Table of Contents
International Journal of Inorganic Chemistry
Volume 2013, Article ID 617837, 8 pages
Research Article

Synthesis, Electrochemical, Spectroscopic, Antimicrobial, and Superoxide Dismutase Activity of Nickel (II) Complexes with Bidentate Schiff Bases

1Department of Chemistry, A.P.S. University, Rewa 486003, India
2Department of Chemistry, Govt. Vivekanand P.G. Collage Maihar, Satna 486755, India
3Department of Chemistry, National Institute of Technology, Patna 800005, India

Received 19 August 2013; Revised 1 October 2013; Accepted 3 October 2013

Academic Editor: Rabindranath Mukherjee

Copyright © 2013 R. N. Patel et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Five new nickel (II) complexes, namely, [Ni(L1)2](ClO4)2(1); [Ni(L2)2](ClO4)2(2); [Ni(L3)2](ClO4)2(3); [Ni(L4)2](ClO4)2(4); [Ni(L5)2](ClO4)2(5), where L1 = benzoylhydrazide; L2 = N-[(1)-1-(2-methylphenyl)ethylidene]benzohydrazide; L3=N-[(1)-1-(4-methylphenyl)ethylidene]benzohydrazide; L4=N-[(1)-1-(2-methoxyphenyl)ethylidene]benzohydrazide; L5 = N-[(1)-1-(4-methoxy-phenyl)ethylidene]benzohydrazide, have been synthesized and characterized by various physicochemical and spectroscopic techniques. The synthesized complexes are stable powders, insoluble in common organic solvents such as ethanol, benzene, carbon tetrachloride, chloroform, and diethyl ether, and are nonelectrolytes. The magnetic and spectroscopic data indicate a distorted square planar geometry for all complexes. The superoxide dismutase activity of these complexes has been measured and discussed. Antibacterial and antifungal properties of these complexes were also tested.