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International Journal of Chemical Engineering
Volume 2016, Article ID 7082381, 10 pages
http://dx.doi.org/10.1155/2016/7082381
Research Article

Modeling and Simulation of the Hydrogenation of α-Methylstyrene on Catalytically Active Metal Foams as Tubular Reactor Packing

Technische Universität Dresden, Münchener Strasse 41, 01062 Dresden, Germany

Received 17 September 2015; Revised 1 December 2015; Accepted 9 December 2015

Academic Editor: Bhaskar Kulkarni

Copyright © 2016 Farzad Lali et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. L. E. Campbell, “Catalyst for production of nitric acid by oxidation of ammonia,” US 5336656 A, 1993.
  2. S. Haase, “Chair of chemical process engineering and plant design,” in Minichannel Flow Reactors for Gas Liquid Solid Reactions, Technische Universität Dresden, Dresden, Germany, 2012. View at Google Scholar
  3. S. Haase, T. Bauer, R. Langsch, and R. Lange, “Modelling of gas/liquid/solid reactions in strict separation for the regime of the forcer flux,” Chemie Ingenieur Technik, vol. 81, no. 12, pp. 1991–1998, 1991. View at Google Scholar
  4. S. Haase, R. Langsch, T. Bauer, and R. Lange, “Impact of spherical catalyst particles on gas-liquid flow regimes in minichannels with square cross section,” Chemie-Ingenieur-Technik, vol. 86, no. 4, pp. 467–475, 2014. View at Publisher · View at Google Scholar · View at Scopus
  5. S. Haase, M. Weiss, R. Langsch, T. Bauer, and R. Lange, “Hydrodynamics and mass transfer in three-phase composite minichannel fixed-bed reactors,” Chemical Engineering Science, vol. 94, pp. 224–236, 2013. View at Publisher · View at Google Scholar · View at Scopus
  6. M. T. Kreutzer, P. Du, J. J. Heiszwolf, F. Kapteijn, and J. A. Moulijn, “Mass transfer characteristics of three-phase monolith reactors,” Chemical Engineering Science, vol. 56, no. 21-22, pp. 6015–6023, 2001. View at Publisher · View at Google Scholar · View at Scopus
  7. F. Lali, G. Böttcher, P.-M. Schöneich, S. Haase, S. Hempel, and R. Lange, “Preparation and characterization of Pd/Al2O3 catalysts on aluminum foam supports for multiphase hydrogenation reactions in rotating foam reactors,” Chemical Engineering Research and Design, vol. 94, pp. 365–374, 2015. View at Publisher · View at Google Scholar · View at Scopus
  8. R. Lange, R. Gutsche, and J. Hanika, “Forced periodic operation of a trickle-bed reactor,” Chemical Engineering Science, vol. 54, no. 13-14, pp. 2569–2573, 1999. View at Publisher · View at Google Scholar · View at Scopus
  9. R. Langsch, S. Haase, and R. Lange, “Hydrodynamics and mass transfer in a pellet string reactor for gas-liquid-solid reactions,” Chemie-Ingenieur-Technik, vol. 85, no. 5, pp. 642–655, 2013. View at Publisher · View at Google Scholar · View at Scopus
  10. R. Langsch, J. Zalucky, S. Haase, and R. Lange, “Investigation of a packed bed in a mini channel with a low channel-to-particle diameter ratio: flow regimes and mass transfer in gas-liquid operation,” Chemical Engineering and Processing, vol. 75, pp. 8–18, 2014. View at Publisher · View at Google Scholar · View at Scopus
  11. J.-N. Tourvieille, R. Philippe, and C. de Bellefon, “Milli-channel with metal foams under an applied gas-liquid periodic flow: external mass transfer performance and pressure drop,” Chemical Engineering Journal, vol. 267, pp. 332–346, 2015. View at Publisher · View at Google Scholar · View at Scopus
  12. F. Turek and R. Lange, “Mass transfer in trickle-bed reactors at low Reynolds number,” Chemical Engineering Science, vol. 36, no. 3, pp. 569–579, 1981. View at Publisher · View at Google Scholar · View at Scopus
  13. S. Haase and T. Bauer, “New method for simultaneous measurement of hydrodynamics and reaction rates in a mini-channel with Taylor flow,” Chemical Engineering Journal, vol. 176-177, pp. 65–74, 2011. View at Publisher · View at Google Scholar · View at Scopus
  14. P. W. A. M. Wenmakers, J. Van Der Schaaf, B. F. M. Kuster, and J. C. Schouten, “Comparative modeling study on the performance of solid foam as a structured catalyst support in multiphase reactors,” Industrial & Engineering Chemistry Research, vol. 49, no. 11, pp. 5353–5366, 2010. View at Publisher · View at Google Scholar · View at Scopus
  15. C. Jakobitz, Investigation of reaction kinetics of the hydrogenation of α-methylstyrene using surface modified and supported Pd/γ-Al2O3 catalysts [Diploma Thesis], Technische Universität Dresden, Dresden, Germany, 2009.
  16. V. Meille, C. De Bellefon, and D. Schweich, “Kinetics of α-methylstyrene hydrogenation on Pd/Al2O3,” Industrial & Engineering Chemistry Research, vol. 41, no. 7, pp. 1711–1715, 2002. View at Publisher · View at Google Scholar · View at Scopus
  17. F. A. Pahner, Simulation of a hydrogeantion reaction on catalytically active foams [diploma thesis], TU Dresden, Dresden, Germany, 2014.
  18. VDI Atlas of Heat Trasfer, Springer, 2006.
  19. B. Chexal, J. Horowitz, G. McCarthy, M. Merilo, and J.-P. Sursock, Electric Power Research Institute, 1999.
  20. P. Cognet, J. Berlan, G. Lacoste, P.-L. Fabre, and J.-M. Jud, “Application of metallic foams in an electrochemical pulsed flow reactor Part I: mass transfer performance,” Journal of Applied Electrochemistry, vol. 25, no. 12, pp. 1105–1112, 1995. View at Publisher · View at Google Scholar · View at Scopus
  21. C. P. Stemmet, Gas-Liquid Solid Foam Reactors: Hydrodynamics and Mass Transfer, Technische Universiteit Eindhoven, 2008.
  22. K. Onda, H. Takeuchi, and Y. Koyama, “Effect of packing materials on the wetted surface area,” Chemical Engineering, vol. 31, no. 2, pp. 126–134, 1967. View at Publisher · View at Google Scholar
  23. K. Onda, H. Takeuchi, and Y. Okumoto, “Mass transfer coefficients between gas and liquid phases in packed columns,” Journal of Chemical Engineering of Japan, vol. 1, no. 1, pp. 56–62, 1968. View at Publisher · View at Google Scholar
  24. C. P. Stemmet, F. Bartelds, J. van der Schaaf, B. F. M. Kuster, and J. C. Schouten, “Influence of liquid viscosity and surface tension on the gas-liquid mass transfer coefficient for solid foam packings in co-current two-phase flow,” Chemical Engineering Research and Design, vol. 86, no. 10, pp. 1094–1106, 2008. View at Publisher · View at Google Scholar · View at Scopus
  25. P. M. Schöneich, Simulation of a hydrogeantion reaction on catalytically active foams [Diploma thesis], TU Dresden, 2011.
  26. H. S. Fogler, Elements of Chemical Reaction Engineering, Prentice-Hall, Englewood Cliffs , NJ, USA, 4th edition, 2005.
  27. G. F. Carey and B. A. Finlayson, “Orthogonal collocation on finite elements,” Chemical Engineering Science, vol. 30, no. 5-6, pp. 587–596, 1975. View at Publisher · View at Google Scholar · View at Scopus
  28. B. A. Finlayson, “Orthogonal collocation in chemical reaction engineering,” Catalysis Reviews, vol. 10, no. 1, pp. 69–138, 1974. View at Google Scholar · View at Scopus
  29. A. Löwe, Chemische Reaktionstechnik: mit MATLAB und SIMULINK, Wiley-VCH, Weinheim, Germany, 2001.
  30. J. Villadsen, Solution of Differential Equation Models by Polynomial Approximation, Physical & Chemical Engineering Science, Edited by M. L. Michelsen, Prentice Hall, Englewood Cliffs , NJ, USA, 1978.
  31. J. V. Villadsen and W. E. Stewart, “Solution of boundary-value problems by orthogonal collocation,” Chemical Engineering Science, vol. 22, no. 11, pp. 1483–1501, 1967. View at Publisher · View at Google Scholar · View at Scopus
  32. S. D. Conte and C. De Boor, Elementary Numerical Analysis/An Algorithmic Approach, McGraw-Hill, Auckland, New Zealand, 3rd edition, 1980.
  33. F. Lali, Catalytic Active Foams for Gas Liquid Solid Reaction, Technische Universität Dresden, Dresden, Germany, 2015.
  34. M. Schubert, “Performance enhancement of trickle bed reaktors,” in Proceedings of the Annual Cardiovascular-Thoracic (CVT) Critical Care, Technische Universität Dresden, 2007.