Research Article
Electrodeposition of Oriented Cerium Oxide Films
Table 1
IR assignment for Ce(III)-acetate complex and calculation of frequency difference (peak position in cm
−1) according to Figure
3.
| | Emission |
a |
b |
c |
d | Diff1
| Diff2
| | Emission type | Sym | Sym | An-sym | An-sym |
| | Ce : Acetate | | | | | | | | 0 : 1 | | 1417.6 | 1552 | | 134.4 | | | 1 : 1 | 1352.8 | 1404 | 1560.0 | 1581.2 | 156 | 228.4 | | 1 : 2 | 1350.9 | 1411.2 | 1556.4 | 1577.6 | 145.2 | 226.7 | | 1 : 3 | 1350.9 | 1414.7 | 1554.6 | 1577.6 | 139.9 | 226.7 | | 1 : 4 | 1353.9 | 1414.7 | 1556.1 | 1576.5 | 141.4 | 222.6 | | 1 : 5 | 1350.9 | 1416.5 | 1554.6 | 1577.6 | 138.1 | 226.7 | | 1 : 6 | 1347.8 | 1416.5 | 1554.2 | 1576.5 | 137.7 | 228.7 | | 1 : 7 | 1351.6 | 1416.5 | 1556.1 | 1576.5 | 139.6 | 224.9 | | 1 : 8 | 1349.7 | 1414.7 | 1556.1 | 1576.5 | 141.4 | 226.8 | | 1 : 9 | 1347.8 | 1414.7 | 1556.1 | 1576.5 | 141.4 | 228.7 | | 1 : 10 | 1350.7 | 1415.1 | 1556 | 1576.1 | 140.9 | 225.4 |
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