International Journal of Inorganic Chemistry

Research Article

Syntheses and Crystal Structures of [ C u 3 { 𝜇 - ( N S P h 2 ) 2 N } 2 C l 2 ] and [ C u 3 { 𝜇 - ( N S P h 2 ) 2 N } 2 { ( N S P h 2 ) 2 N } 2 ] C l 2

Table 2

Selected Bond Lenghts ( ) and angles (deg) Compounds 3 and 4.
3
Cu(1)–N(1)1.962(4)Cu(2)–N(3)*2.079(5)
Cu(1)–N(3)1.990(4)S(1)–N(1)1.508(4)
Cu(2)–Cl(1)2.227(2)S(1)–N(2)1.601(5)
Cu(2)–Cl(2)2.196(2)S(2)–N(2)1.597(5)
Cu(2)–N(1)1.975(4)S(2)–N(3)1.503(4)
N(1)–Cu(1)–N(3)97.50(18)N(2)–S(2)–N(3)119.0(2)
N(1)–Cu(1)–N(3)*82.50(18)Cu(1)–N(1)–Cu(2)100.99(19)
Cl(1)–Cu(2)–Cl(2)101.58(8)Cu(1)–N(1)–S(1)124.8(3)
Cl(1)–Cu(2)–N(1)104.63(15)Cu(2)–N(1)–S(1)132.8(3)
Cl(1)–Cu(2)–N(3)*132.08(15)S(1)–N(2)–S(2)118.1(3)
Cl(2)–Cu(2)–N(1)138.61(17)Cu(1)–N(3)–Cu(2)*96.55(18)
Cl(2)–Cu(2)–N(3)*105.00(15)Cu(1)–N(3)–S(2)123.8(3)
N(1)–Cu(2)–N(3)*79.95(18)Cu(2)*–N(3)–S(2)131.9(3)
N(1)–S(1)–N(2)116.5(3)
4
Cu(1)–N(1)1.966(4)S(1)–N(2)1.590(3)
Cu(1)–N(3)1.976(3)S(2)–N(2)1.597(3)
Cu(2)–N(1)*2.014(3)S(2)–N(3)1.480(4)
Cu(2)–N(3)2.012(3)S(3)–N(4)1.472(4)
Cu(2)–N(4)1.915(4)S(3)–N(5)1.590(4)
Cu(2)–N(6)1.913(4)S(4)–N(5)1.586(4)
S(1)–N(1)1.489(3)S(4)–N(6)1.478(4)
N(1)–Cu(1)–N(3)97.50(14)N(5)–S(4)–N(6)123.5(2)
N(1)–Cu(1)–N(3)*82.50(14)Cu(1)–N(1)–Cu(2)*98.69(15)
N(1)*–Cu(2)–N(3)80.42(14)Cu(1)–N(1)–S(1)126.42(19)
N(1)*–Cu(2)–N(4)143.23(19)Cu(2)*–N(1)–S(1)133.5(2)
N(1)*–Cu(2)–N(6)100.69(15)S(1)–N(2)–S(2)119.0(2)
N(3)–Cu(2)–N(4)100.60(16)Cu(1)–N(3)–Cu(2)98.39(15)
N(3)–Cu(2)–N(6)143.14(19)Cu(1)–N(3)–S(2)126.4(2)
N(4)–Cu(2)–N(6)99.65(16)Cu(2)–N(3)–S(2)133.9(2)
N(1)–S(1)–N(2)118.63(18)Cu(2)–N(4)–S(3)125.5(2)
N(2)–S(2)–N(3)118.64(18)S(3)–N(5)–S(4)118.6(2)
N(4)–S(3)–N(5)123.3(2)Cu(2)–N(6)–S(4)125.2(2)
The atom labeling scheme is shown in Figure 1 and 2.