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International Journal of Electrochemistry
Volume 2014 (2014), Article ID 246746, 11 pages
http://dx.doi.org/10.1155/2014/246746
Research Article

Synthesis of Nitrogen Doped Carbon and Its Enhanced Electrochemical Activity towards Ascorbic Acid Electrooxidation

Electrodics and Electrocatalysis Division, CSIR-Central Electrochemical Research Institute, Karaikudi, Tamil Nadu 630 006, India

Received 10 February 2014; Revised 21 May 2014; Accepted 30 May 2014; Published 26 June 2014

Academic Editor: Hamilton Varela

Copyright © 2014 Sankararao Mutyala and Mathiyarasu Jayaraman. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. R. L. McCreery, “Advanced carbon electrode materials for molecular electrochemistry,” Chemical Reviews, vol. 108, no. 7, pp. 2646–2687, 2008. View at Publisher · View at Google Scholar · View at Scopus
  2. D. R. Rolison, “Catalytic nanoarchitectures—the importance of nothing and the unimportance of periodicity,” Science, vol. 299, no. 5613, pp. 1698–1701, 2003. View at Publisher · View at Google Scholar · View at Scopus
  3. F. Li, Q. Qian, F. Yan, and G. Yuan, “Nitrogen-doped porous carbon microspherules as supports for preparing monodisperse nickel nanoparticles,” Carbon, vol. 44, no. 1, pp. 128–132, 2006. View at Publisher · View at Google Scholar · View at Scopus
  4. M. Endo, C. Kim, T. Karaki et al., “Anode performance of a Li ion battery based on graphitized and B-doped milled mesophase pitch-based carbon fibers,” Carbon, vol. 37, no. 4, pp. 561–568, 1999. View at Publisher · View at Google Scholar · View at Scopus
  5. Y. P. Wu, S. Fang, Y. Jiang, and R. Holze, “Effects of doped sulfur on electrochemical performance of carbon anode,” Journal of Power Sources, vol. 108, no. 1-2, pp. 245–249, 2002. View at Publisher · View at Google Scholar · View at Scopus
  6. Y. Shao, J. Sui, G. Yin, and Y. Gao, “Nitrogen-doped carbon nanostructures and their composites as catalytic materials for proton exchange membrane fuel cell,” Applied Catalysis B, vol. 79, no. 1, pp. 89–99, 2008. View at Publisher · View at Google Scholar · View at Scopus
  7. P. H. Matter, E. Wang, and U. S. Ozkan, “Preparation of nanostructured nitrogen-containing carbon catalysts for the oxygen reduction reaction from SiO2- and MgO-supported metal particles,” Journal of Catalysis, vol. 243, no. 2, pp. 395–403, 2006. View at Publisher · View at Google Scholar · View at Scopus
  8. D. Deng, X. Pan, L. Yu et al., “Toward N-doped graphene via solvothermal synthesis,” Chemistry of Materials, vol. 23, no. 5, pp. 1188–1193, 2011. View at Publisher · View at Google Scholar · View at Scopus
  9. S. Yang, X. Feng, X. Wang, and K. Müllen, “Graphene-based carbon nitride nanosheets as efficient metal-free electrocatalysts for oxygen reduction reactions,” Angewandte Chemie International Edition, vol. 50, no. 23, pp. 5339–5343, 2011. View at Publisher · View at Google Scholar · View at Scopus
  10. S. Ma, G. A. Goenaga, A. V. Call, and D.-J. Liu, “Cobalt imidazolate framework as precursor for oxygen reduction reaction electrocatalysts,” Chemistry: A European Journal, vol. 17, no. 7, pp. 2063–2067, 2011. View at Publisher · View at Google Scholar · View at Scopus
  11. D. Geng, Y. Chen, Y. Chen et al., “High oxygen-reduction activity and durability of nitrogen-doped graphene,” Energy and Environmental Science, vol. 4, no. 3, pp. 760–764, 2011. View at Publisher · View at Google Scholar · View at Scopus
  12. Y. Xia and R. Mokaya, “Generalized and facile synthesis approach to N-doped highly graphitic mesoporous carbon materials,” Chemistry of Materials, vol. 17, no. 6, pp. 1553–1560, 2005. View at Publisher · View at Google Scholar · View at Scopus
  13. A. B. Fuertes and T. A. Centeno, “Mesoporous carbons with graphitic structures fabricated by using porous silica materials as templates and iron-impregnated polypyrrole as precursor,” Journal of Materials Chemistry, vol. 15, no. 10, pp. 1079–1083, 2005. View at Publisher · View at Google Scholar · View at Scopus
  14. C.-M. Yang, C. Weidenthaler, B. Spliethoff, M. Mayanna, and F. Schüth, “Facile template synthesis of ordered mesoporous carbon with polypyrrole as carbon precursor,” Chemistry of Materials, vol. 17, no. 2, pp. 355–358, 2005. View at Publisher · View at Google Scholar · View at Scopus
  15. A. Lu, A. Kiefer, W. Schmidt, and F. Schüth, “Synthesis of polyacrylonitrile-based ordered mesoporous carbon with tunable pore structures,” Chemistry of Materials, vol. 16, no. 1, pp. 100–103, 2004. View at Publisher · View at Google Scholar · View at Scopus
  16. M. Kruk, K. M. Kohlhaas, B. Dufour et al., “Partially graphitic, high-surface-area mesoporous carbons from polyacrylonitrile templated by ordered and disordered mesoporous silicas,” Microporous and Mesoporous Materials, vol. 102, no. 1–3, pp. 178–187, 2007. View at Publisher · View at Google Scholar · View at Scopus
  17. W. Li, D. Chen, Z. Li et al., “Nitrogen-containing carbon spheres with very large uniform mesopores: the superior electrode materials for EDLC in organic electrolyte,” Carbon, vol. 45, no. 9, pp. 1757–1763, 2007. View at Publisher · View at Google Scholar · View at Scopus
  18. C. Jeyabharathi, P. Venkateshkumar, M. S. Rao, J. Mathiyarasu, and K. L. N. Phani, “Nitrogen-doped carbon black as methanol tolerant electrocatalyst for oxygen reduction reaction in direct methanol fuel cells,” Electrochimica Acta, vol. 74, pp. 171–175, 2012. View at Publisher · View at Google Scholar · View at Scopus
  19. L. Li, E. Liu, J. Li et al., “A doped activated carbon prepared from polyaniline for high performance supercapacitors,” Journal of Power Sources, vol. 195, no. 5, pp. 1516–1521, 2010. View at Publisher · View at Google Scholar
  20. Z. Lei, M. Zhao, L. Dang et al., “Structural evolution and electrocatalytic application of nitrogen-doped carbon shells synthesized by pyrolysis of near-monodisperse polyaniline nanospheres,” Journal of Materials Chemistry, vol. 19, no. 33, pp. 5985–5995, 2009. View at Publisher · View at Google Scholar · View at Scopus
  21. M. Trchová, E. N. Konyushenko, J. Stejskal, J. Kovářová, and G. Ćirić-Marjanović, “The conversion of polyaniline nanotubes to nitrogen-containing carbon nanotubes and their comparison with multi-walled carbon nanotubes,” Polymer Degradation and Stability, vol. 94, no. 6, pp. 929–938, 2009. View at Publisher · View at Google Scholar · View at Scopus
  22. J. Stejskal and R. G. Gilbert, “Polyaniline. Preparation of a conducting polymer (IUPAC technical report),” Pure and Applied Chemistry, vol. 74, no. 5, pp. 857–867, 2002. View at Google Scholar · View at Scopus
  23. B. Sreedhar, P. Radhika, B. Neelima, N. Hebalkar, and M. V. B. Rao, “Synthesis and characterization of polyaniline: nanospheres, nanorods, and nanotubes—catalytic application for sulfoxidation reactions,” Polymers for Advanced Technologies, vol. 20, no. 12, pp. 950–958, 2009. View at Publisher · View at Google Scholar · View at Scopus
  24. M. Trchová, P. Matějka, J. Brodinová, A. Kalendová, J. Prokeš, and J. Stejskal, “Structural and conductivity changes during the pyrolysis of polyaniline base,” Polymer Degradation and Stability, vol. 91, no. 1, pp. 114–121, 2006. View at Publisher · View at Google Scholar · View at Scopus
  25. J. Stejskal, M. Trchová, and I. Sapurina, “Flame-retardant effect of polyaniline coating deposited on cellulose fibers,” Journal of Applied Polymer Science, vol. 98, no. 6, pp. 2347–2354, 2005. View at Publisher · View at Google Scholar · View at Scopus
  26. J. Stejskal, M. Trchová, J. Brodinová, and I. Sapurina, “Flame retardancy afforded by polyaniline deposited on wood,” Journal of Applied Polymer Science, vol. 103, no. 1, pp. 24–30, 2007. View at Publisher · View at Google Scholar · View at Scopus
  27. X. Zhang and S. K. Manohar, “Microwave synthesis of nanocarbons from conducting polymers,” Chemical Communications, no. 23, pp. 2477–2479, 2006. View at Publisher · View at Google Scholar · View at Scopus
  28. Z. Rozlívková, M. Trchová, M. Exnerová, and J. Stejskal, “The carbonization of granular polyaniline to produce nitrogen-containing carbon,” Synthetic Metals, vol. 161, no. 11-12, pp. 1122–1129, 2011. View at Publisher · View at Google Scholar · View at Scopus
  29. J. Stejskal, M. Trchová, J. Hromádková, J. Kovářová, and A. Kalendová, “The carbonization of colloidal polyaniline nanoparticles to nitrogen-containing carbon analogues,” Polymer International, vol. 59, no. 7, pp. 875–878, 2010. View at Publisher · View at Google Scholar · View at Scopus
  30. J. Cao, J.-Z. Sun, J. Hong, H.-Y. Li, H.-Z. Chen, and M. Wang, “Carbon nanotube/CdS core-shell nanowires prepared by a simple room-temperature chemical reduction method,” Advanced Materials, vol. 16, no. 1, pp. 84–87, 2004. View at Publisher · View at Google Scholar · View at Scopus
  31. M. I. Boyer, S. Quillard, G. Louarn, G. Froyer, and S. Lefrant, “Vibrational study of the FeCl3-doped dimer of polyaniline; a good model compound of emeraldine salt,” Journal of Physical Chemistry B, vol. 104, no. 38, pp. 8952–8961, 2000. View at Google Scholar · View at Scopus
  32. M. Cochet, G. Louarn, S. Quillard, J. P. Buisson, and S. Lefrant, “Theoretical and experimental vibrational study of emeraldine in salt form part II,” Journal of Raman Spectroscopy, vol. 31, no. 12,, pp. 1041–1049, 2000. View at Google Scholar
  33. S. Y. Chee and M. Pumera, “Metal-based impurities in graphenes: application for electroanalysis,” Analyst, vol. 137, no. 9, pp. 2039–2041, 2012. View at Publisher · View at Google Scholar · View at Scopus
  34. G. Socrate, Infrared and Raman Characteristic Group Frequencies, Wiley, 2001.
  35. L. Niu, Q. Li, F. Wei, X. Chen, and H. Wang, “Electrochemical impedance and morphological characterization of platinum-modified polyaniline film electrodes and their electrocatalytic activity for methanol oxidation,” Journal of Electroanalytical Chemistry, vol. 544, pp. 121–128, 2003. View at Publisher · View at Google Scholar · View at Scopus
  36. G. Wu and B.-Q. Xu, “Carbon nanotube supported Pt electrodes for methanol oxidation: a comparison between multi- and single-walled carbon nanotubes,” Journal of Power Sources, vol. 174, no. 1, pp. 148–158, 2007. View at Publisher · View at Google Scholar · View at Scopus
  37. K. S. Ngai, W. T. Tan, Z. Zainal, R. B. M. Zawawi, and M. Zidan, “Electrochemical oxidation of ascorbic acid mediated by single-walled carbon nanotube/tungsten oxide nanoparticles modified glassy carbon electrode,” International Journal of Electrochemical Science, vol. 7, no. 5, pp. 4210–4222, 2012. View at Google Scholar · View at Scopus
  38. J. B. Raoof, R. Ojani, H. Beitollahi, and R. Hossienzadeh, “Electrocatalytic determination of ascorbic acid at the surface of 2,7-bis(ferrocenyl ethyl)fluoren-9-one modified carbon paste electrode,” Electroanalysis, vol. 18, no. 12, pp. 1193–1201, 2006. View at Publisher · View at Google Scholar · View at Scopus
  39. S. A. Wring, J. P. Hart, and B. J. Birch, “Voltammetric behaviour of ascorbic acid at a graphite-epoxy composite electrode chemically modified with cobalt phthalocyanine and its amperometric determination in multivitamin preparations,” Analytica Chimica Acta, vol. 229, no. 1, pp. 63–70, 1990. View at Publisher · View at Google Scholar · View at Scopus