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Volume 2018, Article ID 3015038, 12 pages
Research Article

Microscale Research on Effective Geosequestration of CO2 in Coal Reservoir: A Natural Analogue Study in Haishiwan Coalfield, China

Kaizhong Zhang,1,2,3 Wei Li,1,2,3 Yuanping Cheng,1,2,3 Jun Dong,1,2,3 Qingyi Tu,1,2,3 and Rong Zhang1,2,3

1Key Laboratory of Coal Methane and Fire Control, Ministry of Education, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China
2National Engineering Research Center of Coal Gas Control, China University of Mining & Technology, Xuzhou, Jiangsu 221116, China
3School of Safety Engineering, China University of Mining and Technology, Xuzhou 221116, China

Correspondence should be addressed to Wei Li; moc.liamtoh@tmucliew and Yuanping Cheng; moc.kooltuo@429026pyc

Received 1 October 2017; Revised 29 January 2018; Accepted 4 February 2018; Published 28 February 2018

Academic Editor: Marco Petitta

Copyright © 2018 Kaizhong Zhang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


A natural analogue study in CO2-rich coalfield (Haishiwan, China) provides a strong support for safe, reliable, and long-term storage by analyzing the mechanism of CO2 migration, entrapment, and storage in coal reservoir. Thus, effects of geological tectonism on reservoir properties were investigated. Simultaneously, coal and oil shale samples before and after supercritical CO2 (SCCO2) treatment via geochemical reactor were collected to analyze changes in pore structure, functional group distributions, and SCCO2 extraction. Observations from in situ properties of coal seam indicate that there is a positive relationship with CH4 contents and F19 fault whereas CO2 and carbonate contents decrease as the distance from F19 increases. Analysis of pore properties reveals that SCCO2 enlarges the development of coal pore and facilitates the diffusion and seepage channel of coal reservoir, while no changes in larger pores are found in oil shale, which may restrain fluids from passing through. Then, oxygen-containing functional groups are mobilized by SCCO2 from oil shale, associated with a decrease in sorption sites. The sealing capacity of cap rock (oil shale) and geological tectonism (F19 fault), as the major contributors to CO2 enrichment and accumulation, provides insights into the suitable selection of CCGS site for long geological time.