Table of Contents
International Journal of Inorganic Chemistry
Volume 2017 (2017), Article ID 5435436, 12 pages
https://doi.org/10.1155/2017/5435436
Research Article

Microwave-Assisted Synthesis and Characterization of [Rh2(OAc)4(L)2] Paddlewheel Complexes: A Joint Experimental and Computational Study

1Departamento de Química, Sede Pueblito de Rocha, División de Ciencias Naturales y Exactas, Universidad de Guanajuato, 36040 Guanajuato, GTO, Mexico
2Facultad de Química, Ciudad Universitaria, Universidad Nacional Autónoma de México, 04510 Ciudad de México, Mexico

Correspondence should be addressed to J. Oscar C. Jiménez-Halla and Oracio Serrano

Received 7 October 2016; Accepted 27 December 2016; Published 19 March 2017

Academic Editor: Stephen Ralph

Copyright © 2017 Oscar F. Gonzalez-Belman et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The synthesis of four rhodium(II) paddlewheel complexes bearing axial aromatic amines and coumarin ligands, with formula [Rh2(OAc)4(L)2] (L = NH2Mesityl (1), NH2Dip (2), NH2Couma (3), coumarin (4)), prompted by microwave irradiation, was carried out successfully. All of the complexes were characterized by the melting point, elemental analysis, NMR, IR, and UV/Visible spectroscopy. Additionally, the structure of complexes 1-2 and 4 was corroborated by single-crystal X-ray diffraction. Cyclic voltammetry, ESI-MS, and tandem MS analyses were carried out in compound 1 for gaining further insight into its stability. Finally, a DFT study shows that complexes 14 are the thermodynamic products, having as intermediates complexes 1′–4′ which, under our experimental conditions, cannot be isolated.