Two-Dimensional Free Energy Surfaces for Electron Transfer Reactions in Solution

Figure 3

First-order ET rate in nonpolar solvent calculated for three values of 𝐸_𝑓∞ with 𝐽₀=100 cm−1 at 6 Å, 𝛽=1 Å−1, 𝑣=1500 cm−1, and 𝜆=0.3 eV. ET occurs at discrete 𝑟 values.