An Empirical Rate Constant Based Model to Study Capacity Fading in Lithium Ion Batteries

<table class="table-group" id="tab4"><tr><td><table class="table"><tr><td class="thead-hr" colspan="2"><hr/></td></tr><tr class="thead"><td align="left">Cell type</td><td align="center"><svg height="11.927pt" id="M41" style="vertical-align:-3.291101pt" version="1.1" viewbox="-0.0498162 -8.6359 13.2655 11.927" width="13.2655pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M593 650H142L136 622C219 616 224 611 209 531L130 120C114 39 108 34 23 28L17 0H501C518 32 557 130 568 158L540 169C519 132 495 93 469 70C439 43 409 35 332 35C272 35 241 37 225 50C211 61 211 89 222 149L253 320H350C441 320 443 312 441 239H471L510 434H481C455 366 448 358 360 358H260L303 572C311 613 312 615 348 615H431C509 615 522 603 532 581C544 555 546 531 545 491L574 493C583 555 592 631 593 650Z" id="g113-70"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="616" vert-adv-y="616"></glyph.data></g><g transform="matrix(.0091,0,0,-0.0091,7.943,3.132)"><path d="M490 97L476 124C442 96 405 70 398 70C392 70 390 78 396 114C419 243 448 379 463 432L457 436C446 436 431 439 418 442C393 447 368 451 343 451C281 451 204 418 155 381C74 320 24 206 24 107C24 23 59 -12 88 -12C118 -12 155 5 191 34C236 70 290 122 328 177H330L312 84C296 0 311 -12 331 -12C355 -12 425 24 490 97ZM374 387C371 367 360 299 347 264C323 202 187 53 142 53C128 53 113 73 113 120C113 224 157 332 221 380C241 395 274 403 303 403C330 403 360 395 374 387Z" id="g50-98"></path><glyph.data ascent="3443" descent="-2856" horiz-adv-x="514" vert-adv-y="514"></glyph.data></g></svg> (kJ mol<sup>−1</sup>)</td></tr><tr><td class="thead-hr" colspan="2"><hr/></td></tr><tr><td align="left">Cylindrical 18650 cell (Sony)</td><td align="center">38.2502</td></tr><tr><td align="left">SAFT DD</td><td align="center">9.4829</td></tr><tr><td align="left">Yardney</td><td align="center">9.4180</td></tr><tr><td align="left">MP</td><td align="center">26.0577</td></tr><tr><td align="left">HE</td><td align="center">23.5943</td></tr><tr class="table-tr"><td colspan="2"><hr class="tbody-hr"/></td></tr></table></td></tr></table>

Reaction activation energies for different battery systems.

International Journal of Electrochemistry

tab4

Table 4

Table 4: An Empirical Rate Constant Based Model to Study Capacity Fading in Lithium Ion Batteries 