New Method of Depositing the Nanostructured Amorphous Carbon for Carbon Based Solar Cell Applications

Fadzilah, A. N.; Dayana, K.; Rusop, M.

doi:https://doi.org/10.1155/2013/784743

International Journal of Photoenergy

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Abstract Introduction Methods Results and Discussion Conclusion References Copyright Related Articles

Research Article | Open Access

Volume 2013 | Article ID 784743 | https://doi.org/10.1155/2013/784743

New Method of Depositing the Nanostructured Amorphous Carbon for Carbon Based Solar Cell Applications

A. N. Fadzilah,¹K. Dayana,¹and M. Rusop²

Academic Editor: Vincenzo Augugliaro

Received07 Mar 2013

Revised25 Apr 2013

Accepted25 Apr 2013

Published19 May 2013

Abstract

Nanostructured amorphous carbon (a-C) solar cells were successfully deposited via a self-designed aerosol-assisted chemical vapor deposition (AACVD). The fabricated solar cell with the configuration of Au/p-C/n-Si/Au achieved efficiency () of % for device deposited at 500°C, % for 450°C, and % for 400°C. Photoresponse characteristic was highlighted under illumination (AM 1.5 illuminations: 100 mW/cm², 25°C), where conductivity increased when the sample was being hit by light. Transmittance spectrum exhibits a large transmittance value (85%) and absorption coefficient value of cm⁻¹ at the visible range from 390 to 790 nm. The nanostructured a-C thin film deposited at higher temperature possesses lower transmittance due to higher absorption as a result of the higher content of sp²-bonded carbon atoms. From Tauc’s plot, optical band gap () was determined, and decreased as deposition temperature increased (1.2 eV, 1.0 eV, 0.7 eV). On the other hand, FESEM images exhibited a nanostructured sized a-C with the particle size less than 100 nm. To the best of our knowledge, the presence of nanostructured particle of a-C by a self-prepared AACVD has not frequently been reported.

1. Introduction

Amorphous carbon (a-C) thin films were extensively studied in the last two decades due to many superior properties such as high mechanical hardness, chemical inertness, and optical transparency [1]. This structure based on carbon materials has attracted a great interest for the potential applications in optoelectronic devices especially in the development of the photovoltaic solar cell, due to the fact that the cost in heterojunction solar cell using silicon is much higher to meet the daily life expectations. Nanostructured a-C is a potential candidate for the solar cell application due to its semiconducting nature which is able to accept dopants [2], wide band gap from 0.0 eV to 5.5 eV [3], and tunable band gap by adjusting the sp² and sp³ of carbon bonding ratio [4]. On the other hand, nanostructured a-C have the advantage over the conventional silicon in photovoltaic due the usage of silicon at a long period of time that leads to the degradation process which limits its lifetime and stability [5].

Prior to the interest in nanostructured a-C utilization for wide range of applications, several techniques were developed to synthesize the nanostructured a-C including pulsed laser deposition (PLD) method [3], pulsed filtered cathodic method [6], and filtered cathodic vacuum arc method [7] which are generally expensive because they involve the use of sophisticated reactors and vacuum systems. On the other hand, the chemical vapor deposition (CVD) technique which involves homogenous and heterogenous chemical reaction of gaseous reactants was also being utilized in the fabrication of nanostructured a-C. However, several limitations has been experienced by researchers in utilizing the CVD method in terms of selection and delivery of multicomponent products, the lack of proper volatile precursor, and the difficulty in controlling the stoichiometry of the deposition [8]. In pursuit of producing high electrical conductivity of nanostructured a-C, the conventional CVD process was self-modified into aerosol-assisted CVD (AACVD), where this method uses the aerosol droplets to transport the precursor, with the aid of carrier gas (inert gas).

AACVD method was widely used in the fabrication by other researchers, such as to fabricate the ZnO [9] and InMe₃ [10]. In addition, Salaün et al. [11] have shown the successful deposition of nanoparticles using AACVD technique, where the incorporation of nanoparticles in thin film fabrication is important due to their functional properties in electronics, sensors, glass, catalysis, and semiconducting applications. Thus, by considering the successful fabrication of other materials using the low-cost aerosol-assisted method, this technique was implied in the preparation of the semiconducting nanostructured a-C thin film for the environmentally safe carbon-based thin film for solar cell application. Considering the advantages of AACVD as the deposition method, this technique was implied in the preparation of the semiconducting nanostructured a-C thin film for the environmentally safe carbon-based solar cell application. The electrical, optical, and solar cell performances were discussed in this paper.

2. Methods

Camphor oil (C₁₀H₁₆O) was chosen as the precursor due to its advantageous over any other precursor, as the single camphor molecule contains 9 sp³ carbon atoms [12]. Corning glass (thickness: 1 mm) and n-Si (100) (thickness 525 ± 25 μm, resistivity 1–10 Ω cm) were used as the substrates. Glass substrates have been cleaned in acetone (C₃H₆O) followed by methanol (CH₃OH) for 10 min, respectively, using an ultrasonic cleaner (Power Sonic 405) to eliminate contaminations. In the case of n-Si substrate cleaning, the cleaning step was further continued with the diluted hydrofluoric acid which plays an important role in removing the resistive element of the substrate. Finally the substrate was blown with nitrogen gas (N₂).

The depositions of nanostructured a-C thin films were carried out using the combination of aerosol-assisted system and CVD with two furnace systems. Camphor oil was heated at the aerosol-assisted system in a close environment (to ensure the desired temperature) at 180°C to make certain of the transformation of the camphor oil in liquid phase into vapours. A double furnace setup of thermal CVD was connected next to the aerosol-assisted setup, where the deposition took place. Argon gas (30 bubbles/min) was selected as the carrier gas, and the quartz tube was kept inside a horizontal tubular furnace. AACVD process includes the atomization of a liquid precursor solution (camphor oil) into fine submicrometer-sized aerosol droplets that distribute throughout the gaseous medium in the CVD with the aid of Ar gas as the carrier gas. Temperature of the furnace was elevated from room temperature to desired deposition temperature under argon atmosphere. Gold (Au) which is a known conductor material was sputtered on the top and bottom of nanostructured a-C thin films by using the sputter coater system. The nanostructured a-C thin films was characterized by PerkinElmer Lambda- 60 mm PbS module integrating sphere relative specular reflectance ACCY- 6DE spectroscope for optical propertie, Bukoh Keiki CEP2000 solar simulator system for electrical properties, and JEOL JSM-7600F field emission scanning electron microscope (FESEM) to determine the particle size.

3. Results and Discussion

Nanostructured amorphous carbon (a-C) films were deposited on n-Si and glass substrate at 3 different deposition temperatures, 400°C (sample A), 450°C (sample B), and 500°C (sample C). To study the electrical properties of nanostructured a-C thin films, the measurement was carried out using Bukoh Keiki CEP2000 solar simulator system in the range from −8 to 8 V to obtain the graph as in Figure 1, and the value of resistivity () and conductivity () was calculated from the value of resistance using, where is the resistivity, is the conductivity, is the width of electrodes, is the thickness of nanostructured a-C thin film, and is the distance between the electrodes. As shown in Figure 1, the linear graph shifted upward as deposition temperature increased, showing low electrical resistance of sample deposited at higher temperature. However, all the samples with low-resistive linear current voltage indicate good ohmic contact. These measurements prove that the graphitic behavior within the nanostructured a-C is able to serve as conductive channels for the transport of electrons [13]. The electrical conductivity, , was plotted as in Figure 2, and it was observed that the sample with sharp slope (sample C) has the highest . The measurement was done in dark and under illumination condition AM 1.5 illumination (100 mW/cm², 25°C). The thickness of the thin films was evaluated from the DEKTAK VEECO 150 surface profiler, and it was noted that as deposition temperature increased the thickness also increased (42, 54 and 67 nm).

Without light irradiation, the in dark conductivity () value starts from 1.04557 × 10⁻⁴ Scm⁻¹ for sample A, increases gradually to 1.35543 × 10⁻⁴ Scm⁻¹ at sample B, and increases sharply at sample C (2.60586 × 10⁻⁴ Scm⁻¹). The conductivity value is higher in comparison with the reported value by Panwar et al. [7] and Dwivedi et al. [14] and is similar to that reported by Alibart et al. [15] and Ben Karoui et al. [16]. Even though the conductivity value was not extremely high, the value was comparable with the conductivity reported for the solar cell application. To explain the conductivity trend, carrier concentration and carrier mobility play the significant role in determining the value of electrical conductivity [15]. Thus it is reported that when thickness increases, the carrier concentration and carrier mobility will increase along [17], and this explains the high conductivity of sample deposited at higher temperature since the thickness increased and can be seen by naked eyes. Other than that, nanostructured a-C conductivity is also attributed by the presence of (sp² graphitic bonding) and (sp² and sp³ diamond bonding). As temperature increases the intensity of region increases, specifying the promotion of sp² bonding due to the increase in graphitic order [18].

Under AM 1.5 illumination (100 mW/cm², 25°C), samples A–C observed the same conductivity trend, but with higher value. The under illumination conductivity () value starts from 1.26746 × 10⁻⁴ Scm⁻¹ for sample A increases gradually to 2.56846 × 10⁻⁴ Scm⁻¹ at sample B, and increases sharply at sample C (3.27256 × 10⁻⁴ Scm⁻¹). Shifting upwards condition of to symbolize the photoresponse characteristic of nanostructured a-C [12]. As one of the potential material for solar cell application, the photoresponse characteristic is highly observed. When being illuminated, the electron-hole pairs that are separated by the electric field between the electrodes from the light absorption will generate the current flow [19]. Current flow is the result of the photoexcited carriers drift before recombination.

Optical properties was investigated by a PerkinElmer Lambda- 60 mm PbS module integrating sphere relative specular reflectance ACCY- 6DE spectroscope measurement for the samples deposited on the glass substrates. The highest transmittance was indicated at sample A followed by B and C. Considering that by naked eyes sample C is darkest and thickest compared to sample A and B, the UV-vis-NIR spectroscope measurement confirmed the condition. At the visible range from 390 to 790 nm (from 1.56 to 3.18 eV), transmittance for sample A is above 95%, sample B 85–95%, and sample C increase from 60% to 90%. Han et al. [20] in the reports on solar cell discussed the suitability of having high transmittance (>85%) at visible range since the reflection at the surface was suppressed. The transmittance obtained is considered high compared to the other reported value for solar cell application, aluminum-doped zinc oxide (ZnO:Al) [21], and Vanadium pentoxide (V₂O₅)/Ag/V₂O₅ [22].

The absorption coefficient () was calculated by the optical transmittance spectra of the film and the film thickness data, which indicates the measurement on how far the light with a specific wavelength or energy can penetrate into the thin film before being absorbed by that film. The of nanostructured a-C thin films could be calculated by Lambert’s law using where is the thickness and is the transmittance of the film. Figure 3 shows the variation of the absorption coefficient as a function of photon energy. As shown in Figure 3, value is approximately ~10⁴ cm⁻¹ and in the range reported by others [23, 24]. The highest value of in sample C is due to the narrow optical band gap from Tauc plot [25]. The optical band gap is the measure of the gap between the extended state in the valence band and the conduction band. Highest band gap was noted at sample A (1.2 eV) followed by sample B (1.0 eV), and the smallest was sample C (0.7 eV). The largest optical band gap is correlated with the amount of sp³ carbon bonding inside the nanostructured a-C and supports the electrical conductivity discussed above.

The surface morphology images were captured by the JEOL JSM-7600F field emission scanning electron microscope (FESEM) at 100 kx magnification, 10 kV electron high tension (EHT). Figures 4(a), 4(b), and 4(c) represent the FESEM images for sample A, B, and C. The samples have the small average grain size, which was approximately ~50 nm. For particles with the size of less than 100 nm, it was said to have the nanostructured sized particles. For sample A, the image was really in amorphous nature, since no sharp images were determined. However, we still manage to obtain the small particle size of sample A. When deposition temperature increased at sample B, more regular pattern was exhibited; however, the particles seem to be agglomerated. Next at sample C, clear shapes were seen, still with the amorphous behavior. At sample C, the particles were becoming more cylindrical in shapes and differed from the previous samples. With increasing deposition temperature, the particle seems to migrate and perform more accurate shapes. The film’s surface morphology were influenced by the charge carrier mobility and absorption spectra [26]. Thus, the connection between the electrical and optical behavior towards the surface morphology was observed.

(a) Sample A

(b) Sample B

(c) Sample C

The presentation of nanostructured material in solar energy conversion was extensively studied by Oelhafen and Schüler [27], where it describes on the dye sensitized solar cell in nanoscale form and the application of nanostructured a-C: H/Au in the solar cell. Nanostructured thin films such as the nanostructured a-C has been studied in this paper plays the role as optically selective absorber layer for the carbon-based solar cell application. For the nanostructured material, the optical absorption path is much larger [28]; thus when light strikes the thin film, the absorption coefficient will greatly increase. Secondly, the nanostructured behavior of the thin film will enable the absorber layer to be designed very thin; thus the light-generated electrons and holes will only have to travel over much shorter path, and thus the recombination losses are greatly reduced [29]. Thirdly, since the size of the nanoparticles is very small and in nanoscale, the energy band gap can be tailored by varying the size of the nanoparticles. Thus more designs of the absorber layers in the solar cell can be done [28]. Those factors have become the fundamental properties of the nanostructured materials to be studied for numerous potential application especially in photovoltaic field [30, 31].

Deposition of nanostructured a-C on n-Si substrate is needed to determine the suitability of nanostructured a-C to create a heterojunction structure between p-n junctions. By using the AACVD method, the nanostructured a-C which is naturally p type was fabricated on n-Si substrate, and the characteristics were measured by a Bukoh Keiki CEP2000 solar simulator system as shown in Figures 5(a) and 5(b). Gold (Au) as the electrode in Au/p-C/n-Si/Au was deposited by using sputter coater system (thickness 60 nm at bottom and 15 nm at top). The contacts served as an active area for the cells of configuration Au/p-C/n-Si/Au.

(a)

(b)

By varying the deposition temperature, the fabricated solar cell was characterized in dark and under illumination conditions. In a dark surrounding, the cell shows very slight rectifying characteristic (Figure 5(a)). However, all the samples indicate 0% for fill factor (FF) value. Thus, the solar cell efficiency [32] where is the overall efficiency, is the short circuit current density, is the open circuit voltage, and is the incident photon flux which was determined to be 0% for all samples. However, when being illuminated under AM 1.5 SUN condition (100 mW/cm², 25°C) a rectifying curve was obtained as in Figure 5(b). Thus these rectifying curves signify a heterojunction between the p-type nanostructured a-C film and the n-Si substrate [33, 34].

The fabricated solar cell with the configuration of Au/p-C/n-Si/Au achieved efficiency () of 1.72 × 10⁻⁴% for sample C, 1.24 × 10⁻⁴% for sample B, and 0.03 × 10⁻⁴% for sample A. Open circuit voltage and short circuit current density vary from 0.06 to 0.13 V and from 0.000078 to 0.02 mA/cm², respectively. Details on the solar cell performance were tabulated in Table 1. Obviously there was a trend in efficiency value which could be observed from the graph in Figures 5(a) and 5(b) since the efficiency increased along with the deposition temperature (thickness increased as deposition temperature increased). The efficiency is still low compared to other reported carbon solar cell with same configuration [35–37], but the value is comparable as reported by Yap et al. [24] and Umeno and Adhikary [38]. Thus the presence of efficiency value clarified the tendency of using the nanostructured a-C by AACVD as the absorber layer in carbon based solar cell.

The mechanism of electron movement in Au/p-C/n-Si/Au will be explained. The n-Si becomes a depletion layer by performing p-n abrupt junction, and the nanostructured a-C film plays the role of electron-transporter and holes blocking film. Few photons emitted from the xenon lamp AM1.5 illumination (100 mW/cm², 25°C) were absorbed by the nanostructured a-C thin film, and many photons were absorbed by the n-Si surface layer, thus generates the electron-hole pair. The Au will then receive the electrons drifted from the nanostructured a-C film, where at first the electrons were excited in conduction band of n-Si and were being transferred to the nanostructured a-C films. The holes excited in the valence band of n-Si will flow back to the n-Si substrate and drift to Au contact. The generation of the electron-hole pair as well as the electrons and holes drifting creates the current with high efficiency. The sp² carbon bonding inside the nanostructured a-C film contributes to the transport of electrons by hopping to the Au contact [34, 39] and acts as the holes barrier to prevent the holes injection. As deposition temperature increased, the thickness increased and the resistivity decreased (sp² increase). Thus the photogenerated carriers could be easily transported to the Au electrode and lead to increasing efficiency as deposition temperature increased [34].

4. Conclusion

Nanostructured amorphous carbon thin films with thickness ~42–67 nm were deposited on glass and n-Si substrates by utilizing the aerosol-assisted chemical vapor deposition (AACVD) method using camphor oil as a precursor. At higher deposition temperature, nanostructured a-C sample obtained higher conductivity due to the fact that when thickness increases, the carrier concentration and carrier mobility will increase along thus leading to higher conductivity. Also, as temperature increases the intensity of region increases, specifying the promotion of sp² bonding due to increase in graphitic order thus contributing to higher conductivity. High transmittance (>85%) and absorption coefficient, in the range of ~10⁴ cm⁻¹, were determined. From Tauc’s plot, optical band gap () was determined, and decreases as deposition temperature increases (1.2 eV, 1.0 eV, 0.7 eV).

On the other hand, the nanostructured behavior of the nanostructured a-C thin films by AACVD was confirmed by using the FESEM images. The suitability of using the nanostructured material for the carbon-based solar cell application was also discussed. To prove the suitability for nanostructured a-C deposited by AACVD for carbon-based solar cell application, the device was fabricated with the configuration of Au/p-C/n-Si/Au. The Au/p-C/n-Si/Au photovoltaic cells under the light illumination AM 1.5 SUN condition (100 mW/cm², 25°C) from solar simulator system indicate the rectifying curve for all the samples. The rectifying curves signify the heterojunction between the p-type nanostructured a-C film and the n-Si substrate and designate the generation of electron-hole pair of the samples under illumination. As deposition temperature increased, the resistivity decreased (sp² increase), and thus the photogenerated carriers could be easily transported to the Au electrode and lead to increasing efficiency as deposition temperature increased.

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Copyright © 2013 A. N. Fadzilah et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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