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Photoanodes | Electrolytes containing redox couple | Sensitizers | Sensitization techniques |
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Wide bandgap semiconductors (TiO2, ZnO, and SnO2) | Liquid electrolytes (e.g., iodide/triiodide) up to 13.0% PCE | Metallo-organic ruthenium complexes (N3, N719, and black dye) | Cosensitization using dyes with complementary absorption spectra |
Different photoanode layer morphologies such as nanoparticle, nanorod, and nanotube | Solid electrolytes (spiro-MeOTAD, PEDOT, and metal complexes) up to 11.7% PCE | Natural or organic dyes (porphyrins, coumarins, rhodamines, etc.) | Dye combinations: Ru complexes/squaraine dyes, N3/Rhodamine B, tertiary aryl-amine D/zinc-metallated porphyrin—11% PCE |
Film deposition techniques: sol-gel, hydrothermal, electrospinning, and atomic layer deposition | Quasi-solid electrolytes (e.g., poly(acrylonitrile), poly(vinyl chloride), and poly(vinylidene fluoride)) | Novel synthetic dyes (e.g., chlorin, indolin, or BODIPY-based) | Sequential cosensitization with multiple dyes (e.g., porphyrins, coumarins, and Ru complexes) up to 8.14% PCE |
Synthesized panchromatic dye sensitizers up to 13.0% PCE | Incorporation of QD nanoparticles, such as Ag or Au up to 7.2% PCE |
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