Research Article
Synthesis, Crystal Structure, and Antimicrobial Properties of a Novel 1-D Cobalt Coordination Polymer with Dicyanamide and 2-Aminopyridine
Table 2
Selected bond lengths [Å] and angles [°] for [Co(2-ampy)2(dca)2].
| | Co(1)-N(3) | 2.126(2) | N(3)-Co(1)-N(3)#1 | 180.0 |
| | Co(1)-N(3)#1 | 2.126(2) | N(3)-Co(1)-N(5) | 92.28(10) | | Co(1)-N(5) | 2.128(2) | N(3)#1-Co(1)-N(5) | 87.72(10) | | Co(1)-N(5)#1 | 2.128(2) | N(3)-Co(1)-N(5)#1 | 87.72(10) | | Co(1)-N(1)#1 | 2.193(3) | N(3)#1-Co(1)-N(5)#1 | 92.28(10) | | Co(1)-N(1) | 2.193(3) | N(5)-Co(1)-N(5)#1 | 180.00(9) | | N(1)-C(1) | 1.342(4) | N(3)-Co(1)-N(1)#1 | 91.68(10) | | N(1)-C(5) | 1.350(4) | N(3)#1-Co(1)-N(1)#1 | 88.32(10) | | N(5)-C(7) | 1.134(3) | N(5)-Co(1)-N(1)#1 | 92.02(10) | | N(2)-C(1) | 1.360(4) | N(5)#1-Co(1)-N(1)#1 | 87.98(10) | | C(5)-C(4) | 1.364(5) | N(3)-Co(1)-N(1) | 88.32(10) | | C(3)-C(2) | 1.358(6) | N(3)#1-Co(1)-N(1) | 91.68(10) | | C(1)-C(2) | 1.391(5) | N(5)-Co(1)-N(1) | 87.98(10) | | C(7)-N(4)#2 | 1.305(15) | N(5)#1-Co(1)-N(1) | 92.02(10) | | C(7)-N(4′)#2 | 1.313(14) | N(1)#1-Co(1)-N(1) | 180.00(13) | | N(3)-C(6) | 1.127(6) | C(1)-N(1)-C(5) | 116.8(3) | | N(3)-C(6′) | 1.129(6) | C(1)-N(1)-Co(1) | 128.3(2) | | N(4)-C(7)#3 | 1.305(15) | C(5)-N(1)-Co(1) | 114.9(2) | | N(4)-C(6) | 1.324(18) | C(7)-N(5)-Co(1) | 157.7(2) | | N(4′)-C(6′) | 1.310(14) | N(1)-C(5)-C(4) | 124.1(3) | | N(4′)-C(7)#3 | 1.314(14) | N(1)-C(1)-N(2) | 118.3(3) | | C(3)-C(2) | 1.358(6) | N(1)-C(1)-C(2) | 121.9(3) | | C(1)-C(2) | 1.391(5) | N(2)-C(1)-C(2) | 119.8(3) | | | | C(3)-C(2)-C(1) | 119.9(4) |
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Symmetry transformations used to generate equivalent atoms:
#1: , , ; #2: , , ; #3: , , .
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