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International Journal of Photoenergy
Volume 2015, Article ID 762532, 7 pages
Research Article

Homogenized Poly(3-hexylthiophene)/Methanofullerene Film by Addition of End-Functionalized Compatibilizer and Its Application to Polymer Solar Cells

Department of Chemistry, Fu Jen Catholic University, Taipei 24205, Taiwan

Received 24 July 2014; Revised 13 October 2014; Accepted 19 January 2015

Academic Editor: Harald Hoppe

Copyright © 2015 Ping-Tsung Huang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


A uniformed poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) blended film prepared by using spin-coating process is achieved by addition of 10% hydroxyl group end-functionalized P3HT (HOC-P3HT-COH) as a compatibilizer. Ratio of P3HT/PCBM on a spin-coated film has been improved from 1 : 1.22 on the edge and 1 : 0.85 in the center of substrate (substrate size, 2 cm × 3 cm) to 1 : 1.03 on the edge and 1 : 0.94 in the center for P3HT/HOC-P3HT-COH/PCBM film (1 : 0.1 : 1). Homogeneous and reproducible polymer solar cell with an average of 3.71% power conversion efficiency under AM1.5G irradiation is fabricated with 10% HOC-P3HT-COH in P3HT/PCBM layer.