Table of Contents
ISRN Inorganic Chemistry
Volume 2013 (2013), Article ID 871640, 5 pages
http://dx.doi.org/10.1155/2013/871640
Research Article

New Insights into the Chemistry of Oxovanadium(IV) Complexes with N4 Coordinating Ligands

1Department of Chemistry, North Eastern Regional Institute of Science and Technology (NERIST), Arunachal Pradesh, Nirjuli 791109, India
2Department of Chemistry, J.P. University, Bihar, Chapra 841301, India
3Department of Chemistry, D.A-V. College, Uttar Pradesh, Kanpur 208001, India

Received 2 September 2012; Accepted 24 September 2012

Academic Editors: W. Ding and S. B. Etcheverry

Copyright © 2012 Ashok Kumar Yadava et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The syntheses of new oxovanadium(IV) complexes having general formula [VO(mac)]SO4 have been carried out by using in situ method of preparation where vanadyl ion acts as kinetic template for the ligands derived by condensation of 2,2′-pyridil with 1,2-diaminopropane and 1,3-diaminopropane. The complexes were characterized by elemental analyses, molar conductance, magnetic moments, and spectral (infrared, electronic, and electron spin resonance) data. All the oxovanadium(IV) complexes are five coordinate wherein derived ligands act as tetradentate chelating agents.