Research Article
Na3MP3O10·12H2O (M = Co, Ni): Crystal Structure and IR Spectroscopy
Table 3
Hydrogen bonding parameters (Å, °) for (1) and (2).
(a) |
| (1) | | | | | | D–H | H⋯A | D–A | D–H⋯A
|
|
O11–H11A⋯O8i | 0.82(3) | 1.92(3) | 2.741(3) | 174(3) | O11–H11B⋯O3i | 0.82(3) | 1.90(3) | 2.707(3) | 169(3) | O12–H12A⋯O2i | 0.82(3) | 1.95(3) | 2.763(3) | 169(3) | O12–H12B⋯O20i | 0.823(19) | 1.87(2) | 2.685(3) | 171(3) | O13–H13B⋯O10ii | 0.83(3) | 1.95(3) | 2.768(3) | 172(3) | O14–H14A⋯O1ii | 0.82(2) | 1.95(2) | 2.757(3) | 167(3) | O14–H14B⋯O1 | 0.83(2) | 1.92(2) | 2.735(3) | 169(4) | O17–H17A⋯O3i | 0.82(3) | 1.95(3) | 2.756(3) | 171(3) | O17–H17B⋯O1iii | 0.82(3) | 1.87(3) | 2.691(3) | 174(4) | O19–H19A⋯O9i | 0.82(2) | 1.96(2) | 2.773(3) | 171(4) | O19–H19B⋯O14iv | 0.820(19) | 1.91(2) | 2.728(3) | 174(3) | O20–H20B⋯O10v | 0.822(14) | 1.893(14) | 2.712(3) | 174(4) |
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(i) , , ; (ii) , , ; (iii) , , ; (iii) , , ; (iv) , , ; (v) , , .
|
(b) |
| (2) | | | | | | D–H | H⋯A | D–A | D–H⋯A |
| O11–H11A⋯O8 | 0.82(3) | 1.91(3) | 2.736(3) | 176(3) | O12–H12A⋯O2 | 0.82(3) | 1.88(3) | 2.760(3) | 173(4) | O12–H12B⋯O20 | 0.82(2) | 1.88(3) | 2.694(4) | 173(4) | O16–H16A⋯O18 | 0.821(16) | 1.965(18) | 2.784(4) | 175(4) |
O18–H18A⋯O21i | 0.82(3) | 1.93(3) | 2.748(4) | 170(3) | O18–H18B⋯O10ii | 0.82(3) | 1.96(3) | 2.775(3) | 177(4) | O19–H19A⋯O9iii | 0.82(3) | 1.96(3) | 2.775(3) | 171(4) | O19–H19B⋯O14 | 0.82(2) | 1.92(3) | 2.735(4) | 174(4) | O22–H22B⋯O13iv | 0.82(3) | 2.01(3) | 2.835(4) | 180(4) |
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(i) , , ; (ii) , ; (iii) , ; (iv) , .
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