The photocatalytic degradationof EDTA over TiO2 has been analyzed to establish the influence
of oxidants on the reaction rate, the nature of the intermediates and the kinetic regime. Degussa P-25 suspensions
containing EDTA at initial pH 3 in different concentrations were irradiated under near UV light.
A Langmuirian behavior was observed. O2 at saturation concentrations was found to be crucial for EDTA
degradation. The rapid depletion of EDTA was not accompanied by a corresponding TOC decrease, indicating
formation of refractory intermediates. An enhancement in TOC reduction could be achieved by keeping pH
constant or by hydrogen peroxide addition. Addition of Fe(III) caused a remarkable increase on the initial
rate of EDTA consumption and also on TOC decrease. Changes in both parameters clearly increased under
the simultaneous addition of Fe(III) and H2O2, until limiting values.Some of the possible intermediates of EDTA degradation were evaluated in the filtered solution. So far,
glycine, ethylenediamine, ammonium, formaldehyde, and formic, iminodiacetic, oxalic, oxamic, glycolic and
glyoxylic acids have been identified in different proportions, depending on the experimental conditions.
Different degradationpathways are proposed. Inthe presence of Fe(III), photo-Fenton reactions would contribute
also to the degradation process.
