Effect of Surfactants on Association Characteristics of Di- and Triblock Copolymers of Oxyethylene and Oxybutylene in Aqueous Solutions: Dilute Solution Phase Diagrams, SANS, and Viscosity Measurements at Different Temperatures

Table 1

Turbidity points T_p and cloud points, C_p for copolymers-surfactants mixture* solutions.

Conc., B-1	SDS								Conc., B-2	SDS
	Tp, °C				Cp, °C					Tp, °C				Cp, °C
	0	0.001	0.05	1.0	0	0.001	0.05	1.0		0	0.0005	0.05	1.0	0	0.0005	0.05	1.0
1.0	51.0	58.0	80.0	>100	58.0	82.0	>100	>100	1.0	79.0	80.0	>100	>100	83.0	85.0	>100	>100
2.0	51.0	57.0	68.0	>100	60.0	80.0	>100	>100	2.0	73.0	75.0	>100	>100	84.0	86.0	>100	>100
5.0	52.0	52.0	53.0	>100	61.0	60.0	62.0	>100	5.0	72.0	73.5	78.0	>100	85.0	85.0	93.0	>100
7.5	—	50.0	54.0	>100	—	61.0	63.0	>100	7.5	—	69.0	75.0	>100	—	87.0	91.0	>100
10.0	53.0	53.0	55.0	>100	62.0	63.0	64.0	>100	10.0	63.0	65.0	72.0	>100	86.0	88.0	89.0	>100
	DTAB									DTAB
		0.05	0.10	1.0		0.05	0.10	1.0			0.0005	0.1	1.0
1.0		54.0	66.0	>100		68.0	90.0	>100	1.0		80.0	>100	>100		85.0	>100	>100
2.0		56.0	62.0	>100		76.0	88.0	>100	2.0		74.0	>100	>100		89.0	>100	>100
5.0		54.0	57.0	>100		68.0	68.0	>100	5.0		73.0	82.0	>100		84.0	>100	>100
7.5		52.0	56.0	>100		64.0	66.0	>100	7.5		68.0	76.0	>100		86.0	92.0	>100
10.0		53.5	54.0	>100		65.0	65.0	>100	10.0		65.0	73.0	>100		87.0	89.0	>100
	TX-100									TX-100
		0.01	3.0	6.0		0.01	3.0	6.0			0.01	3.0	6.0		0.01	3.0	6.0
1.0		52.0	52.0	48.0		59.0	64.0	65.5	1.0		75.0	63.0	59.0		85.0	80.0	76.0
2.0		51.5	54.0	49.0		58.0	68.0	66.0	2.0		73.5	60.0	58.0		82.0	77.0	75.0
5.0		52.5	51.0	48.5		59.0	63.0	65.0	5.0		71.0	59.0	57.0		80.0	76.0	73.0
7.5		51.0	49.0	47.5		58.0	59.0	64.5	7.5		70.0	57.0	56.0		79.0	75.0	72.0
10.0		53.0	48.0	47.0		60.0	60.0	65.0	10.0		69.0	56.0	54.0		78.0	74.0	71.0

*Conc. (all in g·dl⁻¹).