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International Journal of Photoenergy
Volume 2017, Article ID 8107073, 11 pages
Research Article

Effect of Modulating Spin-Coating Rate of TiO2 Precursor for Mesoporous Layer on Hysteresis of Solar Cells with Polar CH3NH3PbI3 Perovskite Thin Film

Research Center for Sensor Technology, Beijing Key Laboratory for Sensor, Ministry of Education Key Laboratory for Modern Measurement and Control Technology, School of Applied Sciences, Beijing Information Science and Technology University, Jianxiangqiao Campus, Beijing 100101, China

Correspondence should be addressed to Xiaoping Zou; moc.361@4102uozpx

Received 17 June 2016; Revised 3 December 2016; Accepted 14 December 2016; Published 10 January 2017

Academic Editor: Meenakshisundaram Swaminathan

Copyright © 2017 Qi Li et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Compared with the crystalline Si solar cells, the - characteristics of CH3NH3PbI3 perovskite solar cells are different under forward and reverse scan, and the CH3NH3PbI3 film exhibits some polarization properties. To explore those performances of the mesoporous TiO2 layer based perovskite solar cells, we focus on the effect of modulating the spin-coating rate of the TiO2 precursor for mesoporous layer on - hysteresis of solar cells with the polar film by - curves, atomic force microscopy topographic images, and piezoresponse force microscopy phase images. Firstly, the AFM images illustrate that the polarization behaviors exist and the deformation scale is large at the corresponding position when the DC bias voltage increases. Secondly, it is suggested that the polar films which applied the positive DC biases voltage show a tendency to 0° phase angle, while the polar films which applied the negative DC biases voltage show a tendency to −180° phase angle. Thirdly, a weak polar hysteresis loop relation for CH3NH3PbI3 film was observed. Finally, the hysteresis index for the 1500 rpm mesostructured solar cell shows relatively low - hysteresis compared with the 3000 rpm mesostructured and the planar-structured solar cell. Our experimental results bring novel routes for reducing the hysteresis and investigating the polar nature for CH3NH3PbI3 material.