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Chengzhao Chen, Cheng Li, Shihao Huang, Yuanyu Zheng, Hongkai Lai, Songyan Chen, "Epitaxial Growth of Germanium on Silicon for Light Emitters", International Journal of Photoenergy, vol. 2012, Article ID 768605, 8 pages, 2012. https://doi.org/10.1155/2012/768605
Epitaxial Growth of Germanium on Silicon for Light Emitters
This paper describes the role of Ge as an enabler for light emitters on a Si platform. In spite of the large lattice mismatch of ~4.2% between Ge and Si, high-quality Ge layers can be epitaxially grown on Si by ultrahigh-vacuum chemical vapor deposition. Applications of the Ge layers to near-infrared light emitters with various structures are reviewed, including the tensile-strained Ge epilayer, the Ge epilayer with a delta-doping SiGe layer, and the Ge/SiGe multiple quantum wells on Si. The fundamentals of photoluminescence physics in the different Ge structures are discussed briefly.
In the past decades, the zeal for investigating germanium has been stimulated by its novel application in electronic and optoelectronic devices. Due to its superior electron and hole mobility compared to Si, Ge has emerged as a feasible candidate to maintain performance for future electronic applications . In addition, the small direct energy band gap of 0.8 eV at room temperature in Ge makes it possible to design efficient high speed (≥40 GHz) reliable photo-detectors operating in the low-loss optical fiber range of 1.3~1.5 μm [2–4]. Ge layers can also be used in conjunction with advanced gate dielectrics such as HfO2 for the formation of bulk Ge [5, 6] or Ge-on-insulator- (GeOI-) [7–9] based metal oxide semiconductor field effect transistors (MOSFETs) with superior hole mobility. Ge has a relatively small energy difference of 0.14 eV between the indirect L valley and the direct Γ valley. This difference is reduced to ~0.11 eV under the tensile strain as large as 0.2% . In heavily doped n+-Ge, the electron scattering between the Γ and L valleys could be slowed down, showing a bright photoluminescence (PL) in the 1.55 μm range [11, 12] and attempting to achieve an optical gain due to the direct transition in Ge [13, 14]. More recently, light-emitting diodes using Ge pin structures on Si have been demonstrated and the first optically pumped Ge-on-Si laser operating at room temperature was fabricated [15, 16]. Finally, due to their small lattice mismatch with GaAs ( = 0.565785 nm, = 0.56533 nm) and similar thermal expansion coefficients, Ge layers can be used as templates for the growth of GaAs-based heterostructures such as diodes and solar cells , laser diodes , high electron mobility and heterojunction bipolar transistors [19, 20].
However, the central issue in obtaining useful Ge films on Si is overcoming the negative effects of the difference in thermal expansion coefficient and the large lattice mismatch (4.2% at 300 K) between these two materials, which cause (i) a high density of misfit dislocations at the interface and a high threading dislocation density (TDD) in the Ge layers, which severely affects the performance of Ge devices because of the recombination centres that are introduced along these dislocations, and (ii) high surface roughness due to island growth, making subsequent device processing very difficult because complementary metal-oxide-semiconductor (CMOS) devices require planar processing. Many recent studies have explored the deposition of Ge films on Si. For example, a method using graded SiGe buffer layers reduced the TDD to the range of 106~107 cm−2 . However, a 10 mm-thick graded layer was required to achieve the 106 cm−2 defects level, and this had to be followed by chemical mechanical polishing to obtain a smooth surface, which is not appropriate for monolithic integration of devices on Si and has poor thermal conduction. An advantage of the low-energy plasma-enhanced chemical vapour deposition (LEPECVD) technique is the high growth rate achievable on the order of 4 nm/second, allowing thick SiGe-graded buffer layers to be grown faster than by other epitaxial techniques and thereby increasing throughput in order to make such structures more manufacturable, and therefore relaxed Ge on a silicon substrate with a threading dislocation density of 1 × 105 cm−2 was achieved . Direct pure Ge deposition on Si has been done with cyclic thermal annealing with a reduced pressure CVD system, which reduces the TDD (6 × 106 cm−2 with 2.5 mm-thick Ge layer) and also creates rather smooth surface roughness (root-mean-square (RMS) surface roughness : ~1 nm) [2, 23]. Nayfeh et al. showed that high-temperature (HT) hydrogen annealing following low-temperature (LT) deposition (400°C) reduced the surface RMS roughness from 24 to 2.9 nm with a 155 nm-thick sample . Liu et al.  proposed a defect-necking technique, which confines the defects to short distances by patterning Ge films followed by a conformal low-temperature oxide (LTO) deposition by low pressure chemical vapor deposition (LPCVD) at 300°C. Vanamu et al.  have reported that high-quality Ge layers, with dislocation density consistently lower than 5 × 105 cm−2, grew on nanostructured Si substrates, which were fabricated by using interferometric lithography combined with reactive ion etching and thermal oxidation methods. Most results have, however, shown that obtaining low TDD and a smooth surface layer at the same time is still very problematic.
2. Epitaxial Growth of Ge on Si with Low Dislocation Density
High-quality epitaxial growth of Ge on Si has been realized by using an ultrahigh-vacuum chemical vapor deposition (UHV/CVD) technique. Langdo et al.  showed that pure Ge grown selectively on SiO2/Si substrates in 100 nm holes is highly perfect at the top surface compared to conventional Ge lattice-mismatched growth on planar Si substrates. This result is achieved through a combination of interferometric lithography SiO2/Si substrate patterning and ultrahigh vacuum chemical vapor deposition Ge selective epitaxial growth. This “epitaxial necking,” in which threading dislocations are blocked at oxide sidewalls, shows promise for dislocation filtering and the fabrication of low-defect density Ge on Si. Defects at the Ge film surface only arise at the merging of epitaxial lateral overgrowth fronts from neighboring holes. Luan et al.  reported that the smooth Ge layer on Si is available using a UHV/CVD growth with a low-high temperature two-step growth technique, which is now employed in the worldwide. In this technique, contrary to the thick SiGe-graded buffer approach, a pure Ge heterolayer as thin as 30 nm, is deposited directly on Si at a low temperature of 300~400°C, followed by a higher-temperature growth (typically 600°C) with a larger growth rate. The low-temperature Ge buffer layer prevents the three-dimensional nucleation of Ge. Recently, Loh et al.  reported a modified two-step growth approach, that is, growing an ultrathin (2~30 nm) LT SiGe buffer layer prior to the deposition of LT Ge seed layer and HT Ge layer. With the help of LT SiGe layer to absorb partially misfit strain, provide Ge nucleation sites, and coalesce dislocations, the TDD can be reduced to 6 × 106 cm−2, without any thermal annealing.
Recently, we investigate the growth of the Ge epilayer on Si by UHV/CVD combined with the advantages of the low-temperature buffer layer and strained layer superlattices (SLSs). In the initial growth step, a thin epitaxial Ge buffer layer of 80 nm was directly grown on Si at 350°C. After that, 220 nm HT Ge layer was grown at 630°C and then 3-period SiGe/Ge-strained layer superlattices (SLSs) was introduced as an intermediate layer for further improving the quality of the top Ge layer. Finally, the growth temperature in the main growth step was increased to 630°C to achieve higher growth rates and better crystal quality. The high-quality Ge epilayer on Si was achieved with a surface RMS roughness of less than 1 nm and a TDD of 1.5 × 106 cm−2.
Figure 1 shows cross-sectional transmission electron microscope images of Ge-on-Si by the typical and our modified two-step methods. It can be seen in Figure 1(a) that most of misfit dislocations are confined at the LT-Ge and Si interface as shown in the inset. Some of them thread upward and generate threading dislocations at the surface and then a number of them meet and annihilate in the region of HT-Ge layer close to the LT-Ge interface. Figure 1(b) clearly shows that the dislocations start at the bottom interface and propagate toward the upper layer till the annihilation reactions occurred, and there is almost no dislocation threading from the first HT-Ge layer to the HT-Ge epilayer. The observation indicated a possible way for dislocation reduction: the separated threading dislocations are driven by the force as a result of the strain accumulated in the SiGe/Ge SLSs and coalesces or annihilation in the end. The TEM observations in Figure 1 confirm that a further reduction of threading dislocations can be achieved by combining with the advantages of low-temperature buffer layer and strained layer superlattices.
The strain status and crystal quality of Ge layers were evaluated by double crystal XRD measurement (Bede, D1 system), using a Cu Ka1 (λ = 0.15406 nm) as the X-ray source. The Ω-2θ symmetric (0 0 4) XRD scan of Ge epilayer is shown in Figure 2, including the result of the simulation of the XRD patterns based on the dynamical diffraction theory. Besides the peak originating from the Ge layer, multiple high order superlattice satellites are also clearly observed for the sample, suggesting the interface between Ge layers and SiGe layers sharp and clear. The peak distance between Ge epilayer and Si is 5525. This value is smaller than the expected one between the fully relaxed Ge and Si. According to Bragg’s law with λ = 0.15406 nm for CuKa1 radiation, the peak distance is 5649 arc sec with the relaxed lattice constants 0.5431 and 0.5658 nm for Si and Ge. The smaller peak distance between epitaxial Ge and Si substrate indicates that the epitaxial Ge layer is under tensile strain . From the peak positions, the in-plane lattice constant is evaluated to be 0.5674 nm for the sample, corresponding to the in-plane tensile strain of 0.13%. The strain in the Ge epilayer mainly arises from the differences in the thermal expansion coefficients between Ge and Si and accumulates in the layers during cooling process from elevated growth temperature to room temperature. Figure 3 shows the atomic force microscope(AFM) image of the sample. The surface is found to consist of step and terrace structures, indicating the two-dimensional layer-to-layer growth. A small RMS surface roughness of 0.45 nm is obtained.
Figures 4(a) and 4(b) show depth profile of TDD in the Ge epilayer on Si substrate and several typical optical images at various depths in the sample after etched by I2 solution (HF : HNO3 : CH3COOH : I2 = 10 mL : 40 mL : 100 mL : 30 mg) for EPD counting. It is found that TDDs weakly depend on the etch depth when the retained Ge layer is larger than 80 nm from SLSs and only the size of the etch pits become larger with increasing etch depth. The typical TDD is in a range of 1.49 × 106 cm−2~1.53 × 106 cm−2. When the Ge layer is etched to be left less than 270 nm from the Si substrate, TDDs in the first HT-Ge layer increase quickly to larger than 1 × 108 cm−2 (limitation of EPD method), and the surface morphology image shown as Figure 4(c). The results indicate that the SLSs can partly filter the thread dislocations, in accordance with the TEM analyses.
3. Ge on Si for Light Emitters
The realization of silicon photonics requires a Si-based light emitter capable of integration with electronic integrated circuits. Ge has been proposed as a very promising candidate to make such a light emitter for Ge is a Si compatible material and a pseudodirect gap behavior because the energy difference between its direct and indirect bandgaps is only 136 meV at room temperature. Ge is normally recognized as a poor light-emitting material due to its indirect band structure. The radiative recombination through indirect transition is inefficient as a result of a phonon-assisted process. Therefore, indirect gap PL was only observed from high-purity single crystalline bulk Ge at cryogenic temperatures. The direct transition in Ge, on the other hand, is a very fast process with radiative recombination rate of four and five orders of magnitude higher than that of the indirect transition, so that the direct gap light emission of Ge is as efficient as that of direct gap III–V materials. The challenge is to have a sufficient number of electrons in the direct valley of the conduction band because most of the electrons are pumped into the lower energy indirect L valleys (fourfold degenerate) following the Fermi distribution.
To turn Ge into an efficient light-emitting material, we have to compensate for the difference between the direct and indirect bandgaps. It has been demonstrated that this difference can be decreased by introducing tensile strain into the Ge layer, and it has been applied to improve the performance of Ge light emitting on Si. Another strategy is to compensate for the rest of the energy difference by n-type doping to fill electrons into the L valleys up to the level of the Γ valley. With these methods, the tensile-strained n-type Ge effectively provides for population inversion in the direct bandgap, leading to strong light emission from its direct bandgap transitions.
The band structure of bulk Ge is schematically shown in Figure 5(a), with a 0.664 eV indirect band gap at the L valleys and a 0.800 eV direct bandgap at the Γ valley. Under the tensile strain, the direct bandgap energies of Ge are reduced. Figure 6 shows a calculation result based on the deformation potential theory . Photoluminescence of the samples of tensile strained Ge grown on Si substrate, as well as bulk Ge is shown in Figure 7. It is observed that PL main peak of the tensile-strained Ge shifts to the low energy comparing to that of the bulk Ge . This result demonstrates that the tensile-strain in the Ge epitaxial layer induces the reduction in direct band gap.
An enhancement of the direct bandgap photoluminescence from Ge layer on silicon with boron or phosphorous delta-doping SiGe layers at room temperature is reported . The n-type delta-doping SiGe layer is proposed to transfer extra electrons to L valley in Ge, which decreases the possibility of the excited electrons in the delta valley to be scattered to the L valley and improves the photoluminescence of the direct band transition in the Ge layer. While precluding the introduction of additional nonradiative recombination centers in the Ge layer.
Room temperature PL spectra of the samples with p- or n-delta-doping SiGe are shown in Figure 8. The PL signal is enhanced by a factor of 1.3 for the sample with the p-type delta-doping SiGe layer and 1.6 for the sample with the n-type doping SiGe layer compared to that of the sample with the undoped SiGe layer. The shape and full width at half maximum (FWHM) of the luminescence spectra of the samples with the doped or undoped SiGe layer is almost the same, suggesting that the luminescence of all the samples should be ascribed to the same origin. In order to well understand the enhancement of luminescence from Ge with the delta-doping SiGe layers, the bandgap structure was calculated by effective mass approximation method including the strain affects in Ge and SiGe layers. Because of the requirement of the same Fermi levels in equilibrium, the activated holes in the boron-doped SiGe layer will transfer to the Ge layer and occupy the top of the valence band, which will induce the band bending near the interface and increase the possibility of the direct band transitions of the laser-excited electrons in the Γ valley due to the coulomb interaction. This results in a little bit enhancement of luminescence. For the sample with the phosphorous delta-doping SiGe layer, the Fermi level is under the indirect conduction band (L valley) with the doping concentration of 5 × 1017 cm−3 in the SiGe layer, the electrons in the SiGe layer will transfer and then be confined in the Ge well by the potential barrier of several tens meV due to the energy band shift of the Ge/SiGe heterostructure. The confined electrons will naturally occupy the L valley in the Ge layer. The electron preoccupation of the L valley will significantly decrease the possibility of the excited electrons in the Γ valley to be scattered to the L valley and increase the possibility of direct band transitions, as schematically described in Figure 9. This will result in more effective enhancement of luminescence from Ge layer with the n-type delta-doping SiGe layer than that with the p-type delta-doping or undoped SiGe layers. Inserting an n-type delta-doping SiGe layer is different from the directly doped Ge and also effective to provide electrons to the Ge layer and exclude the introduction of extra-nonradiative centers resulting in the improvement of PL from Ge.
We directly demonstrate quantum-confined direct band transitions in the tensile strained Ge/SiGe multiple quantum wells grown on silicon substrates by room temperature photoluminescence . It is indicated that the photoluminescence peak energy of the tensile-strained Ge/SiGe quantum wells shifts to higher energy with the reduction of thickness of Ge well layers. This blue shift of the luminescence peak energy can be quantitatively explained by the direct band transitions due to the quantum confinement effect at Γ point of conduction band.
Figure 10 depicts the cross sectional HRTEM images of the sample with 6 periods of Ge/SiGe MQW on Ge-on-Si substrate. It indicates that the surface is smooth and few of dislocations in the Ge/SiGe MQW are observed in the TEM images. The perfect lattice match at the Ge/SiGe interface as shown in the inset suggests that the alternating growth of SiGe and Ge layers is pseudomorphic. Room temperature photoluminescence of the samples with tensile-strained Ge/SiGe MQW on silicon substrates was shown in Figure 11(a). The spectra of the direct band luminescence from all of the samples show broad bands with the distorted shape in the range of 0.85 eV~0.92 eV. The distortion of the photoluminescence spectra can be attributed to the atmospheric water absorption, as reported in . To eliminate the effect of the atmospheric water absorption on the determination of the peak energy, we fit the direct band photoluminescence spectra following the processes described in  and shown in Figure 11(a), as dashed lines. It is clearly shown that the peak energy decreases with the increase of the thickness of Ge quantum well layers. Also shown in Figure 11(b) is the fitted photoluminescence peak energy from the samples, which is in good agreement with the theoretical calculation. Those results demonstrate that the room temperature photoluminescence is originated from the quantum-confined direct band transitions in the tensile-strained Ge wells and the peak energy shift results from the increase of energy separation at Γ point in the tensile strained Ge/SiGe MQW. It is suggested that the tensile-strained Ge/SiGe MQW on Si substrate is one of the promising materials for Si-based integrated photonic devices.
The possible applications of Ge on Si to active photonic devices of light emitters were reviewed in addition to the high-quality growth of Ge on Si. The high-quality Ge epilayer on Si was achieved with a surface RMS roughness of less than 1 nm and a TDD of 1.5 × 106 cm−2. Room temperature photoluminescence spectra due to direct band transitions in the tensile-strained Ge epilayer, the Ge eiplayer with a delta-doping SiGe layer and the Ge/SiGe multiple quantum wells on Si are observed. Those results suggest that Ge will play a significant role as an enabler for intergrating active photonic device on Si.
This paper was supported by the National Basic Research Program of China (Grant no. 2007CB613404), the National Natural Science Foundation of China (Grant nos. 61036003, 60837001, and 61176092), the Fundamental Research Funds for the Central Universities (Grant no. 2010121056), and the National Basic Research Program of China (Grant no. 2012CB933503).
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