Synthesis, Crystal Structure, Antioxidant, Antimicrobial, and Mutagenic Activities and DNA Interaction Studies of Ni(II) Schiff Base 4-Methoxy-3-benzyloxybenzaldehyde Thiosemicarbazide Complexes

Table 3

Selected bond lengths (Å) and bond angles (°) for NiL₂(1) complex.

Ni1–N1^i	1.937(2)	N1–N2	1.386(3)
Ni1–N1	1.937(2)	N2–C16	1.295(4)
Ni1–S1	2.1614(11)	N3–C16	1.335(4)
Ni1–S1^i	2.1614(11)	N4–C19	1.323(7)
S1–C16	1.716(3)	N4–C18	1.384(7)
N1^i–Ni1–N1	180.00(9)	C18–N4–C17	122.0(7)
N1^i–Ni1–S1	94.26(8)	O1–C6–C7	108.3(3)
N1–Ni1–S1	85.74(8)	O1–C8–C9	124.7(3)
N1^i–Ni1–S1^i	85.74(8)	O1–C8–C13	114.6(3)
N1–Ni1–S1^i	94.26(8)	C9–C8–C13	120.7(3)
S1–Ni1–S1^i	180.00(4)	C8–C9–C10	120.3(3)
C16–S1–Ni1	97.15(11)	O2–C13–C12	125.4(3)
C8–O1–C6	117.2(2)	O2–C13–C8	115.0(3)
C13–O2–C14	118.0(2)	C12–C13–C8	119.5(3)
C15–N1–N2	114.2(2)	N1–C15–C10	133.4(3)
C15–N1–Ni1	125.8(2)	N2–C16–N3	119.6(3)
N2–N1–Ni1	119.96(19)	N2–C16–S1	122.8(2)
C16–N2–N1	113.9(2)	N3–C16–S1	117.6(2)
C19–N4–C18	119.3(7)	O2–C13–C12	125.4(3)
C19–N4–C17	118.7(5)	O2–C13–C8	115.0(3)