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International Journal of Polymer Science
Volume 2015, Article ID 190537, 11 pages
Research Article

Comparative Analysis of the Effect of Organoclay, Boron Nitride, and Fluoropolymer on the Rheology and Instabilities in the Extrusion of High Density Polyethylene

1Department of Chemical Engineering, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia
2Gas Processing Center, College of Engineering, Qatar University, P.O. Box 2713, Doha, Qatar

Received 15 October 2014; Revised 8 February 2015; Accepted 9 February 2015

Academic Editor: Seyed-Hassan Jafari

Copyright © 2015 A. A. Adesina et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


The effect of different processing additives on the extrusion instabilities of high density polyethylene (HDPE) was investigated. The concentration of each processing additive was fixed at 0.05 wt%. Organoclay, boron nitride, and fluoropolymer reduced transient shear and extensional viscosities of HDPE melt. Drop in extrusion pressure occurred during the extrusion experiment. The initial loss of glossiness in HDPE was restored with the addition of these additives. However, the fluoropolymer did not succeed in eliminating the stick-slip fracture. Despite the inclusion of the processing additives, gross-melt fracture in HDPE reappeared at apparent shear rate of 141 s−1. Both moment and distortion factor methods of analyses were employed and their findings support the observed visual trends of the extrudate surface. The quantifying tools indicated that combined organoclay and fluoropolymer reduced the pressure fluctuations and its performance surpassed that of the individual additives.