Kinetics of Thermolysis of Nickel(II) Perchlorate Complex with n-Propylamine

Table 3

Activation energy (𝐸), Arrhenius factor, and correlation coefficients (𝑟) for the isothermal decomposition of the complex.

Serial number	Model	ln𝐴	Slope	𝐸/kJmole^−1	𝑟	Mean deviation	Standard deviation
1	Power law^3/4	1.1382	2128.2	17.7	0.9702	2.728	2.877
2	Power law^2/3	1.2143	1978.1	16.4	0.9641	2.613	2.756
3	Power law^1/2	0.6130	2148.7	17.8	0.9714	2.486	2.628
4	Power law^−1/2	0.0605	2207.1	18.3	0.9740	2.269	2.384
5	Power law^−1	−0.0051	2224.6	18.5	0.9742	2.254	2.378
6	Mampel (1−𝛼)	−1.1053	2275.1	18.9	0.9610	1.755	1.853
7	a-e^3/4	0.7241	2177.1	18.1	0.9748	2.570	2.711
8	a-e^2/3	−0.0275	2249.8	18.7	0.9599	2.268	2.390
9	a-e^1/2	−0.4144	2260.2	18.8	0.9605	2.085	2.201
10	cs	0.2240	2249.1	18.7	0.9686	2.393	2.525
11	T-d-diff	0.2629	2305.1	19.1	0.9614	2.470	2.605
12	cc	0.1869	2223.4	18.5	0.9713	2.349	2.478
13	P-T	−1.6300	2237.5	18.6	0.9592	1.454	1.536
14	G-B	1.2040	2256.1	18.7	0.9698	2.891	3.049