Table of Contents
International Journal of Inorganic Chemistry
Volume 2012 (2012), Article ID 608183, 9 pages
http://dx.doi.org/10.1155/2012/608183
Research Article

Kinetic Study of Organic Dye Degradation Using ZnO Particles with Different Morphologies as a Photocatalyst

School of Materials and Mineral Resources Engineering, Universiti Sains Malaysia, Seri Ampangan, 14300 Nibong Tebal, Pulau Pinang, Malaysia

Received 4 November 2011; Revised 15 February 2012; Accepted 20 February 2012

Academic Editor: Wei-Yin Sun

Copyright © 2012 Swee-Yong Pung et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Zinc oxide (ZnO) particles were successfully synthesized via sol-gel approach using zinc acetate dihydrate (Zn(CH3COO)2·2H2O) and ammonia (NH4OH) solution as precursors. By adjusting the reaction parameters such as amount of ammonia and reaction time as well as complexing agent aluminium sulphate Al2(SO4)3, ZnO particles with different morphologies, that is, rodlike, ricelike and disklike could be synthesized. The effectiveness of ZnO particles with different morphologies (rodlike, ricelike and disklike) on the photocatalytic activity has been studied. The results showed that rodlike ZnO particles were the most effective in degrading the Rhodamine B (RhB) solution under the illumination of ultraviolet (UV) light. The rate constant was found to be first order, with rodlike particles the highest (0.06329 min−1), followed by rice-like ZnO particles (0.0431 min−1) and disk-like ZnO particles (0.02448 min−1).