International Journal of Electrochemistry

International Journal of Electrochemistry / 2011 / Article
Special Issue

Lithium-Ion Batteries: Recent Advances and New Horizons

View this Special Issue

Research Article | Open Access

Volume 2011 |Article ID 283491 |

Rushanah Mohamed, Shan Ji, Vladimir Linkov, "Preparation and Characterisation of LiFePO4/CNT Material for Li-Ion Batteries", International Journal of Electrochemistry, vol. 2011, Article ID 283491, 5 pages, 2011.

Preparation and Characterisation of LiFePO4/CNT Material for Li-Ion Batteries

Academic Editor: S. Gopukumar
Received23 Feb 2011
Revised10 Jul 2011
Accepted25 Jul 2011
Published28 Sep 2011


Li-ion battery cathode materials were synthesised via a mechanical activation and thermal treatment process and systematically studied. LiFePO4/CNT composite cathode materials were successfully prepared from LiFePO4 material. The synthesis technique involved growth of carbon nanotubes onto the LiFePO4 using a novel spray pyrolysis-modified CVD technique. The technique yielded LiFePO4/CNT composite cathode material displaying good electrochemical activity. The composite cathode exhibited excellent electrochemical performances with 163 mAh/g discharge capacity with 94% cycle efficiency at a 0.1 C discharge rate in the first cycle, with a capacity fade of approximately 10% after 30 cycles. The results indicate that carbon nanotube addition can enable LiFePO4 to display a higher discharge capacity at a fast rate with high efficiency. The research is of potential interest for the application of carbon nanotubes as a new conducting additive in cathode preparation and for the development of high-power Li-ion batteries for hybrid electric vehicles.

1. Introduction

The exponential growth in portable electronic devices such as cellular phones and laptop computers in recent years has resulted in an enormous demand for compact and light-weight rechargeable batteries which can offer high energy densities. In addition, growing environmental concerns have simultaneously driven the development of advanced batteries for electric vehicles. Li-ion batteries are appealing candidates for these applications as they provide higher energy density compared to the other rechargeable batteries systems available, such as the lead acid, nickel cadmium (NiCd), and nickel-metal hydride (NiMH) batteries. Today, the Li-ion is the fastest growing and most promising rechargeable battery chemistry. The electrochemical performance of Li-ion batteries relies significantly on the properties of the cathode-materials, the anode materials, and the electrolytes. Carbon-based materials have been the material of choice for lithium storage in Li-ion batteries for some time [1, 2]. This paper focuses on our study of the development of new cathode materials which encompass carbon nanotubes (CNTs) to ideally produce highly specific capacities. LiFePO4 has been reported to be an excellent cathode, but its high resistance limits the obtainable capacity. Recently, a variety of techniques have been attempted for the synthesis of high-performance LiFePO4 [3, 4]. Mechanical activation, which involves the blending of ingredients by high-energy ball milling followed by thermal treatment at high temperature, has turned out to be a versatile technique with high capability for scale up [5, 6]. In this study, LiFePO4/CNT composite cathode material has been synthesized via a novel synthesis technique and studied.

2. Experimental and Characterization

2.1. Experimental

LiFePO4/CNT composite material was synthesised by growing carbon nanotubes onto LiFePO4, via CVD using spray pyrolysis. Table 1 lists the experimental parameters employed in the CVD using spray pyrolysis technique.

Flushing gasArgon (UHP) obtained from Afrox
Carbon sourceEthylene Gas (UHP) obtained from Afrox
Deposition temperatures800°C
Flushing gas flow rate100 ml/min
Carbon source flow rate100 ml/min
Times of deposition30, 60, 90 minutes
Catalyst solutions1.0 M NiSO4

MaterialSingle-point BET surface area (m2/g)External surface area (m2/g)Internal pore area (m2/g)Pore volume (cm3/g)Average Pore diameter (nm)

LiFePO4/CNT Ni mist 60 min dep.7.8924.8529.090.10615.772

LiFePO4 material synthesised previously was placed into a quartz crucible and placed into a horizontal tube furnace. The furnace was then heated to 800°C under argon flow of 100 ml/min. Once the set temperature was reached, a Ni mist was introduced to a tubular furnace apparatus. The mist was produced from a 1.0 M NiSO4 solution. The argon gas flow was turned off, and ethylene gas was introduced into the furnace at a flow rate of 100 ml/min each for the desired deposition time. After the time elapsed, the final product was cooled to room temperature under an argon atmosphere.

2.2. Morphological and Structural Analysis

SEM measurements were done using a Hitachi ×650 microscope. The microscope beam energy can be varied over the range from 5 to 40 KeV, with a maximum resolution of 10 nm. Transmission electron microscopy (TEM) analyses were done using a Tecnai G2 F20 X-Twin Mat FEG-TEM. X-ray diffraction (XRD) analyses were performed using a Bruker multipurpose powder diffractometer (D8 Advance). In this investigation, the surface area and porosity of the LiFePO4/CNT cathode materials were investigated with high sensitivity using an accelerated surface area and porosity analyser (Micromeritics ASAP 2010).

2.3. Charge/Discharge Cycle Testing

The positive electrode consisted of 80% of the as-prepared composite, 15% acetylene black, and 5% polytetrafluoroethylene (PTFE) as a binder, and Al metal was used as the current collector. The electrolyte solution was 1.0 mol·L−1 LiPF6 in (1 : 1). Lithium metal foil was used as the counter electrode during electrochemical measurements. All cells were assembled in an argon-filled glovebox. Charge/discharge tests were carried out using a Land-BTL10 fully automatic program test instrument. For the novel Li-ion battery cathodes synthesised, tests were run at a voltage range of 2.40 to 4.10 V versus Li/Li+.

2.4. Electrochemical Conductivity

Electrochemical conductivity was calculated from the resistance values obtained from impedance measurements. Electrochemical impedance spectroscopy (EIS) measurements were carried out using an Eco Chemie Autolab PGSTAT 30. The amplitude of the AC signal was 5 mV over the frequency range between 100 kHz and 0.01 Hz.

3. Results and Discussion

Figure 1 illustrates the SEM images of LiFePO4/CNT composite cathode materials synthesised. From these images, the presence of carbon nanotubes is clearly observed. A mat of carbon nanotubes covers the surfaces of the LiFePO4 particles forming LiFePO4/CNT composite material. The CVD of a carbon gas source generally yields carbon nanotubes having a wide range of carbon nanotube diameters, which is also confirmed by the SEM images.

Figure 2 displays TEM images of the LiFePO4/CNT composite cathode material. From these HR-TEM images, we observe the presence of carbon nanotubes with thick walls, clear evidence that multiwalled carbon nanotubes have been successfully synthesised. Open cap ends are also observed in Figure 2(a). The dark particles were confirmed by EDS analysis to be that of the LiFePO4 and also Ni particles, which is to be expected. It is also visible that the carbon nanotubes grow directly from the particles as evident from Figures 2(a) and 2(b). It is thus possible that this technique yields carbon nanotubes grown via the tip growth mechanism.

Figure 3 shows the XRD patterns of the obtained LiFePO4/CNT composite cathode material. The diffraction peaks were confirmed to be that of olivine LiFePO4, and no impurities were detected. The XRD pattern could be indexed to the orthorhombic Pnma space group (JCPDS card No. 40-1499) based on the well-ordered olivine structure. The intensity of diffraction peaks has a close relation to the crystallinity of the crystal particle. All the XRD peaks are quite sharp and narrow, indicating that highly crystallized LiFePO4 phase is formed.

Li-ion intercalation/deintercalation reactions essentially depend on electronic conductivity, as the process is accompanied by electron removal at the same time [7]. The carbon nanotubes are added in order to enable the active material (LiFePO4) to transport lithium ions and electrons at a fast rate. Furthermore, the diffusion of Li ions in the solid state, which is considered to be the slowest process, depends on the surface area [8], which as seen is higher for the LiFePO4/CNT composites.

To effectively illustrate the effect of carbon nanotube addition on the electron conductivity of the composite materials, electron conductivity measurements were done on the pure LiFePO4 and the LiFePO4/CNT composite material. Figure 4 illustrates the electron conductivity results of the material as a function of CNT deposition time (which is directly proportional to CNT content). The increased electrical conductivity with increased CNT deposition time (and, hence, increased CNT content) for the LiFePO4/CNT cathode material is due to presence of the carbon nanotubes which have higher electrical conductivity. As the CNT content increases, the poorly conductive LiFePO4 grains are more surrounded by a widening ‘‘matrix’’ of fine, contiguous CNT networks. This is in agreement with the findings of Bewlay et al. [9] and Liu et al. [10] who increased the electrochemical conductivity of LiFePO4 by the inclusion of carbon or CNT, respectively; however, our materials displayed better charge discharge capacities.

Figure 5 shows the charge/discharge curves at discharge/charge rates varied from 0.1 to 2 C of the LiFePO4/CNT composite material synthesised using the spray-modified CVD technique. In the potential range of 2.5–4.2 V, the composite cathode delivered 163 mAh/g with 94% cycle efficiency at 0.1 C rate in the first cycle. The cycling characteristics of the LiFePO4/CNT cathode material at different discharge rates are shown in Figure 6. The results showed an almost steady decrease in discharge capacity with cycle number, with a capacity fade of approximately 10% after 30 cycles. The cathode displayed discharge capacity of 163 mAh/g at 0.1 C rate and around 134 mAh/g at 2 C rate.

The optimal deposition time required was established from the subsequent charge-discharge testing of the resulting material. The optimal deposition time was found to be 60 minutes when this Ni spray technique was utilised. In this optimal method of LiFePO4/CNT synthesis, a higher surface area material was obtained. Well-crystallized carbon nanotubes can improve cycle efficiency due to the reduction of oxide group production and the increased surface area. The electron transport between the cathode-active materials and the current collector was improved due to the fact that the interface was filled with carbon nanotubes. Therefore, the rate capability of this LiFePO4/CNT composite cathode material was enhanced effectively by the three-dimensional carbon nanotube network.

4. Conclusions

The composite cathode exhibited excellent electrochemical performances with 163 mAh/g discharge capacity at 0.1 C rate in the first cycle. The results indicate that carbon nanotube addition can enable LiFePO4 to display a higher discharge capacity at a fast rate with high efficiency. The research is of potential interest to the application of carbon nanotubes as a new conducting additive in cathode preparation and for the development of high-power Li-ion batteries for hybrid electric vehicles.


The authors acknowledge the NRF and the DST for funding. They would like to acknowledge Dr. R. Butcher at the iThemba LAbS for running the XRD analyses.


  1. J. R. Dahn, T. Zheng, Y. Liu, and J. S. Xue, “Mechanisms for lithium insertion in carbonaceous materials,” Science, vol. 270, no. 5236, pp. 590–598, 1995. View at: Google Scholar
  2. M. S. Dresselhaus and G. Dresselhaus, “Intercalation compounds of graphite,” Advances in Physics, vol. 30, no. 2, pp. 139–326, 1981. View at: Google Scholar
  3. W. Ojczyk, J. Marzec, K. Świerczek et al., “Studies of selected synthesis procedures of the conducting LiFePO4-based composite cathode materials for Li-ion batteries,” Journal of Power Sources, vol. 173, no. 2, pp. 700–706, 2007. View at: Publisher Site | Google Scholar
  4. G. Meligrana, C. Gerbaldi, A. Tuel, S. Bodoardo, and N. Penazzi, “Hydrothermal synthesis of high surface LiFePO4 powders as cathode for Li-ion cells,” Journal of Power Sources, vol. 160, no. 1, pp. 516–522, 2006. View at: Publisher Site | Google Scholar
  5. X. Z. Liao, Z. F. Ma, L. Wang, X. M. Zhang, Y. Jiang, and Y. S. He, “A novel synthesis route for LiFePO4/C cathode materials for lithium-ion batteries,” Electrochemical and Solid-State Letters, vol. 7, no. 12, pp. A522–A525, 2004. View at: Publisher Site | Google Scholar
  6. J. K. Kim, J. W. Choi, G. Cheruvally et al., “A modified mechanical activation synthesis for carbon-coated LiFePO4 cathode in lithium batteries,” Materials Letters, vol. 61, no. 18, pp. 3822–3825, 2007. View at: Publisher Site | Google Scholar
  7. R. Dominko, M. Gaberscek, J. Drofenik, M. Bele, S. Pejovnik, and J. Jamnik, “The role of carbon black distribution in cathodes for Li ion batteries,” Journal of Power Sources, vol. 119–121, pp. 770–773, 2003. View at: Publisher Site | Google Scholar
  8. X. Li, F. Kang, and W. Shen, “A comparative investigation on multiwalled carbon nanotubes and carbon black as conducting additive in LiNi0.7Co0.3 O2,” Electrochemical and Solid-State Letters, vol. 9, no. 3, pp. A126–A129, 2006. View at: Publisher Site | Google Scholar
  9. S. L. Bewlay, K. Konstantinov, G. X. Wang, S. X. Dou, and H. K. Liu, “Conductivity improvements to spray-produced LiFePO4 by addition of a carbon source,” Materials Letters, vol. 58, no. 11, pp. 1788–1791, 2004. View at: Publisher Site | Google Scholar
  10. Y. Liu, X. Li, H. Guo et al., “Effect of carbon nanotube on the electrochemical performance of C-LiFePO4/graphite battery,” Journal of Power Sources, vol. 184, no. 2, pp. 522–526, 2008. View at: Publisher Site | Google Scholar

Copyright © 2011 Rushanah Mohamed et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

More related articles

 PDF Download Citation Citation
 Download other formatsMore
 Order printed copiesOrder

Related articles

Article of the Year Award: Outstanding research contributions of 2020, as selected by our Chief Editors. Read the winning articles.