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International Journal of Photoenergy
Volume 2014 (2014), Article ID 943537, 6 pages
Research Article

A Facile Synthesis of Graphene-WO3 Nanowire Clusters with High Photocatalytic Activity for O2 Evolution

School of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414000, China

Received 1 April 2014; Revised 24 June 2014; Accepted 8 July 2014; Published 24 July 2014

Academic Editor: Gianluca Li Puma

Copyright © 2014 M.-J. Zhou et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


In the present work, graphene-WO3 nanowire clusters were synthesized via a facile hydrothermal method. The obtained graphene-WO3 nanowire clusters were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, and ultraviolet-visible diffuse reflectance spectroscopy (DRS) techniques. The photocatalytic oxygen (O2) evolution properties of the as-synthesized samples were investigated by measuring the amount of evolved O2 from water splitting. The graphene-WO3 nanowire clusters exhibited enhanced performance compared to pure WO3 nanowire clusters for O2 evolution. The amount of evolved O2 from water splitting after 8 h for the graphene-WO3 nanowire clusters is ca. 0.345 mmol/L, which is more than 1.9 times as much as that of the pure WO3 nanowire clusters (ca. 0.175 mmol/L). The high photocatalytic activity of the graphene-WO3 nanowire clusters was attributed to a high charge transfer rate in the presence of graphene.