Rare Earth Elements in Mineral Deposits: Speciation in Hydrothermal Fluids and Partitioning in Calcite

Table 2

Source of thermodynamic data for minerals, aqueous species, and gases included in the numerical simulations.

Species	References
Minerals
Calcite, CaCO3	1
REE hydroxides, REE(OH)3	2
Ca-species
Ca(CO3)^0, Ca(HCO3)^+, Ca^2+, CaCl^+, , CaOH^+	3, slop98.dat
Na-species
Na(CO3)^−, Na(HCO3)^0,	3, slop98.dat
Na^+, NaCl^0, NaOH^0	4
REE-species
REE^3+, REE(OH)^2+, , ,	3, slop98.dat
REECl^2+,	5
,	6
C-species
CO^0, , , ,	3, slop98.dat
Cl-species
Cl^−	3, slop98.dat
HCl^0	7
H-O-species
, , OH^−, H^+, H2O^0	3, slop98.dat
Gases
CO, CO2, CH4, H2, H2O, O2	8, 9, 10

olland and Powell (1998) [55]. ²Navrotsky et al. (2015) [56]. ³SUPCRT92, Johnson et al. (1992) [57]. ⁴Miron et al. (2016) [58]. ⁵Migdisov et al. (2009; 2016) [35, 39]. ⁶Haas et al. (1995) [36]. ⁷Tagirov et al. (1997) [59]. ⁸Frenkel (1994) [60].⁹Proust and Vera (1989) [61]. ¹⁰Stryjek and Vera (1986) [62].