Synthesis and Characterization of Heteronuclear Copper(II)-Lanthanide(III) Complexes of N,N′-1,3-Propylenebis(Salicylaldiminato) Where Lanthanide(III) = Gd or Eu
Table 2
Lattice parameter, volume, and figure of merit of ligand(salbn), complex (1), complex (2), and complex (3).
Compound
System
Figure of merit (FOM)
Lattice parameters
Volume ()3
()
()
()
(°)
(°)
(°)
Ligand (salbn)
Triclinic
F(12) = 47.5(0.0097, 26)
15.469(5)
5.085(1)
4.775(9)
74.46
92.66
93.63
361.06
Complex (1)
Triclinic
F(12) = 14.0(0.0094, 91)
12.758(2)
10.523 (2)
3.595(8)
72.15
91.62
94.84
457.88
Complex (2)
Monoclinic
F(12) = 14.2(0.096, 89)
23.016(2)
7.037(7)
16.307(9)
144.31
90.00
90.00
640.87
Complex (3)
Triclinic
F(12) = 14.8(0.0092, 88)
11.331(1)
10.579(1)
7.010(4)
50.33
114.11
122.19
544.33
Salbn: N,N′-1,3-propylenebis(salicylaldiminato); F: figure of merit.
