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International Journal of Polymer Science
Volume 2014 (2014), Article ID 194726, 10 pages
Research Article

Enhancement of Lignin Biopolymer Isolation from Hybrid Poplar by Organosolv Pretreatments

1Beijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University, Beijing 100083, China
2State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China

Received 30 April 2014; Revised 15 August 2014; Accepted 15 August 2014; Published 28 August 2014

Academic Editor: Geoffrey R. Mitchell

Copyright © 2014 Miao Wu et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Lignocellulosic biomass is an abundant renewable resource that has the potential to displace petroleum in the production of biomaterials and biofuels. In the present study, the fractionation of different lignin biopolymers from hybrid poplar based on organosolv pretreatments using 80% aqueous methanol, ethanol, 1-propanol, and 1-butanol at 220°C for 30 min was investigated. The isolated lignin fractions were characterized by Fourier transform infrared spectroscopy (FT-IR), high-performance anion exchange chromatography (HPAEC), 2D nuclear magnetic resonance (2D NMR), and thermogravimetric analysis (TGA). The results showed that the lignin fraction obtained with aqueous ethanol (EOL) possessed the highest yield and the strongest thermal stability compared with other lignin fractions. In addition, other lignin fractions were almost absent of neutral sugars (1.16–1.46%) though lignin preparation extracted with 1-butanol (BOL) was incongruent (7.53%). 2D HSQC spectra analysis revealed that the four lignin fractions mainly consisted of -O-4′ linkages combined with small amounts of - and -5′ linkages. Furthermore, substitution of in -O-4′ substructures had occurred due to the effects of dissolvent during the autocatalyzed alcohol organosolv pretreatments. Therefore, aqueous ethanol was found to be the most promising alcoholic organic solvent compared with other alcohols to be used in noncatalyzed processes for the pretreatment of lignocellulosic biomass in biorefinery.