Al³⁺ (<10 ppm) were too low to be effective material source for authigenic kaolinites [11]. However, there were a lot of authigenic kaolinites in the sandstone reservoirs of Es in Dongying Sag. Vertically, the content of authigenic kaolinites was negatively correlated with feldspar content (Figures 4 and 14; [35, 47, 65]). In other words, the dissolution of aluminosilicate minerals (mainly feldspars) was important material source for authigenic kaolinites [9, 66–71].

K1 was featured by perfect crystal forms and exclusive Al, Si, and O ions, indicating those authigenic kaolinites to be precipitated directly from pore fluids [72, 73]. High content of K1 often appeared in samples with no or little feldspar dissolution, while low content of K1 was common in samples with a large amount of feldspar dissolution [74], which indicated the significant amount of free Si⁴⁺ and Al³⁺ which are released by dissolution of feldspar and then migration in pore fluids during the formation of K1. In the deep burial environment, pore fluids flowed slowly, dissolving only a small amount of free Si⁴⁺ and Al³⁺. Therefore, it was hard for silicon and aluminum to migrate in the form of Si⁴⁺ and Al³⁺ [75–77]. Considering the formation temperature (60–115°C) of K1, which was suitable for formation and preservation of carboxylic acids, it was suggested that complex reaction between carboxylic acids and cations of Si⁴⁺ and Al³⁺ could induce the dissolution of feldspars [27, 35, 78]. The Si⁴⁺ and Al³⁺ migrated over long distances in the form of clathrates and precipitated as authigenic kaolinite (K1) in the proper geological environment.

K2 was featured by imperfect crystal forms and more other ions (like Fe and K) besides Al, Si, and O, which indicated these authigenic kaolinites to be products of feldspar transformation [72, 73]. Pore fluids rich in CO₂ led to the occurrence of a large amount of H⁺ and in pore fluids at the depth of 2800–3200 m (Figure 5). Under this situation, K-feldspar particles were totally or partly transformed into K2 and Q2 [5, 61].

5.2.4. Material Sources of Other Water-Rock Reaction Products

In the depth range of 2800–3200 m, kaolinization of K-feldspars and dissolution of metamorphic lithic fragments led to concentration of K⁺, Fe²⁺, and Mg²⁺ in pore fluids. At the same time, a large amount of H⁺ was consumed. All of these led authigenic kaolinites (K1 and K2) to be unstable [56, 79]. Once the depth was above 3200 m (130°C), K1 and K2 were partly or totally transformed into illites and chlorites (Figures 6(h), 13(g), and 15).

5.3. Material Exchanges between Pore Fluids and Rocks during Diagenetic Processes

The material exchange between pore fluids and rocks was mainly controlled by geochemical and physical properties of pore fluids. During diagenetic processes, fluids, which were recharged by mudstones and flowed along faults, could lead to obvious changes of properties of pore fluids. Based on analyses of changes of detrital composition, geochemical features of pore fluids, and material sources of diagenetic products in Es of Dongying Sag, this study divided the material exchanges during diagenetic processes in rift basins into five stages.

Stage 1. Certain amounts of Ca²⁺, Mg²⁺, Fe³⁺, , and were existent in lake waters of the Paleogene in Dongying Sag [51, 80, 81]. During syngenetic stage, evaporation of lake water led to concentration of ions, and they precipitated as a small amount of micritic high-Mg calcite [51, 54, 81–83]. At the same time, activities of sulfate-reducing bacteria led to the change of Fe³⁺ and to Fe²⁺ and S^2-, respectively. Part of Fe²⁺ entered into crystal lattices of Cc1 as heteroatom, while the remaining part was combined with S^2-, precipitating as Py1 associated with Cc1. In this stage, mainly Mg²⁺, Ca²⁺, , Fe²⁺, and , which originated from lake waters, entered sandstones in the forms of Cc1 and Py1.

Stage 2. In the depth range of 500–1000 m (paleotemperature of 30–50°C), concentrated compaction waters rich in Ca²⁺ and entered into sandstones from mudstones, resulting in the formation of Cc2 in sandstones close to the sandstone-mudstone interfaces. During this stage, Ca²⁺ and from compaction waters entered into sandstones and precipitated as Cc2.

Stage 3. In the depth range of 1250–2800 m (paleotemperature of 60–120°C), waters rich in carboxylic acids enter into sandstones from mudstones, leading to dissolution of plagioclases. In this process, Na⁺ and Ca²⁺ entered into pore fluids and were well preserved. Si⁴⁺ and Al³⁺ were complexed with carboxylic acids, and these complexes migrated in pores and then precipitated as K1 and Q1 in the proper geological conditions. In this stage, activation of faults could cause the blend of hydrothermal fluids (upwelling through faults, rich in Mg²⁺, Ca²⁺, and partly organic source ) and formation waters (in place, rich in Ca²⁺), leading to the precipitation of Cc3.

Stage 4. In the depth range of 2800–3200 m (paleotemperature of 120–140°C), CO₂ with organic sources, formed by cracking of organic matters and carboxylic acids, entered the pore fluids and was preserved as H₂CO₃ (). The presence of organic source H₂CO₃ () led to the transformation of K-feldspars and the dissolution of Cc2, Cc3, and metamorphic lithic fragments. During transformation of K-feldspars, a large amount of K⁺ entered into pore fluids and was well preserved. The dissolution of Cc2 and Cc3 led to the entrance of a large amount of sedimentary source Ca²⁺ and into pore fluids, which were then well preserved. The dissolution and transformation of metamorphic lithic fragments led to the entrance of Fe²⁺ and Mg²⁺ into pore fluids and subsequently good preservation (Figure 5). The transformation of K-feldspars led to the formation of K2 and Q2. In this process, K⁺, Ca²⁺, , Mg²⁺, Fe²⁺, and Mn²⁺ entered pore fluids.

Stage 5. In the depth above 3200 m (paleotemperature above 140°C), less or no formation of organic CO₂ resulted in the transformation of pore fluids into alkaline. In this depth range, the contents of Na⁺, K⁺, Ca²⁺, and significantly declined (Figure 5), which might be due to the precipitation of Cc4 as well as illitization and chloritization of K. During this process, because of declining of H⁺, transformed to . This caused (dissolution of Cc2 and Cc3, organic source ), Ca²⁺, Mg²⁺, Fe²⁺, and Mn²⁺ to precipitate as Cc4. Concentration of K⁺ and declining of H⁺ contributed to the transformation of K1 and K2 into illites, while concentration of Mg²⁺ and Fe²⁺ as well as declining of H⁺ led to the transformation of K1 and K2 into chlorites. In this process, , Ca²⁺, Mg²⁺, Fe²⁺, Mn²⁺, and K⁺ entered sandstones in the forms of Cc4, illites, and chlorites.

6. Conclusions

The material exchange of pore fluids in rift basins could be divided into five stages. The first stage was the near surface evaporation concentration stage, during which Ca²⁺, Mg²⁺, and in lake waters precipitated as high-Mg calcites (Cc1), mainly caused by evaporation. The second stage was the shale compaction stage, during which Ca²⁺ and from shale compaction waters precipitated as calcites (Cc2), mainly caused by compaction of shales. The third stage was the carboxylic acid dissolution stage, during which dissolution of plagioclases (by carboxylic acid) occurred. During this stage, Ca²⁺ and Na⁺ entered into pore fluids as ions, while Si⁴⁺ and Al³⁺ entered into pore fluids and migrated as clathrates, ultimately precipitating as kaolinites (K1) and quartz overgrowth (Q1). Partly, the upwelling of hydrothermal fluids caused by active faults led to the precipitation of carbon cements (Cc3). Those processes were mainly caused by carboxylic acids and upwelling of hydrothermal fluids. The fourth stage was the organic CO₂ stage, which was featured by the kaolinization of K-feldspar, formation of organic CO₂, and dissolution of metamorphic lithic fragments and carbon cements (mainly Cc2 and Cc3). During this stage, K⁺, Fe²⁺, Mg²⁺, Ca²⁺, , and entered into pore fluids, driven by formation of organic CO₂. The fifth stage was the alkaline fluid stage, which was characterized by the cementation of ferro-carbonates and ankerite as well as illitization or chloritization of kaolinites. During this stage, K⁺, Fe²⁺, Mg²⁺, Ca²⁺, and precipitated from pore fluids and entered into sandstones, caused by declining concentration of H⁺.

Conflicts of Interest

The authors declare that they have no conflicts of interest.

Acknowledgments

This study was financially supported by the National Science and Technology Special Grant (no. 2016ZX05006001) and National Natural Science Foundation of China (no. 41172128). The authors also appreciate Shengli Oilfield Company of Sinopec for providing core samples and other geological data of Dongying Sag.

References

M. C. Li, J. Li, Y. J. Wan, Z. Y. Deng, and X. Q. Du, “Fluids in the sedimentary basin,” Acta Petrolei Sinica, vol. 04, pp. 13–17, 2001, [In Chinese with English abstract].
View at: Google Scholar
J. H. Zeng, “Geofluids Flow and Hydrocarbon Accumulation in Sedimentary Basin,” Marine Origin Petroleum Geology, vol. 01, pp. 37–42, 2005, [In Chinese with English abstract].
View at: Google Scholar
X. N. Xie, J. M. Cheng, and Y. L. Meng, “Basin fluid flow and associated diagenetic processes,” Acta Sedimentologica Sinica, vol. 05, pp. 863–871, 2009, [In Chinese with English abstract].
View at: Google Scholar
S. T. Paxton, J. O. Szabo, J. M. Ajdukiewicz, and R. E. Klimentidis, “Construction of an intergranular volume compaction curve for evaluating and predicting compaction and porosity loss in rigid-grain sandstone reservoirs,” AAPG Bulletin, vol. 86, no. 12, pp. 2047–2067, 2002.
View at: Google Scholar
S. J. Huang, H. W. Wu, J. Liu, L. C. Shen, and C. G. Huang, “Generation of secondary porosity by meteoric water during time of subaerial exposure: An example from Yanchang Formation sandstone of Triassic of Ordos Basin,” Earth Science, vol. 04, pp. 419–424, 2003, [In Chinese with English abstract].
View at: Google Scholar
M. A. K. El-ghali, H. Mansurbeg, S. Morad, I. Al-Aasm, and G. Ajdanlisky, “Distribution of diagenetic alterations in fluvial and paralic deposits within sequence stratigraphic framework: evidence from the Petrohan Terrigenous Group and the Svidol Formation, Lower Triassic, NW Bulgaria,” Sedimentary Geology, vol. 190, no. 1-4, pp. 299–321, 2006.
View at: Publisher Site | Google Scholar
M. P. Verma, “Qrtzgeotherm: An ActiveX component for the quartz solubility geothermometer,” Computers & Geosciences, vol. 34, no. 12, pp. 1918–1925, 2008.
View at: Publisher Site | Google Scholar
A. Berger, S. Gier, and P. Krois, “Porosity-preserving chlorite cements in shallow-marine volcaniclastic sandstones: Evidence from cretaceous sandstones of the sawan gas field, Pakistan,” AAPG Bulletin, vol. 93, no. 5, pp. 595–615, 2009.
View at: Publisher Site | Google Scholar
K. Bjørlykke, M. Ramm, and G. C. Saigal, “Sandstone diagenesis and porosity modification during basin evolution,” Geologische Rundschau, vol. 78, no. 1, pp. 243–268, 1989.
View at: Publisher Site | Google Scholar
K. Bjørlykke, “Fluid flow in sedimentary basins,” Sedimentary Geology, vol. 86, no. 1-2, pp. 137–158, 1993.
View at: Publisher Site | Google Scholar
K. Bjørlykke and J. Jahren, “Open or closed geochemical systems during diagenesis in sedimentary basins: Constraints on mass transfer during diagenesis and the prediction of porosity in sandstone and carbonate reservoirs,” AAPG Bulletin, vol. 96, no. 12, pp. 2193–2214, 2012.
View at: Publisher Site | Google Scholar
G. Yuan, Y. Cao, T. Yang et al., “Porosity enhancement potential through mineral dissolution by organic acids in the diagenetic process of clastic reservoir,” Earth Science Frontiers, vol. 20, no. 5, pp. 207–219, 2013.
View at: Google Scholar
G.-H. Yuan, Y.-C. Cao, Z.-Z. Jia, Y.-Z. Wang, and T. Yang, “Research progress on anomalously high porosity zones in deeply buried clastic reservoirs in petroliferous basin,” Natural Gas Geoscience, vol. 26, no. 1, pp. 28–42, 2015.
View at: Publisher Site | Google Scholar
X. Q. Ding, M. M. Han, S. N. Zhang, M. Y. Fu, and Y. L. Wan, “Roles of meteoric water on secondary porosity of siliciclastic reservoirs,” International Geology Review, vol. 60, pp. 145–158, 2014, [In Chinese with English abstract].
View at: Google Scholar
A. Putnis, “Transient porosity resulting from fluid-mineral interaction and its consequences,” Reviews in Mineralogy and Geochemistry, vol. 80, no. 1, pp. 1–23, 2015.
View at: Publisher Site | Google Scholar
Z. Cao, G. Liu, Y. Kong et al., “Lacustrine tight oil accumulation characteristics: Permian Lucaogou Formation in Jimusaer Sag, Junggar Basin,” International Journal of Coal Geology, vol. 153, pp. 37–51, 2016.
View at: Publisher Site | Google Scholar
M. H. Liu and C. L. Zhao, “Review of the studies on oil and gas reservoirs,” Journal of China University of Petroleum, vol. 15, pp. 115–124, 1991, [In Chinese with English abstract].
View at: Google Scholar
P. Luo, Y. N. Qiu, A. L. Jia, and X. S. Wang, “The Present Challenges of Chinese Petroleum Reservoir Geology and Research Direction,” Acta Sedimentologica Sinica, vol. 21, pp. 142–147, 2003, [In Chinese with English abstract].
View at: Google Scholar
S. N. Ehrenberg, P. H. Nadeau, and Ø. Steen, “A megascale view of reservoir quality in producing sandstones from the offshore Gulf of Mexico,” AAPG Bulletin, vol. 92, no. 2, pp. 145–164, 2008.
View at: Publisher Site | Google Scholar
S. N. Ehrenberg, P. H. Nadeau, and Ø. Steen, “Petroleum reservoir porosity versus depth: Influence of geological age,” AAPG Bulletin, vol. 93, no. 10, pp. 1281–1296, 2009.
View at: Publisher Site | Google Scholar
C.-L. Ye, G.-D. Zheng, and J. Zhao, “Research review of Water-Rock interactions in reservoir rocks,” Bulletin of Mineralogy Petrology and Geochemistry, vol. 29, no. 1, pp. 89–97, 2010.
View at: Google Scholar
J. M. Ajdukiewicz and R. H. Lander, “Sandstone reservoir quality prediction: the state of the art,” AAPG Bulletin, vol. 94, no. 8, pp. 1083–1091, 2010.
View at: Publisher Site | Google Scholar
T. R. Taylor, M. R. Giles, L. A. Hathon et al., “Sandstone diagenesis and reservoir quality prediction: models, myths, and reality,” AAPG Bulletin, vol. 94, no. 8, pp. 1093–1132, 2010.
View at: Publisher Site | Google Scholar
R. C. Tobin, T. McClain, R. B. Lieber et al., “Reservoir quality modeling of tight-gas sands in Wamsutter field: integration of diagenesis, petroleum systems, and production data,” AAPG Bulletin, vol. 94, no. 8, pp. 1229–1266, 2010.
View at: Publisher Site | Google Scholar
J. Lai, G. Wang, Y. Ran, Z. Zhou, and Y. Cui, “Impact of diagenesis on the reservoir quality of tight oil sandstones: The case of Upper Triassic Yanchang Formation Chang 7 oil layers in Ordos Basin, China,” Journal of Petroleum Science and Engineering, vol. 145, pp. 54–65, 2016.
View at: Publisher Site | Google Scholar
Z. Cao, G. D. Liu, W. Meng, P. Wang, and C. Y. Yang, “Origin of different chlorite occurrences and their effects on tight clastic reservoir porosity,” Journal of Petroleum Science Engineering160, pp. 384–392, 2017.
View at: Google Scholar
R. C. Surdam and P. Yin, “Organic Acids and Carbonate Stability, the Key to Predicting Positive Porosity Anomalies,” in in. Organic Acids in Geological Processes, Pittman E. D. and M. D. Lewan, Eds., pp. 398–448, Springer, Berlin, Germany, 1994.
View at: Google Scholar
S. M. C. D. Anjos, L. F. D. Ros, R. S. D. Souza, C. M. D. A. Silva, and C. L. Sombra, “Depositional and diagenetic controls on the reservoir quality of Lower Cretaceous Pendência sandstones, Potiguar rift basin, Brazil,” AAPG Bulletin, vol. 84, 2000.
View at: Publisher Site | Google Scholar
P. Gouze and A. Coudrain-Ribstein, “Chemical reactions and porosity changes during sedimentary diagenesis,” Applied Geochemistry, vol. 17, no. 1, pp. 39–47, 2002.
View at: Publisher Site | Google Scholar
J. M. Ketzer, M. Holz, S. Morad, and I. S. Al-Aasm, “Sequence stratigraphic distribution of diagenetic alterations in coal-bearing, paralic sandstones: evidence from the Rio Bonito Formation (early Permian), southern Brazil,” Sedimentology, vol. 50, no. 5, pp. 855–877, 2003.
View at: Publisher Site | Google Scholar
S. J. Huang, K. K. Huang, L. W. Feng, H. P. Tong, L. H. Liu, and X. H. Zhang, “Mass exchanges among feldspar , kaolinite and illite and their influences on secondary porosity formation in clastic diagenesis — a case study on the Upper Paleozoic, Ordos Basin and Xujiahe Formation, Western Sichuan Depression,” Geochimica, vol. 38, pp. 498–506, 2009, [In Chinese with English abstract].
View at: Google Scholar
H. Mansurbeg, M. A. K. El-ghali, S. Morad, and P. Plink-Björklund, “The impact of meteoric water on the diagenetic alterations in deep-water, marine siliciclastic turbidites,” Journal of Geochemical Exploration, vol. 89, no. 1-3, pp. 254–258, 2006.
View at: Publisher Site | Google Scholar
B. S. Yu and X. Y. Lai, “Dissolution of calcite cement and its contribution to the secondary pores of reservoir in the kela2 gas field in the Tarim basin,” Journal of Mineralogy and Petrology, vol. 26, pp. 74–79, 2006, [In Chinese with English abstract].
View at: Google Scholar
Z. Cao, G. Liu, H. Zhan et al., “Pore structure characterization of Chang-7 tight sandstone using MICP combined with N² GA techniques and its geological control factors,” Scientific Reports, vol. 6, Article ID 36919, 2016.
View at: Publisher Site | Google Scholar
G. Yuan, J. Gluyas, Y. Cao et al., “Diagenesis and reservoir quality evolution of the Eocene sandstones in the northern Dongying Sag, Bohai Bay Basin, East China,” Marine and Petroleum Geology, vol. 62, pp. 77–89, 2015.
View at: Publisher Site | Google Scholar
Y. Li, J. G. Cai, and J. M. Liu, “High-resolution sequence stratigraphy of paleogene in Dongying Depression,” Acta Sedimentologica Sinica, vol. 20, pp. 212-213, 2002, [In Chinese with English abstract].
View at: Google Scholar
I. Friedma and O'Neil. Jr, “Compilation of stable isotope fractionation factors of geochemical interest,” in in. Data of Geochemistry, M. Fleischer, Ed., p. 114, Geological Survey, USA, 6 edition, 1977.
View at: Google Scholar
P. Deines, “The isotopic composition of reduced organic carbon,” in in. Handbook of Environmental Isotope Geochemistry, P. Fritz and J. C. Fontes, Eds., pp. 329–406, Elsevier, Amsterdam, The Netherlands, 1980.
View at: Google Scholar
S. M. Savin, “Oxygen and hydrogen isotope effects in low-temperature mineral-water interactions,” in In : Handbook of environmental isotope geochemistry, P. Fritz and J. C. Fontes, Eds., pp. 283–327, Elsevier, Amsterdam, The Netherlands, 1980.
View at: Google Scholar
K. Kelts and M. Talbot, “Lacustrine Carbonates as Geochemical Archives of Environmental Change and Biotic/Abiotic Interactions,” in Large Lakes, Brock/Springer Series in Contemporary Bioscience, pp. 288–315, Springer Berlin Heidelberg, Berlin, Heidelberg, 1990.
View at: Publisher Site | Google Scholar
J. Veizer, D. Ala, K. Azmy et al., “⁸⁷Sr/⁸⁶Sr, δ¹³C and δ¹⁸O evolution of Phanerozoic seawater,” Chemical Geology, vol. 161, no. 1, pp. 59–88, 1999.
View at: Publisher Site | Google Scholar
D. Ala, K. Azmy, P. Bruckschen et al., “⁸⁷Sr/⁸⁶Sr, δ¹³C and δ¹⁸O evolution of Phanerozoic seawater,” Chemical Geology, vol. 161, no. 1, pp. 1586–1586, 1999.
View at: Publisher Site | Google Scholar
M. Fayek, T. M. Harrison, M. Grove, K. D. McKeegan, C. D. Coath, and J. R. Boles, “In situ stable isotopic evidence for protracted and complex carbonate cementation in a petroleum reservoir, north coles levee, san joaquin basin, California, U.S.A,” Journal of Sedimentary Research, vol. 71, no. 3, pp. 444–458, 2001.
View at: Publisher Site | Google Scholar
S. G. Franks, R. F. Dias, K. H. Freeman et al., “Carbon isotopic composition of organic acids in oil field waters, San Joaquin Basin, California, USA,” Geochimica et Cosmochimica Acta, vol. 65, no. 8, pp. 1301–1310, 2001.
View at: Publisher Site | Google Scholar
S. Liu, S. Huang, Z. Shen, Z. Lü, and R. Song, “Diagenetic fluid evolution and water-rock interaction model of carbonate cements in sandstone: An example from the reservoir sandstone of the Fourth Member of the Xujiahe Formation of the Xiaoquan-Fenggu area, Sichuan Province, China,” Science China Earth Sciences, vol. 57, no. 5, pp. 1077–1092, 2014.
View at: Publisher Site | Google Scholar
B. Wu, A. Wei, C. Liu et al., “Stable isotope tracing on the formation of white sandstone in Yan'an Group, northern Ordos Basin, and its geological significance,” Earth Science Frontiers, vol. 22, no. 3, pp. 205–214, 2015.
View at: Publisher Site | Google Scholar
S. X. Shao, J. H. Zeng, S. W. Zhang et al., “Types , characteristics and origin of kaolinite in sandstone reservoir of Shahejie Formation, Dongying Sag,” Acta Sedimentologica Sinica, vol. 33, pp. 1204–1216, 2015, [In Chinese with English abstract].
View at: Google Scholar
A. Matthews and A. Katz, “Oxygen isotope fractionation during the dolomitization of calcium carbonate,” Geochimica et Cosmochimica Acta, vol. 41, no. 10, pp. 1431–1438, 1977.
View at: Publisher Site | Google Scholar
C. L. Liu, “Carbon and oxygen isotopic compositions of lacustrine carbonates of the Shahejie Formation in the Dongying depression and their paleolimnological significance,” Acta Sedimentologica Sinica, vol. 16, pp. 109–114, 1998, [In Chinese with English abstract].
View at: Google Scholar
N. Qiu, S. Li, and J. Zeng, “Thermal history and tectonic-thermal evolution of the Jiyang depression in the Bohai Bay Basin, East China,” Acta Geologica Sinica, vol. 78, no. 2, pp. 263–269, 2004.
View at: Google Scholar
X. C. Lu, W. X. Hu, Q. Fu et al., “Study of salinity evolution of geofluids during syngenesis and diagenesis using composition of carbonate minerals,” Acta Sedimentologica Sinica, vol. 16, pp. 120–126, 1998, [In Chinese with English abstract].
View at: Google Scholar
J. H. Zeng, J. L. Peng, N. S. Qiu, and Z. Q. Zhu, “Carbonate dissolution-precipitation in sandstone-shale contact and its petroleum geological meanings,” Natural Gas Geoscience, vol. 06, pp. 760–764, 2006, [In Chinese with English abstract].
View at: Google Scholar
S. Zhang, L. Zhang, S. Zhang, Q. Liu, R. Zhu, and Y. Bao, “Formation of abnormal high pressure and its application in the study of oil-bearing property of lithologic hydrocarbon reservoirs in the Dongying Sag,” Chinese Science Bulletin, vol. 54, no. 23, pp. 4468–4478, 2009.
View at: Publisher Site | Google Scholar
J. Guo, J. H. Zeng, G. Q. Song, Y. W. Zhang, X. J. Wang, and W. Meng, “Characteristics and Origin of Carbonate Cements of Shahejie Formation of Central Uplift Belt in Dongying Depression,” Earth Science, vol. 39, pp. 565–576, 2014, [In Chinese with English abstract].
View at: Google Scholar
Y. W. Zhang, J. H. Zeng, X. Gao, and S. Y. Zhou, “Distribution characteristics and main controlling Factors of carbonate cements in the paleogene reservoirs in Dongying Depression,” Journal of Jilin University, vol. 39, pp. 16–22, 2009, [In Chinese with English abstract].
View at: Google Scholar
H. O. Cookenboo and R. M. Bustin, “Pore water evolution in sandstones of the Groundhog Coalfield, northern Bowser Basin, British Columbia,” Sedimentary Geology, vol. 123, no. 1-2, pp. 129–146, 1999.
View at: Publisher Site | Google Scholar
N. R. Goulty, C. Sargent, P. Andras, and A. C. Aplin, “Compaction of diagenetically altered mudstones – Part 1: Mechanical and chemical contributions,” Marine and Petroleum Geology, vol. 77, pp. 703–713, 2016.
View at: Publisher Site | Google Scholar
J. Zhao, “Laws of mudstone compaction on the west slope of the Songliao Basin,” Oil and Gas Geology, vol. 31, pp. 486–492, 2010, [In Chinese with English abstract].
View at: Google Scholar
Y. J. Han, S. He, G. Q. Song et al., “Origin of carbonate cements in the overpressured top seal and adjacent sandstones in Dongying depression,” Petroleum Processing Section, vol. 33, pp. 385–393, 2012, [In Chinese with English abstract].
View at: Google Scholar
R. C. Surdam, L. J. Crossey, E. S. Hagen, and H. P. Heasler, “Organic-inorganic interactions and sandstone diagenesis,” The American Association of Petroleum Geologists Bulletin, vol. 73, no. 1, pp. 1–23, 1989.
View at: Google Scholar
D. K. Zhong, X. M. Zhu, and J. G. Cai, “Vertical distribution of secondary pores in Paleogene sandstones in Zhanhua Depression,” Oil and Gas Geology, vol. 24, pp. 286–290, 2003, [In Chinese with English abstract].
View at: Google Scholar
G. R. Davies and L. B. Smith Jr., “Structurally controlled hydrothermal dolomite reservoir facies: an overview,” AAPG Bulletin, vol. 90, no. 11, pp. 1641–1690, 2006.
View at: Publisher Site | Google Scholar
B. J. Wang, S. He, and J. Wang, “Hydrochemistry field origin and its coupling relationship with overpressure system , Dongying depression,” Journal of China University of Petroleum, vol. 36, pp. 54–64, 2012, [In Chinese with English abstract].
View at: Google Scholar
R. Shiraki and T. L. Dunn, “Experimental study on water-rock interactions during CO2 flooding in the Tensleep formation, Wyoming, USA,” Applied Geochemistry, vol. 15, no. 3, pp. 265–279, 2000.
View at: Publisher Site | Google Scholar
Y. Zhang, J. Zeng, Z. Qu, and J. Chen, “Development characteristics and genetic mechanism of authigenic kaolinite in sandstone reservoirs of the Dongying Sag, Bohai Bay Basin,” Oil and Gas Geology, vol. 36, no. 1, pp. 73–79, 2015.
View at: Publisher Site | Google Scholar
Q. P. Che and H. B. Sun, “Authigenic kaolinite orign analysis of paleogene sandstone reservoirs in Niuju area,” Journal of Changchun University of science and Technology, vol. 25, pp. 306–309, 1995, [In Chinese with English abstract].
View at: Google Scholar
J. Y. Gu and B. He, “Study on triassic fin delta sedimention and reservoir in Lunnan Area Tarim basin,” Acta Sedimentologica Sinica, vol. 12, pp. 54–62, 1994, [In Chinese with English abstract].
View at: Google Scholar
X. Y. Zhao, “The conditions for formation of kaolinite subgroup in Tarim Basin,” Xinjiang Petroleum Geology, vol. 24, pp. 419–423, 2003, [In Chinese with English abstract].
View at: Google Scholar
H. Y. Zou, F. Hao, G. D. Liu, and C. Sui, “Genesis of authigenic kaolinite and gas accumulation in Bashijiqike Fm sandstone in Kuqa thrust belt,” Oil and Gas Geology, vol. 26, pp. 786–791, 2005, [In Chinese with English abstract].
View at: Google Scholar
J. Cao, Y. J. Zhang, H. u. WX et al., “Developing characteristics of kaolinite in central Junggar Basin and their effect on the reservoir quality,” Acta Mineralogica Sinica, vol. 25, pp. 367–373, 2005, [In Chinese with English abstract].
View at: Google Scholar
X. Chen, J. Zhong, J. Yuan, K. Nie, and Y. Yang, “Development and formation of Paleogene kaolinite, Bonan subsag,” Shiyou Kantan Yu Kaifa/Petroleum Exploration and Development, vol. 36, no. 4, pp. 456–462, 2009.
View at: Google Scholar
H. Irwin and A. Hurst, “Applications of geochemistry to sandstone reservoir studies,” Geological Society, London, Special Publications, vol. 12, pp. 127–146, 1983.
View at: Publisher Site | Google Scholar
W. J. Fu and W. B. Liu, “Study on the alteration of feldspar from clastic rock in Tarim Basin,” Acta Sedimentologica Sinica, pp. 84–89, 1996, [In Chinese with English abstract].
View at: Google Scholar
J. H. Zeng, “Effect of fluid-rock interaction on porosity of reservoir rocks in Tertiary System, Dongying Sag,” Shiyou Xuebao/Acta Petrolei Sinica, vol. 22, no. 4, p. 39, 2001.
View at: Google Scholar
J. Tóth, “Cross-formational gravity-flow of groundwater: A mechanism of the transport and accumulation of petroleum (the generalized hydraulic theory of petroleum migration),” in in : Problems of petroleum migration, I. Roberts and R. J. Cordell, Eds., pp. 121–167, AAPG Studies in Geology, USA, 1980.
View at: Google Scholar
M. Zha, “The dynamic models and numerical simulation of secondary petroleum migration in compactional flow basins an example from the Dong Ying Depression,” Acta Sedimentologica Sinica, vol. 15, pp. 86–90, 1997, [In Chinese with English abstract].
View at: Google Scholar
K. Bjørlykke, “Relationships between depositional environments, burial history and rock properties. Some principal aspects of diagenetic process in sedimentary basins,” Sedimentary Geology, vol. 301, pp. 1–14, 2014.
View at: Publisher Site | Google Scholar
E. H. Oelkers and J. Schott, “Experimental study of anorthite dissolution and the relative mechanism of feldspar hydrolysis,” Geochimica et Cosmochimica Acta, vol. 59, no. 24, pp. 5039–5053, 1995.
View at: Publisher Site | Google Scholar
J. S. Jahren and P. Aagaard, “Compositional variations in diagenetic chlorites and illites, and relationships with formation-water chemistry,” Clay Minerals, vol. 24, no. 2, pp. 157–170, 1989.
View at: Publisher Site | Google Scholar
C. L. Liu, H. Q. Zhao, and P. X. Wang, “Water Chemistry of the Paleogene Dongying Lake: Evidence from Fossil Assemblages and Shell Isotopes,” Acta Geoscientia Sinica, vol. 23, pp. 237–242, 2002, [In Chinese with English abstract].
View at: Google Scholar
Z. H. Chen, M. Zha, and Q. Jin, “Mineral elemental response to the evolution of terrestrial Brine faulted-basin: a case study in the Paleogene of Well Haoke-1, Dongying Sag,” Acta Sedimentologica Sinica, vol. 26, pp. 925–932, 2008, [In Chinese with English abstract].
View at: Google Scholar
B. N. Popp and B. H. Wilkinson, “Holocene lacustrine ooids from Pyramid lake, Nevada,” in In: Coated Grains, T. Peryt, Ed., pp. 141–153, Springer-Verlag, Berlin, Germany, 1983.
View at: Google Scholar
P. A. Sandberg, “New interpretations of Great Salt Lake ooids and of ancient non‐skeletal carbonate mineralogy,” Sedimentology, vol. 22, no. 4, pp. 497–537, 1975.
View at: Publisher Site | Google Scholar

Copyright

Copyright © 2018 W. Meng et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

PDF Download Citation

Download other formats

Order printed copies

Views

998

Downloads

1151

Citations