Research Article | Open Access
Xia Yan, Selvaraj Venkataraj, Armin G. Aberle, "Wet-Chemical Surface Texturing of Sputter-Deposited ZnO:Al Films as Front Electrode for Thin-Film Silicon Solar Cells", International Journal of Photoenergy, vol. 2015, Article ID 548984, 10 pages, 2015. https://doi.org/10.1155/2015/548984
Wet-Chemical Surface Texturing of Sputter-Deposited ZnO:Al Films as Front Electrode for Thin-Film Silicon Solar Cells
Transparent conductive oxides (TCOs) play a major role as the front electrodes of thin-film silicon (Si) solar cells, as they can provide optical scattering and hence improved photon absorption inside the devices. In this paper we report on the surface texturing of aluminium-doped zinc oxide (ZnO:Al or AZO) films for improved light trapping in thin-film Si solar cells. The AZO films are deposited onto soda-lime glass sheets via pulsed DC magnetron sputtering. Several promising AZO texturing methods are investigated using diluted hydrochloric (HCl) and hydrofluoric acid (HF), through a two-step etching process. The developed texturing procedure combines the advantages of the HCl-induced craters and the smaller and jagged—but laterally more uniform—features created by HF etching. In the two-step process, the second etching step further enhances the optical haze, while simultaneously improving the uniformity of the texture features created by the HCl etch. The resulting AZO films show large haze values of above 40%, good scattering into large angles, and a surface angle distribution that is centred at around 30°, which is known from the literature to provide efficient light trapping for thin-film Si solar cells.
Transparent conductive oxide (TCO) front electrodes are extensively utilised in thin-film silicon (Si) solar cells. Compared to wafer-based Si solar cells, thin-film Si solar cells have a very thin absorber layer (about 200–300 nm for amorphous Si cells and about 1–3 μm for microcrystalline Si cells ), which is insufficient for absorbing a large fraction of the incoming solar photons. Therefore the front TCO layer requires a rough surface to scatter incident light into the absorber layer. An efficient light management scheme leads to an elongation of the optical path length in the device and thus a higher chance of photon absorption [1, 2]. As a result, the short-circuit current density () and the conversion efficiency of the solar cells can be increased.
Commonly used TCO materials include fluorine-doped tin oxide (FTO), tin-doped indium oxide (ITO), and zinc oxide doped with group III impurities (e.g., Al, Ga, and B) . Of these, aluminium-doped zinc oxide (ZnO:Al or AZO) is becoming more favoured as the front electrode for superstrate thin-film solar cell applications, owing to its advantages such as nontoxicity, stability against hydrogen plasma, low cost, and easy postdeposition texturing by wet-chemical etching for light management [4–6].
For magnetron sputtered AZO films, the surface texture is usually obtained through a wet-chemical etching process (resulting in crater-like features) in weak or diluted acids , such as hydrochloric acid (HCl), nitric acid (HNO3), phosphoric acid (H3PO4), acetic acid (CH3COOH), and hydrofluoric acid (HF) [8–14]. Conventional AZO texturing is based on a single etching process using diluted HCl solution. The standard HCl-etched AZO surface commonly has lateral uniformity issues due to an inhomogeneous attack by the HCl acid, regardless of the used HCl concentration [15, 16]. The appearance of small holes is also often observed after HCl etching, which may cause shunting issues for the solar cells . It has been reported that HF etching of AZO is more uniform than HCl etching . As a weak acid, HF tends to only slightly dissociate in water. Undissociated HF molecules are relatively small compared to the water hydronium cluster (e.g., H3O+) and thus can penetrate deep into grain boundaries before the start of the chemical reaction . Thus HF is able to create a higher density of attack points than HCl, which contributes to more homogenously etched textures .
Therefore, a two-step texturing procedure based on etching in HCl and HF is tested in this study. The idea behind the two-step process is to improve the lateral uniformity of the surface texture and also to further enhance the light scattering via HF etching. In order to achieve a homogeneously textured surface with enhanced light scattering capabilities, in this work we systemically investigate (i) single-step HCl or HF etching as the reference, (ii) two-step etching procedure using HF and then HCl acid, and (iii) two-step etching procedure using HCl and then HF acid for the surface texturisation of AZO films. For these experiments, pulsed DC sputtered AZO films with high transmission () in the visible wavelength range and low resistivity (~8 × 10−4 Ωcm) are used.
2. Experimental Details
2.1. Deposition of AZO Samples
AZO films were deposited onto planar A3 size (30 cm × 40 cm) soda-lime glass sheets by an inline multichamber magnetron sputter machine (Model Line 540 from FHR Anlagenbau GmbH) using a pulsed DC power supply . Dual cylindrical ZnO : Al2O3 (98 : 2 wt%) rotatable ceramic targets were used to deposit the AZO films. The applied power for each cathode was kept constant at 2 kW. During deposition, the substrate heater temperature was kept constant at 350°C (the corresponding substrate temperature was maintained at about 190°C). The chamber pressure was maintained at 3 × 10−3 mbar by introducing pure argon and oxygen-diluted argon (1% O2 and 99% Ar) as processing gases via mass flow controllers (MFCs) at constant flow rates of 155 and 50 sccm, respectively.
The deposition was carried out in dynamic mode (i.e., moving substrate). During deposition, the glass sheet was vertically attached (i.e., portrait format) on a moving carrier and allowed to oscillate 18 times in front of the AZO sputter cathodes, at a moving speed of 10 mm/s. This multiple-pass deposition potentially reduces the formation of pinholes and thus benefits the subsequent etching process . The rotating speed of the targets was kept constant at 10 rpm for all depositions. After deposition, the AZO-coated glass sheets were cut into 12 square pieces (each 10 cm × 10 cm) for the wet-chemical surface texturing experiments.
All the acids used for the AZO texturisation experiments were diluted into aqueous solutions and are represented via their volume fraction (vol%). Although diluted HF solutions can still attack the glass substrates, the reaction proceeds at a very slow speed and barely affects the glass flatness . Hence, the effect of glass etching was neglected in this study.
The optical properties of AZO films were characterised with a double-beam UV/Vis/NIR spectrophotometer featuring a 150 mm diameter integrating sphere (PerkinElmer, LAMBDA 950), which records the reflectance and transmittance spectra (diffuse and total) from 300 to 1200 nm before and after texturing the AZO films. The diffuse transmittance was measured by opening the reflectance port at the rear of the integrating sphere and thereby letting the specular light escape from the integrating sphere. The haze value was calculated via where , , and are the transmission haze, the diffuse transmittance, and the total transmittance, respectively. In addition to the spectrophotometer measurements, visible transmission and haze values (in the 350–700 nm range) of the textured AZO films were also recorded with a haze meter (BYK-Gardner, haze-gard plus) to quantitatively evaluate the optical performance. The electrical performance of the AZO films was represented by the sheet resistance value, which was measured with the four-point probe method (Napson, CRESBOX).
The AZO film thicknesses were obtained by curve fitting of the measured spectral transmittances, using the commercial optical simulation software CODE . Three dielectric models were used to model the optical properties of the AZO films: the O’Leary-Johnson-Lim (OJL) model, the extended Drude (EDR) model, and Kim’s oscillator model. Details about the fitting method can be found in [20, 21]. The surface morphology resulting from texturing the AZO films was analysed by scanning electron microscopy (SEM; Carl Zeiss, Auriga-39-35) and atomic force microscopy (AFM; Veeco, NanoScope D3100). The AFM images were taken in the central region of each sample, using the tapping mode at a scan rate of 0.5 Hz. The image scan size was set as 10 μm × 10 μm for all samples.
2.3. Analysis of Surface Inclination Angle
Statistical analysis of the surface inclination angle of textured AZO samples was carried out based on the AFM measurements and a MATLAB image processing programme [22–24]. Each AFM image consists of 512 × 512 data points, and each data pixel contains the local height information. Consider the pixel in the centre (as illustrated in Figure 1), vector one ( vertical tangent vector), and vector two ( horizontal tangent vector) connect the central pixel with its neighbouring pixels, which describes the orientation of the planar surface of the central pixel. Vector three () is perpendicular to the studied surface, thus calculated by the cross product of and via Based on these vectors, the inclination angle (α) is calculated as the angle between the normal vector () of the plane in respect to the -axis (the axis perpendicular to the mean surface level, represented by vector ). The angle distributions of the surface textures are then statistically analysed and quantified into a histogram with 5-degree increments. The literature suggests that a surface angle distribution centred at about 30° provides effective light trapping for thin-film Si solar cell applications [24, 25].
3. Results and Discussion
For comparison, two sets of etching experiments were carried out in this work. In the first set, AZO samples were textured using 1% HF for 20 s (step 1) and then further etched using 0.5% HCl (step 2) from 0 to 40 s (noted as HF/HCl etching). For the second set, AZO films were textured using 0.5% HCl for 20 s (step 1) and then further etched using 1% HF (step 2) from 0 to 40 s (noted as HCl/HF etching).
These as-grown AZO films show a low sheet resistance of 3.8 Ω/□ with a thickness of around 1.8 µm. After 20 s of HF or HCl etching (step 1), both the sheet resistance had increased to around 4.8 Ω/□. After the second etching step, the corresponding sheet resistance had further increased to 7.3 and 7.5 Ω/□ (see Figures 2(a) and 2(b)), due to the reduced film thickness. Using the thickness value obtained from CODE (as described in Section 2.2), it follows that the AZO etching rates in 0.5% HCl and 1% HF are approximately the same (15–20 nm/s). This explains why the etching sequence seems to have little effect on the change of the sheet resistance value.
In contrast to the electrical performance, the optical properties are quite sensitive to the etching sequence. The values measured with the haze meter (see Figure 2) well agree with the spectral variations measured with the spectrophotometer (see Figure 3). Before texturing, these as-grown AZO films show a high visible transmission value fluctuating around 85% but virtually no scattering capabilities with a haze value of approximately 1%. With respect to HF/HCl etching, the first step HF-etched AZO film yields a haze value of 14% at 600 nm wavelength. A maximum haze value of 31% is obtained after the second step HCl etching for 20 s. Further etching above 30 s gradually deteriorates the haze value by up to 10% (see Figure 3(b)). A similar trend is observed in the optical transmittance value (see Figure 3(a)), which reduces from around 85% (as-grown) to a minimum value of 70% at 600 nm when the second etching step (HCl) lasted 20 s and then slightly rebounces to 73% while further etching to 40 s.
A different scenario is observed for the reversed two-step etching sequence (HCl/HF). In this case the spectral profiles show that, with increasing duration of the second etching step (HF), the AZO films gradually become more scattering. The HCl-etched AZO film shows a haze value of 22% at 600 nm wavelength, which further increases to 54% when the second step HF etching time increases to 40 s (see Figure 3(d)). The film transmission into air slightly decreases from 72% to 67% at 600 nm wavelength through the second step HF etching from 0 to 40 s (see Figure 3(c)). At the same time, the near-infrared (NIR) transmission starts to improve from ~900 nm wavelength due to reduced free carrier absorption for thinner films. For both two-step etching processes (HF/HCl and HCl/HF), regardless of the duration of the second etching step, the transmission into air is only weakly affected and, at around 600 nm wavelength, generally lies in the narrow range of %; see Figures 3(a) and 3(c). It is also important to note that the actual value of the transmission into Si should be much higher than the value measured into air owing to a much high refractive index of the Si material.
The SEM micrographs in Figures 4(a)–4(e) and 4(f)–4(j) show the evolution of the AZO surface morphology during the second etching step, for the two investigated etching sequences. With regard to the HF/HCl sequence, the HCl etching step gradually removes a certain amount of HF-induced features while introducing HCl-induced craters; see Figures 4(b) to 4(e). As a result, the corresponding haze value initially increases, then reaches a maximum, and then decreases again for etching times of more than 20 s. For 40 s of HCl etching (see Figure 4(e)) a surface morphology is obtained which looks similar to that solely etched by HCl acid (see Figure 4(f)). In this case, further etching would overetch the AZO film by complete removal of these first step HF-induced features.
For the HCl/HF sequence the SEM micrographs show (see Figures 4(f) to 4(j)) that lots of small jagged HF-induced features gradually evolve and superimposedly grow on top of the HCl-etched craters. Even after relatively long etching in HF (e.g., 40 s, which is twice as long as the duration of the first etching step in HCl), the dominant surface features are still these HCl-induced craters (see Figure 4(j)). Therefore, for strong scattering, it is preferred to first use HCl to texture the AZO film, followed by etching in diluted HF to optimise the features and thus enhance the haze value. Around 20 or 30 s of HF etching is enough to achieve a good scattering, and further etching seems not to improve much anymore. From the SEM observation, it is also confirmed that the lateral uniformity of the surface textures benefits from the second step HF etching.
Figure 5 compares AFM 2D images (see Figures 5(a)–5(d)) of AZO films textured with different etching procedures and the corresponding processed images (see Figures 5(e)–5(h)). In order to better understand the light scattering capabilities of these textured films, as described in Section 2.3, the measured AFM images were processed using a MATLAB programme to determine information on the surface height and inclination angle of the texture features.
The feature height and angle distributions of the textured surface are then calculated from AFM and MATLAB simulations. Figures 6(a) and 6(c) show the height histograms of the AZO films textured with the two sets of two-step texturing methods. The HF-induced texture has a very narrow height distribution, while the additional HCl etching broadens the height distribution for the HF/HCl etching sequence. In contrast, the second step HF etching slightly widens and shifts the height distribution of HCl-etched film, for the HCl/HF etching. From the literature it is well known that a broad surface height distribution is beneficial for light trapping in thin-film Si solar cells, for a wide range of wavelengths . In this case, two-step textured AZO shows a better height distribution than either HCl or HF solely etched film.
Figures 6(b) and 6(d) compare the distribution of the surface inclination angles of these two-step textured AZO films. Texturing in HF for 20 s results in an angle distribution that peaks at about 20°; see Figure 6(b). Subsequent etching in HCl for 10 to 40 s shifts the peak by 15–20° to the right and simultaneously widens the angle distribution. In contrast, first texturing in HCl yields a narrow distribution with a peak maximum at 30°. Subsequent etching in HF for 10 to 40 s causes only slight changes to both the peak position (<5°) and the width of the distribution curve; see Figure 6(d).
In addition to the surface height and angle, the feature size also plays an essential role in the light scattering process. One of the most commonly used methods to describe the surface feature of textured AZO films is to use the power spectral density (PSD) function [27, 28]. The two-dimensional (2D) isotropic PSD function is derived by the fast Fourier transform (FFT) of the AFM scans of the surface-textured AZO films [27, 29].
Figures 7(a) and 7(c) compare the distribution of the PSD function of the two-step textured AZO films. The inverse of the -scale (spatial frequency) represents the lateral feature sizes of the surface texture; that is, a low spatial frequency represents a large lateral features size. A higher PSD intensity indicates that the corresponding lateral feature size is more dominant in the textured surface. In order to effectively scatter the incoming light, the lateral feature size of the surface texture should be comparable to the effective wavelength () , that is, around 300 to 600 nm. It is clearly observed that the lateral size of the HCl-induced texture is much larger than that of the HF-induced texture, and the second step etching can further expand the lateral size of the texture features.
The PSD function can also provide an exact value to represent the surface morphology of the textured films, such as the root-mean-square (RMS) roughness () and the autocorrelation length (), as shown in Figures 7(b) and 7(d). The RMS roughness represents how rough the textured surface is, and the autocorrelation length corresponds to the average lateral size of the randomly textured surface . The two-step textured AZO films prepared by HF and then HCl etching tends to have a small lateral size of around 150 nm, attributed to the small HF-induced textures. In contrast, the AZO films textured by HCl etching for 20 s and then HF etching for 30 or 40 s show a good average lateral feature size of around 340 nm, comparable to the effective scattering feature sizes. In addition, the RMS roughness of such two-step textured AZO films is around 100 nm, which is in the acceptable range for solar cell fabrication (note that excessive surface roughness will cause shunting issues in solar cell diodes).
Angular resolved scattering (ARS) defines the distribution of diffuse scattered light between 0° and 90°. The light intensity at an angle of 0° represents the specularly transmitted light (i.e., the nonscattered light). In this work, the ARS of the transmitted light for the textured AZO films was simulated based on the phase model by using experimental AFM images and the refractive indices of the two media (AZO/air interface) . The typical solar wavelength of 600 nm is used for the calculation. The calculated ARS results are normalised so that the total integrated transmission is equal to unity. Figure 8 shows the simulated ARS of the two-step textured AZO films. The zig-like profile line is due to the finite resolution of AFM scan .
A good correlation is observed between the calculated ARS results of Figure 8 and the optical haze measurements of Figure 3. From these experiments, as stated above, the second etching step greatly enhances optical scattering (represented by a high haze value and ARS intensity) for both texturing procedures. These textured films also show good ARS intensity at large scattering angles. The ARS results indicate that the two-step etching procedure that starts with HCl is more user-friendly, as a wide range of second-step etching times gives maximum scattering properties.
In this paper, wet-chemical texturing of pulsed DC sputtered AZO films was investigated using several etching processes: (i) single-step etching in HCl or HF acid as the reference, (ii) two-step etching in HF acid and then HCl acid, and (iii) two-step etching in HCl acid and then HF acid. Although the texturing increases the sheet resistance value of the AZO films due to reduced film thickness, there is no much difference between these different etching methods.
Compared to standard HCl-etched AZO, it is advantageous to use two-step texturing to modify the surface morphology for better optical performance. The two-step textured AZO films, initially textured in HCl and then in HF (e.g., 20 or 30 s), which slightly modified the texture features, have stronger light scattering capabilities (haze values of above 40% and good ARS intensity at large scattering angles), while maintaining similar optical transmission (~70% transmission into air at 600 nm wavelength) and a good surface angle distribution (centred at around 30°). The two-step textured films also show better lateral texture uniformity than the standard HCl-etched films, owing to the HF etching step. Thus, it is expected that the two-step texturing method (etching in HCl acid and then HF acid) produces the best performing AZO films for thin-film Si solar cell applications.
Conflict of Interests
The authors declare that there is no conflict of interests regarding the publication of this paper.
The Solar Energy Research Institute of Singapore (SERIS) is sponsored by the National University of Singapore (NUS) and Singapore’s National Research Foundation (NRF) through the Singapore Economic Development Board (EDB). This research was supported by the NRF, Prime Minister’s Office, Singapore, under its Clean Energy Research Programme (CERP, Award no. NRF2011EWT-CERP001-019). Xia Yan acknowledges a Ph.D. scholarship jointly funded by SERIS and the NUS Graduate School for Integrative Sciences and Engineering (NGS).
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