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International Journal of Photoenergy
Volume 2012, Article ID 907290, 5 pages
Research Article

Synthesis of Hollow CdS-TiO2 Microspheres with Enhanced Visible-Light Photocatalytic Activity

The Education Ministry Key Lab of Resource Chemistry, Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, China

Received 20 January 2012; Accepted 20 February 2012

Academic Editor: Weifeng Yao

Copyright © 2012 Yuning Huo et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


CdS-TiO2 composite photocatalyst in the shape of hollow microsphere was successfully synthesized via the hard-template preparation with polystyrene microspheres followed by ion-exchange approach. The hollow CdS-TiO2 microspheres significantly extended the light adsorption into visible light region, comparing to TiO2 microspheres. It led to much higher photocatalytic activities of hollow CdS-TiO2 microspheres than that of TiO2 during the photodegradation of rhodamine B under visible light irradiations. Furthermore, the well-remained hollow structure could achieve light multireflection within the interior cavities and the separation of photo-induced electrons and holes is efficient in CdS-TiO2, which were facilitated to improving the photoactivity.