Kinetics and Mechanism of Oxidation of Leucine and Alanine by Ag(III) Complex in Alkaline Medium

<table>The second-order rate constant, <svg height="12.8125" id="M32" style="vertical-align:-0.13794pt" version="1.1" viewbox="0 0 12.9375 12.8125" width="12.9375" xmlns="http://www.w3.org/2000/svg">
<g transform="matrix(1.25,0,0,-1.25,0,12.8125)">
<g transform="translate(72,-61.75)">
<text transform="matrix(1,0,0,-1,-71.95,61.94)">
<tspan style="font-size: 12.50px; " x="0" y="0">𝑘</tspan>
</text>
<text transform="matrix(1,0,0,-1,-65.17,67.01)">
<tspan style="font-size: 8.75px; " x="0" y="0"></tspan>
</text>
</g>
</g>
</svg>, as a function of the concentration of <svg height="10.9125" id="M33" style="vertical-align:-0.17554pt" version="1.1" viewbox="0 0 30.8125 10.9125" width="30.8125" xmlns="http://www.w3.org/2000/svg">
<g transform="matrix(1.25,0,0,-1.25,0,10.9125)">
<g transform="translate(72,-63.27)">
<text transform="matrix(1,0,0,-1,-71.95,63.5)">
<tspan style="font-size: 12.50px; " x="0" y="0">O</tspan>
<tspan style="font-size: 12.50px; " x="9.0271664" y="0">H</tspan>
</text>
<text transform="matrix(1,0,0,-1,-53.9,68.67)">
<tspan style="font-size: 8.75px; " x="0" y="0">−</tspan>
</text>
</g>
</g>
</svg> at different temperatures for oxidation of alanine.</table>

International Journal of Inorganic Chemistry

fig4

Figure 4

Figure 4: Kinetics and Mechanism of Oxidation of Leucine and Alanine by Ag(III) Complex in Alkaline Medium 