Table of Contents
International Journal of Inorganic Chemistry
Volume 2015, Article ID 478380, 5 pages
http://dx.doi.org/10.1155/2015/478380
Research Article

Synthesis, Characterisation, Crystal Structure, and Antimicrobial and Larvicidal Studies of [Cu(2,2′-bipy)2SO4]·3CH4N2O·2H2O

Department of Chemistry, DKM College for Women (Autonomous), Vellore 632 001, India

Received 21 August 2014; Accepted 27 November 2014

Academic Editor: Alfonso Castiñeiras

Copyright © 2015 Sundaramurthy Santha Lakshmi and Srinivasan Samundeeswari. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

A pentacoordinated mononuclear copper(II) complex, namely, bis(2,2′-bipyridine)sulphatecopper(II) urea trisolvate dihydrate, has been synthesised and characterised by molar conductance and UV-Vis and FTIR spectra. The structure of the complex was unambiguously confirmed by single crystal XRD. The complex crystallizes in monoclinic system, space group C2/c, with the values (4), (4), and (3) Å; °, °, and °; (2) Å3 and . The Cu(II) ion is coordinated to four nitrogen atoms of two bidentate 2,2′-bipyridine ligands (bipy) and by one oxygen atom of the sulphate group and displays distorted trigonal bipyramidal geometry. The crystal packing is stabilized by inter- and intramolecular hydrogen bonding. The Cu(II) complex was screened for antimicrobial activity against Staphylococcus aureus, Escherichia coli, Klebsiella pneumonia, Aspergillus niger, Aspergillus flavus, and Candida albicans. Larvicidal activity of the synthesized copper(II) complex was carried out against larvae of Culex quinquefasciatus and Anopheles subpictus.