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International Journal of Electrochemistry
Volume 2014 (2014), Article ID 246746, 11 pages
Research Article

Synthesis of Nitrogen Doped Carbon and Its Enhanced Electrochemical Activity towards Ascorbic Acid Electrooxidation

Electrodics and Electrocatalysis Division, CSIR-Central Electrochemical Research Institute, Karaikudi, Tamil Nadu 630 006, India

Received 10 February 2014; Revised 21 May 2014; Accepted 30 May 2014; Published 26 June 2014

Academic Editor: Hamilton Varela

Copyright © 2014 Sankararao Mutyala and Mathiyarasu Jayaraman. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Nitrogen doped carbon, synthesized by a novel way of carbonizing polyaniline in an inert atmosphere at a constant temperature of , exhibits several unique features. The carbon: nitrogen ratio is found to increase with the treatment duration up to 120 minutes and a mass reduction of 60 wt% is observed with an interesting observation of the retention of the bulk polymer morphology, surprisingly, even after the carbonization process. The electrochemical activity evaluated with potassium hexacyanoferrate and hexamine ruthenium redox systems at a regular time interval helps to tune the catalytic activity. This type of nitrogen doped carbon prepared from polyaniline base exhibits excellent electrocatalytic activity as illustrated by the oxidation of ascorbic acid in neutral medium.