Table of Contents Author Guidelines Submit a Manuscript
International Journal of Polymer Science
Volume 2012, Article ID 173624, 17 pages
Review Article

Design and Synthesis of Functional Silsesquioxane-Based Hybrids by Hydrolytic Condensation of Bulky Triethoxysilanes

Department of Polymer Science and Engineering, Graduate School of Science and Engineering, Yamagata University, 4-3-16, Jonan, Yonezawa 992-8510, Japan

Received 12 July 2012; Accepted 15 September 2012

Academic Editor: Kimihiro Matsukawa

Copyright © 2012 Hideharu Mori. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


This paper presents a short overview of recent advances in the design and synthesis of organic-inorganic hybrids using silsesquioxane-based nanoparticles having nanometer size, relatively narrow size distribution, high functionalities, and various characteristic features, mainly focusing on our recent researches related to the subject. A highlight of this paper is the water-soluble silsesquioxane-based nanoparticles, including hydroxyl-functionalized and cationic silsesquioxanes, which were synthesized via the one-step condensation of the bulky triethoxysilane precursors. The design and synthesis of R-SiO1.5/SiO2 and R-SiO1.5/TiO2 hybrids by hydrolytic cocondensation of a triethoxysilane precursor and metal alkoxides are briefly introduced. This paper also deals with recent results in stimuli-responsive hybrids based on the water-soluble silsesquioxane nanoparticles and fluorinated and amphiphilic silsesquioxane hybrids.