Table of Contents
ISRN Organic Chemistry
Volume 2013, Article ID 793159, 6 pages
http://dx.doi.org/10.1155/2013/793159
Research Article

Nanorod-Shaped Basic Catalyzed N,N-Diformylation of Bisuracil Derivatives: A Greener “NOSE” Approach

Department of Chemical Sciences, Tezpur University (A Central University), Napaam, Assam 784028, India

Received 14 May 2013; Accepted 10 June 2013

Academic Editors: R. Pohl and D. Sémeril

Copyright © 2013 Vijay K. Das and Ashim J. Thakur. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

A feasible “NOSE” (nanoparticles-catalyzed organic synthesis enhancement) protocol has been developed for N,N-diformylation of bisuracil derivatives using nano-Al2O3 rods as an efficient, inexpensive, and recyclable catalyst under solvent-free reaction condition at 40°C. The catalyst was reused up to the 4th cycle without affecting the rate and yield of the N,N-diformylation products appreciably.