Table of Contents
International Journal of Inorganic Chemistry
Volume 2011 (2011), Article ID 918435, 13 pages
http://dx.doi.org/10.1155/2011/918435
Review Article

The Utility of 2,2′-Bipyrimidine in Lanthanide Chemistry: From Materials Synthesis to Structural and Physical Properties

Ecole polytechnique, LPICM, CNRS UMR 7647, 91128 Palaiseau, France

Received 2 January 2011; Accepted 1 March 2011

Academic Editor: W. T. Wong

Copyright © 2011 Gaël Zucchi. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

This paper reviews the recent investigations undertaken on the use of 2,2′-bipyrimidine (bpm) as a ligand for designing molecular complexes as well as polymeric lanthanide materials. A special emphasis is put on the ability of this polydentate neutral ligand to yield compounds of various dimensionalities, to act as a connector between these large ions, and influence their emissive and magnetic properties. This ligand can adopt a terminal or a bridging coordination mode with lanthanide ions, thus generating a wealth of frameworks of various topologies with the 4f elements. The main focus of this review is to show the originality brought by bpm in lanthanide structural chemistry and solid-state photophysics and magnetism.