Effect of Structure of Monocyclic Aromatic Solvents on the Packing Density of Fullerene C₆₀ Solvation Shell

Figure 1

Graphic illustration of the procedure of obtaining the AS spectra corresponding to the true value 𝑐_AS,sp of AS concentration from the spectrum of (1) (C₆₀+AS) solution in THF. (2) is the transformed standard spectrum of C₆₀; (3) is the spectrum of AS corresponding to 𝑐_AS,cal; (4) is the spectrum of AS obtained as the difference (1) and (2) spectra and corresponding to the required concentration 𝑐_AS,sp (AS is chlorobenzene; 𝑐_𝐹=0.0058mg/mL, 𝑐_{chlorbenzene,cal}=1.974mg/mL, and 𝑐_{chlorobenzene,sp}=1.806mg/mL).