Table of Contents
ISRN Spectroscopy
Volume 2012, Article ID 712837, 7 pages
http://dx.doi.org/10.5402/2012/712837
Research Article

Characterization of Biochar Properties Affected by Different Pyrolysis Temperatures Using Visible-Near-Infrared Spectroscopy

1College of Information Engineering, Zhejiang University of Technology, Hangzhou 310032, China
2School of Biosystems Engineering and Food Sciences, Zhejiang University, Hangzhou 310058, China

Received 15 October 2012; Accepted 2 November 2012

Academic Editors: P. Johansson and S. Prati

Copyright © 2012 Haiqing Yang and Kuichuan Sheng. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Rapid characterization of biochar for energy and ecological purpose utilization is fundamental. In this work, visible and near-infrared (vis-NIR) spectroscopy was used to measure ash, volatile matter, fixed carbon contents, and calorific value of three types of biochar produced from pine wood, cedar wood, and cotton stalk, respectively. The vis-NIR spectroscopy was also used to discriminate biochar feedstock types and pyrolysis temperature. Prediction result shows that partial least squares (PLS) regression calibrating the spectra to the values of biochar properties achieved very good or excellent performance with coefficient of determination () of 0.86~0.91 and residual prediction deviation (RPD) of 2.58~3.32 for ash, volatile matter, and fixed carbon, and good prediction with of 0.81 and RPD of 2.30 for calorific value. Linear discrimination analysis (LDA) of the principal components (PCs) produced from PCA of wavelength matrix shows that three types of biochar can be successfully discriminated with 95.2% accuracy. The classification of biochar with different pyrolysis temperatures can be conducted with 69% accuracy for all three types and 100% accuracy for single type of cotton stalk. This experiment suggests that the vis-NIR spectroscopy is promising as an alternative of traditionally quantitative and qualitative analysis of biochar properties.