Research Article
Synthesis and Characterization of Nanometric Pure Phase SnO2 Obtained from Pyrolysis of Diorganotin(IV) Derivatives of Macrocycles
Table 2
Kinetic data of thermal decomposition of n-Bu2Sn (L2).
| | Complex | Parameters
| From Horowitz and Metzger method
| From Coats and Redfern method
|
| | n-Bu2Sn (L2) | (kJ mol−1) | 272.20 | 312.67 | | A (s−1) | 9.01 × 1023 | 7.2 × 1024 | | (J K-1 mol−1) | −672.31 | −655.00 | | (kJ mol−1) | 644.70 | 680.13 | | (kJ mol−1) | 267.53 | 312.67 |
|
|
