Table of Contents
International Journal of Inorganic Chemistry
Volume 2013 (2013), Article ID 281270, 9 pages
http://dx.doi.org/10.1155/2013/281270
Research Article

Synthesis and Characterization of Heteronuclear Copper(II)-Lanthanide(III) Complexes of N,N′-1,3-Propylenebis(Salicylaldiminato) Where Lanthanide(III) = Gd or Eu

Department of Chemistry, Manipur University, Imphal 795 003, India

Received 10 December 2012; Revised 6 April 2013; Accepted 15 April 2013

Academic Editor: Alfonso Castiñeiras

Copyright © 2013 Longjam Jaideva Singh and Rajkumar Hemakumar Singh. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Three complexes, namely, [Cu(salbn)] (1), [Cu(salbn)Gd(NO3)3·H2O] (2), and [Cu(salbn)Eu(NO3)3·H2O] (3) where salbn = N,N′-1,3-propylenebis (salicylaldiminato) have been synthesized and characterized by elemental analyses, ICP-AES, IR, UV, NMR, MS, EDX, powder XRD, and EPR spectroscopies. The EDX results suggest the presence of two different metal ions in heteronuclear complexes (2) and (3). The ligand(salbn), complex (1), and complex (3) crystallize in triclinic system while complex (2) crystallizes in monoclinic system. The EPR studies suggest that [Cu(salbn)] complex is tetragonally coordinated monomeric copper(II) complex with unpaired electron in the orbital and spectral features that are the characteristics of axial symmetry while complex (2) in DMF solution at liquid nitrogen temperature exhibits an anisotropic broad signal around g ~ 2.03 which may suggest a weak magnetic spin-exchange interaction between Gd(III) and Cu(II) ions. The fluorescence intensity of Eu(III) decreased markedly in the complex (3).