Investigation of the Specific Retention Volume of the Probe Volume and the Effects on the Polymer-Probe System by Inverse Gas Chromatography

Table 10

Flory-Huggins interaction parameters of the alkanes-CHMMA polymer system.

(K)
	n-Hexane			n-Heptane			n-Octane			n-Nonane
	0,3 μl	0,6 μl	0,9 μl	0,3 μl	0,6 μl	0,9 μl	0,3 μl	0,6 μl	0,9 μl	0,3 μl	0,6 μl	0,9 μl
423	−0,306	−0,33	−0,407	0,43	0,379	0,317	0,915	0,825	0,766	1,253	1,168	1,122
413	−0,255	−0,28	−0,285	0,537	0,517	0,448	0,974	0,925	0,902	1,295	1,261	1,231
403	−0,0983	−0,11	−0,137	0,708	0,693	0,614	1,181	1,155	1,083	1,532	1,505	1,45
393	0,0538	0,014	−0,008	0,881	0,863	0,793	1,395	1,356	1,294	1,759	1,739	1,68
383	0,223	0,199	0,181	1,072	1,058	0,988	1,614	1,579	1,522	1,964	1,938	1,904
373	0,393	0,372	0,339	1,278	1,267	1,172	1,86	1,789	1,771	2,226	2,183	2,139
363	0,57	0,564	0,535	1,503	1,468	1,388	2,058	2,031	1,984	2,457	2,434	2,324
353	0,779	0,756	0,742	1,716	1,65	1,628	2,32	2,291	2,259	2,749	2,631	2,556
343	0,991	0,933	0,865	1,974	1,873	1,847	2,576	2,469	2,501	2,96	2,827	2,75
333	1,319	1,265	1,207	2,31	2,21	2,172	2,893	2,806	2,761	3,279	3,147	3,052
323	1,495	1,396	1,303	2,451	2,37	2,294	2,978	2,869	2,795	3,275	3,266	3,119
313	1,592	1,578	1,43	2,591	2,501	2,383	2,982	2,881	2,857	3,309	3,126	3,038