Table of Contents
ISRN Organic Chemistry
Volume 2012, Article ID 635835, 6 pages
http://dx.doi.org/10.5402/2012/635835
Research Article

I 𝟐 -SDS- H 𝟐 O System: A highly Efficient Dual Catalytic Green System for Deprotection of Imines and in Situ Preparation of Bis(indolyl)alkanes from Indoles in Water

1Department of Chemistry, Jorhat Institute of Science and Technology, Assam Jorhat 785010, India
2Synthetic Organic Chemistry Division, North East Institute of Science and Technology, Assam Jorhat 785006, India

Received 27 April 2012; Accepted 7 June 2012

Academic Editors: D. Morales-Morales, G. Palumbo, and J.-P. Praly

Copyright © 2012 Parasa Hazarika et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

A novel catalytic system consisting of I2-SDS-H2O has been developed which cleaves 2,3-diaza-1,3-butadiene, 1-aza-1,3-butadienes, oximes and in presence of indoles in the medium uses the corresponding aldehyde products to produce bis(indolyl)alkanes in situ. This one pot simple and mild dual catalytic system works in water at room temperature under neutral conditions.