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International Journal of Polymer Science
Volume 2017 (2017), Article ID 8236870, 13 pages
https://doi.org/10.1155/2017/8236870
Research Article

Rheological Properties in Aqueous Solution for Hydrophobically Modified Polyacrylamides Prepared in Inverse Emulsion Polymerization

1Facultad de Ciencias Básicas, Ingeniería y Tecnología, Universidad Autónoma de Tlaxcala, Calzada Apizaquito S/N, 90300 Apizaco, TLAX, Mexico
2Facultad de Ingeniería Química, Benemérita Universidad Autónoma de Puebla, Av. San Claudio y 18 Sur, Col. San Manuel Ciudad Universitaria, 72520 Puebla, PUE, Mexico
3Centro de Investigación en Química Aplicada, Blvd. Enrique Reyna #140, 25253 Saltillo, COAH, Mexico

Correspondence should be addressed to Valeria J. Gonzalez-Coronel; xm.paub.oerroc@zelaznog.airelav

Received 6 October 2016; Revised 2 February 2017; Accepted 6 February 2017; Published 29 March 2017

Academic Editor: Atsushi Sudo

Copyright © 2017 Shirley Carro et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. E. J. Jiménez-Regalado, G. Cadenas-Pliego, M. Pérez-Álvarez, and Y. Hernández-Valdez, “Study of three different families of water-soluble copolymers: synthesis, characterization and viscoelastic behavior of semidilute solutions of polymers prepared by solution polymerization,” Polymer, vol. 45, no. 6, pp. 1993–2000, 2004. View at Publisher · View at Google Scholar · View at Scopus
  2. V. J. González-Coronel and E. J. Jiménez-Regalado, “Synthesis, characterization and rheological properties of three different microstructures of water-soluble polymers prepared by solution polymerization,” Polymer Bulletin, vol. 62, no. 6, pp. 727–736, 2009. View at Publisher · View at Google Scholar · View at Scopus
  3. F. Candau and J. Selb, “Hydrophobically-modified polyacrylamides prepared by micellar polymerization,” Advances in Colloid and Interface Science, vol. 79, no. 2-3, pp. 149–172, 1999. View at Publisher · View at Google Scholar · View at Scopus
  4. A. Hill, F. Candau, and J. Selb, “Properties of hydrophobically associating polyacrylamides: influence of the method of synthesis,” Macromolecules, vol. 26, no. 17, pp. 4521–4532, 1993. View at Publisher · View at Google Scholar · View at Scopus
  5. W. D. Emmons and T. E. Stevens, “Acrylamide copolymer thickener for aqueous systems,” U.S. Patent 4 395 524, 1982.
  6. S. A. Ezzell and C. L. McCormick, “Water-soluble copolymers. 39. Synthesis and solution properties of associative acrylamido copolymers with pyrenesulfonamide fluorescence labels,” Macromolecules, vol. 25, no. 7, pp. 1881–1886, 1992. View at Publisher · View at Google Scholar · View at Scopus
  7. J. J. Effing, I. J. McLennan, and J. C. T. Kwak, “Associative phase separation observed in a hydrophobically modified poly(acrylamide)/sodium dodecyl sulfate system,” Journal of Physical Chemistry, vol. 98, no. 10, pp. 2499–2502, 1994. View at Publisher · View at Google Scholar · View at Scopus
  8. J. Bock, D. B. Siano, D. N. Schulz, S. R. Turner, and S.-L. Valint Jr., “Hydrophobically associating polymers,” Polymeric Materials: Science and Engineering, vol. 55, article 355, 1986. View at Google Scholar
  9. J. Bock, P. L. Valint Jr., S. J. Pace, D. B. Siano, D. N. Schulz, and S. R. Turner, “Hydrophobically associating polymers,” in Water-Soluble Polymers for Petroleum Recovery, G. A. Stahl and D. N. Schulz, Eds., pp. 147–160, Plenum Press, 1988. View at Google Scholar
  10. S. R. Turner, D. B. Siano, and J. Bock, “Acrylamide-Alkylacrylamide Copolymers,” U.S. Patent 4520 182, 1985.
  11. S. R. Turner, D. B. Siano, and J. Bock, “Micellar Process for the Production of Acrylamide-Alkylacrylamide Copolymers,” U.S. Patent 4528 348, 1985.
  12. S. Evani, “Water Dispersible Hydrophobic Thickening Agent,” U.S. Patent 4432 881, 1984.
  13. D. Hunkeler, “Synthesis and characterization of high molecular weight water-soluble polymers,” Polymer International, vol. 27, no. 1, pp. 23–33, 1992. View at Publisher · View at Google Scholar · View at Scopus
  14. F. Stanley Jr., “Water-In-Oil Emulsions of Hydrophobe Association Polymers,” U.S. Patent 4524 175, 1985.
  15. M. Pabon, J.-M. Corpart, J. Selb, and F. Candau, “Synthesis in inverse emulsion and associating behavior of hydrophobically modified polyacrylamides,” Journal of Applied Polymer Science, vol. 91, no. 2, pp. 916–924, 2004. View at Publisher · View at Google Scholar · View at Scopus
  16. S. R. Turner, D. B. Siano, and J. Bock, “Microemulsion Process for Producing Acrylamide-Alkyl Acrylamide Copolymers,” U.S. Patent 4521 580, 1985.
  17. J. W. Vanderhoff, E. B. Bradford, H. L. Tarkowski, J. B. Shaffer, and R. M. Wiley, “Inverse emulsion polymerization,” in Polymerization and Polycondensation Processes, vol. 34 of Advances in Chemistry, pp. 32–51, American Chemical Society, Washington, DC, USA, 1962. View at Publisher · View at Google Scholar
  18. J. W. Vanderhoff, D. L. Visioli, and M. S. El-Aasser, “Inverse emulsion polymerization of acrylamide: anomalous behavior of tetronic 1102 emulsifier,” in Polymeric Materials Science and Engineering, vol. 54, pp. 375–380, 1986. View at Google Scholar
  19. C. Graillat, C. Pichot, A. Guyot, and M. S. El Aasser, “Inverse emulsion polymerization of acrylamide. I. Contribution to the study of some mechanistic aspects,” Journal of Polymer Science Part A: Polymer Chemistry, vol. 24, no. 3, pp. 427–449, 1986. View at Publisher · View at Google Scholar · View at Scopus
  20. J. Hernández-Barajas and D. J. Hunkeler, “Inverse-emulsion polymerization of acrylamide using block copolymeric surfactants: mechanism, kinetics and modelling,” Polymer, vol. 38, no. 2, pp. 437–447, 1997. View at Publisher · View at Google Scholar · View at Scopus
  21. E. Kobitstaya, Synthesis of hydrophobically modified polyacrylamide in inverse miniemulsion [Thesis], Universität Ulm, Moscu, Russia, 2008.
  22. P. L. Valint Jr., J. Bock, and D. N. Schulz, “Synthesis and characterization of hydrophobically associating polymers,” in Polymeric Materials: Science and Engineering, vol. 57, p. 482, 1987. View at Google Scholar
  23. Z. Zhu, O. Jian, S. Paillet, J. Desbrières, and B. Grassl, “Hydrophobically modified associating polyacrylamide (HAPAM) synthesized by micellar copolymerization at high monomer concentration,” European Polymer Journal, vol. 43, no. 3, pp. 824–834, 2007. View at Publisher · View at Google Scholar · View at Scopus
  24. C. Lu, W. Li, Y. Tan et al., “Synthesis and aqueous solution properties of hydrophobically modified polyacrylamide,” Journal of Applied Polymer Science, vol. 131, no. 18, pp. 40754–40761, 2014. View at Publisher · View at Google Scholar · View at Scopus
  25. S. L. Cram, H. R. Brown, G. M. Spinks, D. Hourdet, and C. Creton, “Hydrophobically modified dimethylacrylamide synthesis and rheological behavior,” Macromolecules, vol. 38, no. 7, pp. 2981–2989, 2005. View at Publisher · View at Google Scholar · View at Scopus
  26. S. Hietala, P. Mononen, S. Strandman et al., “Synthesis and rheological properties of an associative star polymer in aqueous solutions,” Polymer, vol. 48, no. 14, pp. 4087–4096, 2007. View at Publisher · View at Google Scholar · View at Scopus
  27. E. K. Penott-Chang, L. Gouveia, I. J. Fernández, A. J. Müller, A. Díaz-Barrios, and A. E. Sáez, “Rheology of aqueous solutions of hydrophobically modified polyacrylamides and surfactants,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 295, no. 1-3, pp. 99–106, 2007. View at Publisher · View at Google Scholar · View at Scopus
  28. F. Bezzaoucha, P. Lochon, A. Jonquières, A. Fischer, A. Brembilla, and D. Aïnad-Tabet, “New amphiphilic polyacrylamides: synthesis and characterisation of pseudo-micellar organisation in aqueous media,” European Polymer Journal, vol. 43, no. 10, pp. 4440–4452, 2007. View at Publisher · View at Google Scholar · View at Scopus
  29. Q. Ye, X. Ge, H. Liu, H. Jia, W. He, and Z. Zhang, “Formation of monodisperse polyacrylamide particles by dispersion polymerization. I. Synthesis and polymerization kinetics,” Journal of Macromolecular Science—Pure and Applied Chemistry, vol. 39, no. 6, pp. 545–556, 2002. View at Publisher · View at Google Scholar · View at Scopus
  30. Y. Li and J. C. T. Kwak, “Rheology and binding studies in aqueous systems of hydrophobically modified acrylamide and acrylic acid copolymers and surfactants,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 225, no. 1-3, pp. 169–180, 2003. View at Publisher · View at Google Scholar · View at Scopus
  31. J. Klein, G. Hannemann, and W.-M. Kulicke, “Zum Fließverhalten niedermolekularer Polyacrylamide in einem weiten Konzentrationsbereich,” Colloid and Polymer Science Kolloid Zeitschrift & Zeitschrift für Polymere, vol. 258, no. 6, pp. 719–732, 1980. View at Publisher · View at Google Scholar · View at Scopus
  32. I. Capek, “Inverse emulsion polymerization of acrylamide initiated by oil- and water-soluble initiators: effect of emulsifier concentration,” Polymer Journal, vol. 36, no. 10, pp. 793–803, 2004. View at Publisher · View at Google Scholar · View at Scopus
  33. J. Herrera-Ordonez, O. Rivera, H. Maldonado-Textle, and J. C. Ramirez, “Kinetics of styrene emulsion polymerization above the critical micelle concentration: effect of the initial monomer concentration on the molecular weight,” Journal of Polymer Science, Part A: Polymer Chemistry, vol. 43, no. 9, pp. 1963–1972, 2005. View at Publisher · View at Google Scholar · View at Scopus
  34. S. Carro, J. Herrera-Ordonez, and J. Castillo-Tejas, “On the evolution of the rate of polymerization, number and size distribution of particles in styrene emulsion polymerization above CMC,” Journal of Polymer Science, Part A: Polymer Chemistry, vol. 48, no. 14, pp. 3152–3160, 2010. View at Publisher · View at Google Scholar · View at Scopus
  35. V. J. González Coronel and E. J. Jiménez-Regalado, “Rheological properties of three different microstructures of water-soluble polymers prepared by solution polymerization,” Polymer Bulletin, vol. 67, no. 2, pp. 251–262, 2011. View at Publisher · View at Google Scholar · View at Scopus
  36. J. Bock, D. B. Siano, P. L. Valint Jr., and S. J. Pace, “Structure and properties of hidrophobically associated polymers,” in Polymeric Materials: Science and Engineering, vol. 57, pp. 487–491, 1987. View at Google Scholar
  37. E. Volpert, J. Selb, and F. Candau, “Associating behaviour of polyacrylamides hydrophobically modified with dihexylacrylamide,” Polymer, vol. 39, no. 5, pp. 1025–1033, 1998. View at Publisher · View at Google Scholar · View at Scopus
  38. E. Volpert, J. Selb, and F. Candau, “Influence of the hydrophobe structure on composition, microstructure, and rheology in associating polyacrylamides prepared by micellar copolymerization,” Macromolecules, vol. 29, no. 5, pp. 1452–1463, 1996. View at Publisher · View at Google Scholar · View at Scopus
  39. W. Xue, I. W. Hamley, V. Castelletto, and P. D. Olmsted, “Synthesis and characterization of hydrophobically modified polyacrylamides and some observations on rheological properties,” European Polymer Journal, vol. 40, no. 1, pp. 47–56, 2004. View at Publisher · View at Google Scholar · View at Scopus
  40. L. Ouyang, L. Wang, and F. J. Schork, “Synthesis and nucleation mechanism of inverse emulsion polymerization of acrylamide by RAFT polymerization: a comparative study,” Polymer, vol. 52, no. 1, pp. 63–67, 2011. View at Publisher · View at Google Scholar · View at Scopus
  41. F. Candau, Y. S. Leong, and G. J. Pouyet, “Inverse microemulsion polymerization of acrylamide; Characterization of the water-in-oil microemulsions and the final microlatexes,” Journal of Colloid and Interface Science, vol. 114, no. 2, pp. 167–183, 1984. View at Google Scholar
  42. F. Candau, Z. Zekhnini, and J. P. Durand, “Copolymerization of water-soluble monomers in nonionic bicontinuous microemulsions,” Journal of Colloid and Interface Science, vol. 114, no. 2, pp. 398–408, 1986. View at Google Scholar
  43. I. Capek, L. Fialová, and D. Berek, “On the kinetics of inverse emulsion polymerization of acrylamide,” Designed Monomers and Polymers, vol. 11, no. 2, pp. 123–137, 2008. View at Publisher · View at Google Scholar · View at Scopus
  44. M. Barari, M. Abdollahi, and M. Hemmati, “Synthesis and characterization of high molecular weight polyacrylamide nanoparticles by inverse-emulsion polymerization,” Iranian Polymer Journal, vol. 20, no. 1, pp. 65–76, 2011. View at Google Scholar · View at Scopus
  45. C. Chassenieux, T. Nicolai, and L. Benyahia, “Rheology of associative polymer solutions,” Current Opinion in Colloid and Interface Science, vol. 16, no. 1, pp. 18–26, 2011. View at Publisher · View at Google Scholar · View at Scopus
  46. J. Castillo-Tejas, O. Castrejón-González, S. Carro, V. González-Coronel, J. F. J. Alvarado, and O. Manero, “Associative polymers. Part III: shear rheology from molecular dynamics,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 491, pp. 37–49, 2016. View at Publisher · View at Google Scholar · View at Scopus
  47. M. Camail, A. Margaillan, I. Martin, A. L. Papailhou, and J. L. Vernet, “Synthesis of N-alkyl- and N-arylalkylacrylamides and micellar copolymerization with acrylamide,” European Polymer Journal, vol. 36, no. 9, pp. 1853–1863, 2000. View at Publisher · View at Google Scholar · View at Scopus
  48. V. Castelletto, I. W. Hamley, W. Xue, C. Sommer, J. S. Pedersen, and P. D. Olmsted, “Rheological and structural characterization of hydrophobically modified polyacrylamide solutions in the semidilute regime,” Macromolecules, vol. 37, no. 4, pp. 1492–1501, 2004. View at Publisher · View at Google Scholar · View at Scopus
  49. A. A. Abdala, W. Wu, K. R. Olesen, R. D. Jenkins, A. E. Tonelli, and S. A. Khan, “Solution rheology of hydrophobically modified associative polymers: effects of backbone composition and hydrophobe concentration,” Journal of Rheology, vol. 48, no. 5, pp. 979–994, 2004. View at Publisher · View at Google Scholar · View at Scopus
  50. D. A. Z. Wever, F. Picchioni, and A. A. Broekhuis, “Branched polyacrylamides: synthesis and effect of molecular architecture on solution rheology,” European Polymer Journal, vol. 49, no. 10, pp. 3289–3301, 2013. View at Publisher · View at Google Scholar · View at Scopus